A Novel d‐f Heterometallic CdII‐EuIII Metal‐organic Framework as a Sensitive Luminescent Sensor for the Dual Detection of Ronidazole and 4‐Nitrophenol

Zeitschrift fur Anorganische und Allgemeine Chemie - Tập 646 Số 5 - Trang 268-274 - 2020
Mengyue Jiang1, Li Yu1, Yicheng Zhou1, Jing Jia1, Xue‐Jian Si1, Wen‐Wen Dong1, Zhengfang Tian2, Jun Zhao1, Dong‐Sheng Li1
1College of Materials and Chemical Engineering Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials China Three Gorges University 443002 Yichang P. R. China
2Hubei Key Laboratory of Processing and Application of Catalytic Materials Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials Huanggang Normal University 438000 Huanggang P. R. China

Tóm tắt

A novel three‐dimensional (3D) d‐f heterometallic metal‐organic framework (MOF) formulated as [EuCd1.5L2(H2O)3]·2H2O (1) [H3L = 5‐(4‐(tetrazol‐5‐yl)phenyl)isophthalic acid] was successfully synthesized and characterized. Structural analysis displays that 1 features a 3D (3, 12)‐connected framework constructed by [Eu2Cd3(tetrazole)4(COO)8] units. The powder X‐ray diffraction measurement of 1 immersed in different solvents reveals that 1 possess good solvent stability. It is worth noting that 1 displays highly selective detection for ronidazole (RDZ) and 4‐nitrophenol (4‐NP) through luminescence quenching. The possible mechanism of luminescent sensing is also well discussed.

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Zeitschrift fur Anorganische und Allgemeine Chemie

Tập 646 Số 5

268-274

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