Revisiting the use of gold and silver functionalised nanoparticles as colorimetric and fluorometric chemosensors for metal ions

Earthquake Spectra - Tập 212 - Trang 297-328 - 2015
Elisabete Oliveira1,2,3, Cristina Núñez1,2,4, Hugo Miguel Santos1,2,5, Javier Fernández-Lodeiro1,2, Adrián Fernández-Lodeiro1,2, José Luis Capelo1,2, Carlos Lodeiro1,2
1BIOSCOPE Research Group, REQUIMTE-UCIBIO, Chemistry Department, Faculty of Science and Technology, NOVA University of Lisbon, Caparica Campus, 2829-516 Caparica, Portugal
2PROTEOMASS Scientific Society, Rua dos Inventores, Madam Parque, Caparica Campus, Portugal
3Veterinary Science Department, CECAV, University of Trás-os-Montes and Alto Douro, 5001-801 Vila Real, Portugal
4Inorganic Chemistry Department, Faculty of Chemistry, University of Santiago de Compostela, Spain
5Center of Genomics and Biotechnology, Institute for Biotechnology and Bioengineering, University of Trás-os-Montes and Alto Douro, 5001-801 Vila Real, Portugal

Tài liệu tham khảo

Chen, 2004, The structure of catalytically active gold on titania, Science, 306, 252, 10.1126/science.1102420 Campbell, 2004, The roots of plant-microbe collaborations, Science, 304, 234, 10.1126/science.1104246 Lim, 2008, DNA-embedded Au/Ag core-shell nanoparticles, Chem. Commun., 5312, 10.1039/b810195g Leesutthiphonchai, 2011, Selective determination of homocysteine levels in human plasma using a silver nanoparticle-based colorimetric assay, Talanta, 85, 870, 10.1016/j.talanta.2011.04.041 Li, 2009, Glutathione-stabilized silver nanoparticles as colorimetric sensor for Ni2+ ion, Sens. Actuators B, 143, 87, 10.1016/j.snb.2009.09.013 Liang, 2012, The surface-plasmon-resonance effect of nanogold/silver and its analytical applications, Trends Anal. Chem., 37, 32, 10.1016/j.trac.2012.03.015 Evanoff, 2004, Size-controlled synthesis of nanoparticles. Measurement of extinction, scattering, and absorption cross sections, J. Phys. Chem. B, 108, 13957, 10.1021/jp0475640 Kelly, 2003, The optical properties of metal nanoparticles: the influence of size, shape, and dielectric environment, J. Phys. Chem. B, 107, 668, 10.1021/jp026731y Gosh, 2007, Interparticle coupling effect on the surface plasmon resonance of gold nanoparticles: from theory to applications, Chem. Rev., 107, 4797, 10.1021/cr0680282 Link, 2003, Optical properties and ultrafast dynamics of metallic nanocrystals, Annu. Rev. Phys. Chem., 54, 331, 10.1146/annurev.physchem.54.011002.103759 Mie, 1908, Beiträge zur Optik trüber Medien, speziell kolloidaler Metallösungen, Ann. Phys., 330, 377, 10.1002/andp.19083300302 Haes, 2004, Using solution-phase nanoparticles, surface-confined nanoparticle arrays and single nanoparticles as biological sensing platforms, J. Fluoresc., 14, 355, 10.1023/B:JOFL.0000031817.35049.1f Gans, 1912, The shape of ultra microscopic gold particles, Ann. Phys., 37, 881, 10.1002/andp.19123420503 Link, 1999, Spectral properties and relaxation dynamics of surface plasmon electronic oscillations in gold and silver nanodots and nanorods, J. Phys. Chem. B, 103, 8410, 10.1021/jp9917648 Burda, 2005, Chemistry and properties of nanocrystals of different shapes, Chem. Rev., 105, 1025, 10.1021/cr030063a Evanoff, 2005, Synthesis and optical properties of silver nanoparticles and arrays, ChemPhysChem, 6, 1221, 10.1002/cphc.200500113 Kumbhar, 2004, Synthesis and characterization of titania-coated silver nanoparticles, J. Nanosci. Nanotechnol., 4, 299, 10.1166/jnn.2004.032 Haes, 2004, A localized surface plasmon