About Lanthanoid Fluoride Selenide Oxoselenotantalates with the Composition Ln3F2Se2TaO4 (Ln = La – Nd)

Zeitschrift fur Anorganische und Allgemeine Chemie - Tập 646 Số 18 - Trang 1588-1594 - 2020
Hagen Grossholz1, Constantin Buyer1, Sebastian M. A. Lotter1, Sarah Wolf1, Thomas Schleid1,2
1Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany
2Prof. Dr. Th. Schleid

Tóm tắt

After solid‐state reactions of the light lanthanoid metals, their oxides and fluorides as well as selenium in sealed tantalum ampoules with sodium chloride as a fluxing agent at 850 °C for 8 days needle‐shaped single crystals of Ln3F2Se2TaO4 (Ln = La – Nd) were obtained. They crystallize in the orthorhombic space group Pnma analogous to La3F2Se2NbO4 with a = 1133–1120 pm, b = 400–393 pm and c = 1812–1778 pm (Ln = La – Nd) for Z = 4 as the first known quinary lanthanoid(III) oxoselenotantalates(V) with fluoride and selenide anions. The three crystallographically different Ln3+ cations are all surrounded by nine anions (O2–, F– and Se2–) each. Tantalum resides in an octahedral chalcogen coordination by forming trans‐vertex oxygen‐connected [TaO5Se]7– polyhedra, which build up chains 1∞{[TaOV2/2Ot3/1Set1/1]5–} along [010]. The sites of the four crystallographically different oxygen atoms and the two distinct fluoride anions were established by bond‐valence calculations. One fluorine and three oxygen atoms are surrounded tetrahedrally by cations, while another fluoride and oxide anion exhibit just triangular non‐planar coordination spheres. The two independent Se2– anions have five or six cationic neighbors.

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Zeitschrift fur Anorganische und Allgemeine Chemie

Tập 646 Số 18

1588-1594

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