Bromide-ion distribution in the interlayer of the layered double hydroxides of Zn and Al: Observation of positional disorder

Cambridge University Press (CUP) - 2009
S. Prasanna1, Anu Radha1, P. Vishnu Kamath1, Kannan Srinivasan2
1Department of Chemistry, Central College, Bangalore University, Bangalore, India
2Discipline of Inorganic Materials and Catalysis, Central Salt and Marine Research Institute (Council of Scientific and Industrial Research), Bhavnagar, India

Tóm tắt

AbstractBecause of the anisotropy in bonding, layered hydroxides crystallize with extensive structural disorder due to the incorporation of stacking faults. In contrast, the loss of crystallinity in Br−-ion intercalated layered double hydroxides (LDHs) arises due to the positional disorder of Br− in the interlayer. The structure of the interlayer in other LDHs is poorly understood due to the low X-ray scattering power of the commonly found anions such as Cl− and NO3−\$\end{document} relative to that of the metal hydroxide layers. On heating to 175°C, the Br− ion migrates from positions of lesser site degeneracy to those of greater site degeneracy as dehydration of the interlayer opens up access to positions hitherto occupied by intercalated water molecules. The new (18h) site is situated closer to the proton of the metal hydroxide layer (1.809 Å) compared to the 6c site (2.402 Å). This shows a pre-association of the bromide ion with the proton of the hydroxide layer leading to the release of HBr upon decomposition of the bromide-containing LDHs. The fact that Cl−-containing LDHs also decompose with the evolution of HCl shows that such a redistribution of the atoms in the interlayer is more common than is generally recognized.

Từ khóa


Tài liệu tham khảo

De Roy, 2001, Layered Double Hydroxides: Past and Future, 1

10.1021/jp0000735

10.1346/CCMN.2004.0520603

10.1346/CCMN.1993.0410504

10.1021/jp960039j

10.1346/CCMN.2005.0530508

10.1016/0920-5861(91)80068-K

10.1081/CR-120001809

10.1016/j.materresbull.2006.09.021

10.1016/j.jcis.2006.08.064

10.1006/jssc.2000.8740

10.1007/BF02708774

10.1021/ie060757k

Rodriguez-Carvajal, Full Prof 2000

10.1016/0167-2738(93)90373-B

Treacy, 1991, A general recursion method for calculating diffracted intensities from crystals containing planar faults, Proceedings of Royal Society, London, A433, 499

10.1021/jp0684170

10.1016/j.clay.2006.08.010

10.1021/jp061377f

10.1016/j.clay.2006.06.010

Thông tin
Thông tin xuất bản

Cambridge University Press (CUP)

Thông tin tác giả