resonance biosensor: first steps toward an assay for Alzheimer's disease, Nano Lett., 4, 1029, 10.1021/nl049670j Zhu, 2010, Optical properties and immunoassay applications of noble metal nanoparticles, J. Nanomater., 10.1155/2010/562035 Lee, 2006, Gold and silver nanoparticles in sensing and imaging: sensitivity of plasmon response to size, shape, and metal composition, J. Phys. Chem. B, 110, 19220, 10.1021/jp062536y Kim, 2002, Photochemical synthesis of gold nanorods, J. Am. Chem. Soc., 124, 14316, 10.1021/ja028110o Yin, 2002, Synthesis and characterization of stable aqueous dispersions of silver nanoparticles through the Tollens process, J. Mater. Chem., 12, 522, 10.1039/b107469e Liu, 2004, Adenosine-dependent assembly of aptazyme-functionalized gold nanoparticles and its application as a colorimetric biosensor, Anal. Chem., 76, 1627, 10.1021/ac0351769 Liu, 2007, A DNAzyme catalytic beacon sensor for paramagnetic Cu2+ ions in aqueous solution with high sensitivity and selectivity, J. Am. Chem. Soc., 129, 9838, 10.1021/ja0717358 Pasternack, 1995, Resonance light scattering: a new technique for studying chromophore aggregation, Science, 269, 935, 10.1126/science.7638615 Pasternack, 1993, Porphyrin assemblies on DNA as studied by a resonance light-scattering technique, J. Am. Chem. Soc., 115, 5393, 10.1021/ja00066a006 Xu, 2012, Ultrasensitive colorimetric DNA detection using a combination of rolling circle amplification and nicking endonuclease-assisted nanoparticle amplification (NEANA), Small, 8, 1846, 10.1002/smll.201200263 Xue, 2009, Multiplex single-nucleotide polymorphism typing by nanoparticle-coupled DNA-templated reactions, J. Am. Chem. Soc., 131, 11668, 10.1021/ja904728v Xie, 2011, Colorimetric detection of HIV-1 ribonuclease H activity by gold nanoparticles, Small, 7, 1393, 10.1002/smll.201002150 Chah, 2005, Gold nanoparticles as a colorimetric sensor for protein conformational changes, Chem. Biol., 12, 323, 10.1016/j.chembiol.2005.01.013 Han, 2006, A gold nanoparticle based approach for screening triplex DNA binders, J. Am. Chem. Soc., 128, 4954, 10.1021/ja0606475 Zhang, 2008, Visual cocaine detection with gold nanoparticles and rationally engineered aptamer structures, Small, 4, 1196, 10.1002/smll.200800057 Reynolds, 2006, Gold glyconanoparticles for mimics and measurement of metal ion-mediated carbohydrate-carbohydrate interactions, Langmuir, 22, 1156, 10.1021/la052261y Yang, 2007, Fast colorimetric detection of copper ions using l-cysteine functionalized gold nanoparticles, J. Nanosci. Nanotechnol., 7, 712, 10.1166/jnn.2007.116 Cushing, 2004, Recent advances in the liquid-phase syntheses of inorganic nanoparticles, Chem. Rev., 104, 3893, 10.1021/cr030027b Grainer, 2008, Nanobiomaterials and nanoanalysis: opportunities for improving the science to benefit biomedical technologies, Adv. Mater., 20, 867, 10.1002/adma.200701760 Moragues, 2011, Chromogenic and fluorogenic chemosensors and reagents for anions. A comprehensive review of the year 2009, Chem. Soc. Rev., 40, 2593, 10.1039/c0cs00015a Han, 2009, Silica-based chromogenic and fluorogenic hybrid chemosensor materials, Chem. Soc. Rev., 38, 1904, 10.1039/b818893a Das, 2011, Interaction of inorganic nanoparticles with graphene, Chem. Phys. Chem., 12, 937, 10.1002/cphc.201001090 Voggu, 2009, Effect of electronic coupling between CdSe nanocrystals on the photoluminescence spectra, J. Nanosci. Nanotechnol., 9, 5646, 10.1166/jnn.2009.1178 Li, 2006, Elimination efficiency of different reagents for the memory effect of mercury using ICP-MS, J. Anal. At. Spectrom., 21, 94, 10.1039/B511367A Leermakers, 2005, Mercury in environmental samples: speciation, artifacts and validation, Trends Anal. Chem., 24, 383, 10.1016/j.trac.2004.01.001 Valeur, 2002 Zhang, 2011, Metal ion sensors based on DNAzymes and related DNA molecules, Annu. Rev. Anal. Chem., 4, 105, 10.1146/annurev.anchem.111808.073617 Chen, 2007, Controllable colors and shapes of silver nanostructures based on pH: application to surface-enhanced Raman scattering, Nanotechnology, 18, 325602, 10.1088/0957-4484/18/32/325602 Pilo-Pais, 2014, Surface-enhanced Raman scattering plasmonic enhancement using DNA origami-based complex metallic nanostructures, Nano Lett., 14, 2099, 10.1021/nl5003069 Li, 2010, Silver nanoparticle-enhanced fluorescence in microtransponder-based immuno- and DNA hybridization assays, Anal. Bioanal. Chem., 1993, 10.1007/s00216-010-4108-7 Crut, 2014, Optical absorption and scattering spectroscopies of single nano-objects, Chem. Soc. Rev., 43, 3921, 10.1039/c3cs60367a Turkevich, 1951, A study of the nucleation and growth processes in the synthesis of colloidal gold, Discuss. Faraday Soc., 11, 55, 10.1039/df9511100055 Frens, 1973, Controlled nucleation for the regulation of the particle size in monodisperse gold suspensions, Nat. Phys. Sci., 241, 20, 10.1038/physci241020a0 Yonezawa, 1999, Practical preparation of anionic mercapto ligand-stabilized gold nanoparticles and their immobilization, Colloids Surf. A, 149, 193, 10.1016/S0927-7757(98)00309-4 Gittins, 2001, Spontaneous phase transfer of nanoparticulate metals from organic to aqueous media, Angew. Chem. Int. Ed., 40, 3001, 10.1002/1521-3773(20010817)40:16<3001::AID-ANIE3001>3.0.CO;2-5 Templeton, 1999, Water-soluble, isolable gold clusters protected by tiopronin and coenzyme A monolayers, Langmuir, 15, 66, 10.1021/la9808420 Cliffel, 2000, Mercaptoammonium-monolayer-protected, water-soluble gold, silver, and palladium clusters, Langmuir, 16, 9699, 10.1021/la000922f Marin, 2008, Photochemical strategies for the synthesis of gold nanoparticles from Au(III) and Au(I) using photoinduced free radical generation, J. Am. Chem. Soc., 130, 16572, 10.1021/ja803490n Patel, 2008, Potassium ion recognition by facile dithiocarbamate assembly of benzo-15-crown-5-gold nanoparticles, Chem. Commun., 1849 Lee, 1982, Adsorption and surface-enhanced Raman of dyes on silver and gold sols, J. Phys. Chem., 86, 3391, 10.1021/j100214a025 Pillai, 2004, What factors control the size and shape of silver nanoparticles in the citrate ion reduction method?, J. Phys. Chem. B, 108, 945, 10.1021/jp037018r Henglein, 1999, Formation of colloidal silver nanoparticles: capping action of citrate, J. Phys. Chem. B, 103, 9533, 10.1021/jp9925334 Creighton, 1979, Plasma resonance enhancement of Raman scattering by pyridine adsorbed on silver or gold sol particles of size comparable to the excitation wavelength, J. Chem. Soc. Faraday Trans. II, 75, 790, 10.1039/f29797500790 Wang, 2002, Polyelectrolyte multilayer nanoreactors for preparing silver nanoparticle composites: controlling metal concentration and nanoparticle size, Langmuir, 18, 3370, 10.1021/la015725a Malynych, 2003, Vacuum deposition of silver island films on chemically modified surfaces, J. Vac. Sci. Technol. A, 21, 723, 10.1116/1.1570837 Mafuné, 2000, Structure and stability of silver nanoparticles in aqueous solution produced by laser ablation, J. Phys. Chem. B, 104, 8333, 10.1021/jp001803b Abid, 2002, Preparation of silver nanoparticles in solution from a silver salt by laser irradiation, Chem. Commun., 7, 792, 10.1039/b200272h Zhu, 2000, Shape-controlled synthesis of silver nanoparticles by pulse sonoelectrochemical methods, Langmuir, 16, 6396, 10.1021/la991507u Preuss, 2008, Comparing metabolic effects of six different commercial trivalent chromium compounds, J. Inorg. Biochem., 102, 1986, 10.1016/j.jinorgbio.2008.07.012 Oszlanczi, 2010, Functional neurotoxicity of Mn-containing nanoparticles in rats, Ecotoxicol. Environ. Safe, 73, 2004, 10.1016/j.ecoenv.2010.09.002 Gharehbaghi, 2009, Cold-induced aggregation microextraction based on ionic liquids and fiber optic-linear array detection spectrophotometry of cobalt in water samples, J. Hazard. Mater., 165, 1049, 10.1016/j.jhazmat.2008.10.128 Mulrooney, 2003, You have free access to this content, nickel uptake and utilization by microorganisms, FEMS Microbiol. Rev., 27, 239, 10.1016/S0168-6445(03)00042-1 Rozga, 2010, A Direct determination of the dissociation constant for the Cu(II) complex of amyloid β 1–40 peptide, Chem. Res. Toxicol., 23, 336, 10.1021/tx900344n Ratte, 1999, Bioaccumulation and toxicity of silver compounds: a review, Environ. Toxicol. Chem., 18, 89, 10.1002/etc.5620180112 Burdette, 2003, Meeting of the minds: metalloneurochemistry, Proc. Natl. Acad. Sci. U. S. A., 100, 3605, 10.1073/pnas.0637711100 Templeton, 2010, Multiple roles of cadmium in cell death and survival, Chem. Biol. Interact., 188, 267, 10.1016/j.cbi.2010.03.040 Martínez-Mañez, 2003, Fluorogenic and chromogenic chemosensors and reagents for anions, Chem. Rev., 103, 4419, 10.1021/cr010421e Darbre, 2006, Metalloestrogens: an emerging class of inorganic xenoestrogens with potential to add to the oestrogenic burden of the human breast, J. Appl. Toxicol., 26, 191, 10.1002/jat.1135 Needleman, 2004, Lead poisoning, Annu. Rev. Med., 55, 209, 10.1146/annurev.med.55.091902.103653 Mohan, 2007, Arsenic removal from water/wastewater using adsorbents – a critical review, J. Hazard. Mater., 142, 1, 10.1016/j.jhazmat.2007.01.006 Baxter, 1997, The determination of the authenticity of wine from its trace element composition, Food Chem., 60, 443, 10.1016/S0308-8146(96)00365-2 Gowenlock, 2002, 601 Machata, 1988, 97 2012 Murphy, 2008, Chemical sensing and imaging with metallic nanorods, Chem. Commun., 544, 10.1039/B711069C Obare, 2002, Sensing strategy for lithium ion based on gold nanoparticles, Langmuir, 18, 10407, 10.1021/la0260335 Liu, 2004, Colorimetric biosensors based on DNAzyme-assembled gold nanoparticles, Fluorescence, 14, 343, 10.1023/B:JOFL.0000031816.06134.d3 Pearson, 1963, Hard and soft acids and bases, J. Am. Chem. Soc., 85, 3533, 10.1021/ja00905a001 Chen, 2013, A simple colorimetric sensor for potassium ion based on DNA G-quadruplex conformation and salt-induced gold nanoparticles aggregation, Anal. Chim. Acta, 787, 189, 10.1016/j.aca.2013.05.020 Kim, 2009, Bioinspired colorimetric detection of Calcium(II) ions in serum using calsequestrin-functionalized gold nanoparticles, Angew. Chem. Int. Ed., 48, 4138, 10.1002/anie.200900071 Kim, 2011, A colorimetric selective sensing probe for calcium ions with tunable dynamic ranges using cytidine triphosphate stabilized gold nanoparticles, Chem. Commun., 47, 10299, 10.1039/c1cc13489b Zhang, 2011, Specifically colorimetric recognition of calcium, strontium, and barium ions using 2-mercaptosuccinic acid-functionalized gold nanoparticles and its use in reliable detection of calcium ion in water, Analyst, 136, 3865, 10.1039/c1an15175d Lai, 2011, Role of 5-thio-(2-nitrobenzoic acid)-capped gold nanoparticles in the sensing of chromium(VI): remover and sensor, Analyst, 136, 2712, 10.1039/c1an15162b Tan, 2011, Selective detection of nanomolar Cr(VI) in aqueous solution based on 1,4-dithiothreitol functionalized gold nanoparticles, Anal. Methods, 3, 343, 10.1039/C0AY00534G Zhao, 2012, Novel, highly selective detection of Cr(III) in aqueous solution based on a gold nanoparticles colorimetric assay and its application for determining Cr(VI), Anal. Chim. Acta, 731, 75, 10.1016/j.aca.2012.04.022 Hughes, 2013, Sensitive and selective detection of trivalent chromium using hyper Rayleigh scattering with 5,5′-dithio-bis-(2-nitrobenzoic acid)-modified gold nanoparticles, Sens. Actuators B, 178, 514, 10.1016/j.snb.2012.12.003 Sugunan, 2005, Heavy-metal ion sensors using chitosan-capped gold nanoparticles, Sci. Technol. Adv. Mater., 6, 335, 10.1016/j.stam.2005.03.007 Liu, 2011, A gold nanorod based colorimetric probe for the rapid and selective detection of Cu2+ ions, Analyst, 136, 3904, 10.1039/c1an15460e Weng, 2013, Self-assembly of core-satellite gold nanoparticles for colorimetric detection of copper ions, Anal. Chim. Acta, 803, 128, 10.1016/j.aca.2013.09.036 Wu, 2011, Colorimetric detection of Fe3+ ions using pyrophosphate functionalized gold nanoparticles, Analyst, 136, 1887, 10.1039/c1an15028f Zhang, 2011, A colorimetric assay method for Co2+ based on thioglycolic acid functionalized hexadecyl trimethyl ammonium bromide modified Aunanoparticles (NPs), Nanoscale, 3, 2150, 10.1039/c1nr10149h Patel, 2013, 4-Aminothiophenol functionalized gold nanoparticles as colorimetric sensors for the detection of cobalt using UV–visible spectrometry, Res. Chem. Intermed., 39, 771, 10.1007/s11164-012-0773-9 Krpetic, 2012, Importance of nanoparticle size in colorimetric and SERS-based multimodal trace detection of Ni(II) ions with functional gold nanoparticles, Small, 8, 707, 10.1002/smll.201101980 Fu, 2012, Aggregation of glutathione-functionalized Au nanoparticles induced by Ni2+ ions, J. Nanopart. Res., 14, 929, 10.1007/s11051-012-0929-y Haghnazar, 2013, Simple optical determination of silver ion in aqueous solutions using benzo crown-ether modified gold nanoparticles, Microchim. Acta, 180, 287, 10.1007/s00604-012-0928-9 Sung, 2014, Highly selective and sensitive colorimetric detection of Ag(I) using N-1-(2-mercaptoethyl)adenine functionalized gold nanoparticles, Sens. Actuators B, 197, 172, 10.1016/j.snb.2014.02.044 Xue, 2011, Colorimetric detection of Cd2+ using gold nanoparticles cofunctionalized with 6-mercaptonicotinic acid and l-cysteine, Analyst, 136, 3725, 10.1039/c1an15238f Wang, 2013, Sensitive and selective colorimetric detection of cadmium(II) using gold nanoparticles modified with 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole, Microchim. Acta, 180, 1051, 10.1007/s00604-013-1030-7 Yin, 2011, SERS-active nanoparticles for sensitive and selective detection of cadmium ion (Cd2+), Chem. Mater., 23, 4756, 10.1021/cm201791r Oliveira, 2011, Novel small stable gold nanoparticles bearing fluorescent cysteine-coumarin probes as new metal-modulated chemosensors, Inorg. Chem., 50, 8797, 10.1021/ic200664z Oliveira, 2011, Bioinspired systems for metal-ion sensing: new emissive peptide probes based on benzo[d]oxazole derivatives and their gold and silica nanoparticles, Inorg. Chem., 50, 8834, 10.1021/ic200792t Oliveira, 2012, From colorimetric chemosensors to metal nanoparticles using two new tyrosine Schiff-base ligands for Cu2+ detection, Inorg. Chim. Acta, 380, 22, 10.1016/j.ica.2011.08.034 Brust, 1994, Synthesis of thiol-derivatised gold nanoparticles in a two-phase liquid–liquid system, J. Chem. Soc., Chem. Comm., 801, 10.1039/C39940000801 Battistini, 2008, The erratic emission of pyrene on gold nanoparticles, ACS Nano, 2, 77, 10.1021/nn700241w Fernández-Lodeiro, 2013, 1D chain fluorescein-functionalized gold and silver nanoparticles as new optical mercury chemosensor in aqueous media, J. Nanopart. Res., 15, 1828, 10.1007/s11051-013-1828-6 Fernández-Lodeiro, 2013, Polyamine ligand-mediated self-assembly of gold and silver nanoparticles into chainlike structures in aqueous solution: towards new nanostructured chemosensors, ChemistryOpen, 2, 200, 10.1002/open.201300023 Tanaka, 2007, 15N–15N J-coupling across HgII: direct observation of HgII-mediated T–T base pairs in a DNA duplex, J. Am. Chem. Soc., 129, 244, 10.1021/ja065552h Xu, 2009, Colorimetric detection of mercury ion (Hg2+) based on DNA oligonucleotides and unmodified gold nanoparticles sensing system with a tunable detection range, Biosens. Bioelectron., 24, 3153, 10.1016/j.bios.2009.03.025 Liu, 2010, Visual detection of Hg2+ with high selectivity using thymine modified gold nanoparticles, Anal. Sci., 26, 1169, 10.2116/analsci.26.1169 Chen, 2011, N-1-(2-Mercaptoethyl)thymine modification of gold nanoparticles: a highly selective and sensitive colorimetric chemosensor for Hg2+, Analyst, 136, 4770, 10.1039/c1an15585g Liu, 2010, Highly sensitive, colorimetric detection of mercury(II) in aqueous media by quaternary ammonium group-capped gold nanoparticles at room temperature, Anal. Chem., 82, 9606, 10.1021/ac1021503 Chen, 2011, Coordination of mercury(II) to gold nanoparticle associated nitrotriazole towards sensitive colorimetric detection of mercuric ion with a tunable dynamic range, Analyst, 136, 1690, 10.1039/c0an00903b Du, 2011, Flexible colorimetric detection of mercuric ion by simply mixing nanoparticles and oligopeptides, Small, 7, 1407, 10.1002/smll.201002270 Chansuvarn, 2012, Visual and colorimetric detection of mercury(II) ion using gold nanoparticles stabilized with a dithia–diaza ligand, Microchim. Acta, 176, 57, 10.1007/s00604-011-0691-3 Chai, 2010, l-Cysteine functionalized gold nanoparticles for the colorimetric detection of Hg2+ induced by ultraviolet light, Nanotechnology, 21, 025501, 10.1088/0957-4484/21/2/025501 Placido, 2013, Assembly of gold nanorods for highly sensitive detection of mercury ions, IEEE Sens. J., 13, 2834, 10.1109/JSEN.2013.2257738 Li, 2011, Highly selective and sensitive visualizable detection of Hg2+ based on anti-aggregation of gold nanoparticles, Talanta, 84, 508, 10.1016/j.talanta.2011.01.037 Yang, 2011, A simple and cost-effective sensing strategy of mercury (II) based on analyte-inhibited aggregation of gold nanoparticles, Nanotechnology, 22, 275503, 10.1088/0957-4484/22/27/275503 Lou, 2012, A simple and sensitive colorimetric method for detection of mercury ions based on anti-aggregation of gold nanoparticles, Anal. Methods, 4, 488, 10.1039/c2ay05764f Li, 2014, Selective and sensitive colorimetric sensor of mercury (II) based on gold nanoparticles and 4-mercaptophenylboronic acid, Sens. Actuators B: Chem., 196, 106, 10.1016/j.snb.2014.01.060 Wu, 2011, Colorimetric assay for mercury (II) based on mercury-specific deoxyribonucleic acid-functionalized gold nanoparticles, Anal. Chim. Acta, 694, 115, 10.1016/j.aca.2011.02.045 Kim, 2007, Dissecting metal ion-dependent folding and catalysis of a single DNAzyme, Nat. Chem. Biol., 3, 763, 10.1038/nchembio.2007.45 Wang, 2008, Label-free colorimetric detection of lead ions with a nanomolar detection limit and tunable dynamic range by using gold nanoparticles and DNAzyme, Adv. Mater., 20, 3263, 10.1002/adma.200703181 Liu, 2007, Colorimetric Cu2+ detection with a ligation DNAzyme and nanoparticles, Chem. Commun., 4872, 10.1039/b712421j Liu, 2006, Preparation of aptamer-linked gold nanoparticle purple aggregates for colorimetric sensing of analytes, Nat. Protoc., 1, 246, 10.1038/nprot.2006.38 Li, 2008, Optical analysis of Hg2+ ions by oligonucleotide-gold-nanoparticle hybrids and DNA-based machines, Angew. Chem. Int. Ed., 47, 3927, 10.1002/anie.200705991 Alizadeh, 2010, Rapid and selective lead (II) colorimetric sensor based on azacrown ether-functionalized gold nanoparticles, Nanotechnology, 21, 315503, 10.1088/0957-4484/21/31/315503 Huang, 2010, Sensitivity enhancement in the colorimetric detection of lead(II) ion using gallic acid-capped gold nanoparticles: improving size distribution and minimizing interparticle repulsion, Biosens. Bioelectron., 25, 984, 10.1016/j.bios.2009.09.006 Xu, 2012, A colorimetric method for the determination of lead(II) ions using gold nanoparticles and a guanine-rich oligonucleotide, Microchim. Acta, 177, 89, 10.1007/s00604-011-0744-7 Zhu, 2012, A FRET ratiometric fluorescence sensing system for mercury detection and intracellular colorimetric imaging in live Hela cells, Biosens. Bioelectron., 31, 499 Zhang, 2013, The colorimetric detection of Pb2+ by using sodium thiosulfate andhexadecyl trimethyl ammonium bromide modified gold nanoparticles, Dalton Trans., 42, 5485, 10.1039/c3dt32532f Li, 2010, Gold nanoparticle-based colorimetric assay for selective detection ofaluminium cation on living cellular surfaces, Chem. Commun., 46, 988, 10.1039/B920135A Chen, 2013, Colorimetric detection of Al3+ ions using triazole-ether functionalized gold nanoparticles, Talanta, 117, 70, 10.1016/j.talanta.2013.08.054 Xue, 2014, Specific and sensitive colorimetric detection of Al3+ using 5-mercaptomethyltetrazole capped gold nanoparticles in aqueous solution, Talanta, 119, 306, 10.1016/j.talanta.2013.11.012 Xia, 2012, Simple, rapid and label-free colorimetric assay for arsenic based on unmodified gold nanoparticles and a phytochelatin-like peptide, Anal. Methods, 4, 3937, 10.1039/c2ay25803j Wu, 2012, Ultrasensitive aptamer biosensor for arsenic(III) detection in aqueous solution based on surfactant-induced aggregation of gold nanoparticles, Analyst, 137, 4171, 10.1039/c2an35711a Li, 2010, Synthesis of aza-crown ether-modified silver nanoparticles as colorimetric sensors for Ba2+, Supramol. Chem., 22, 544, 10.1080/10610278.2010.497209 Wu, 2010, Highly selective light scattering imaging of chromium (III) in living cells with silver nanoparticles, Anal. Bioanal. Chem., 397, 1273, 10.1007/s00216-010-3619-6 Ravindran, 2012, Selective colorimetric detection of nanomolar Cr (VI) in aqueous solutions using unmodified silver nanoparticles, Sens. Actuators B, 166, 365, 10.1016/j.snb.2012.02.073 Wu, 2013, Colorimetric determination of hexavalent chromium with ascorbic acid capped silver nanoparticles, Anal. Methods, 5, 560, 10.1039/C2AY25989C Zhou, 2012, Colorimetric detection of Mn2+ using silver nanoparticles cofunctionalized with 4-mercaptobenzoic acid and melamine as a probe, Talanta, 97, 331, 10.1016/j.talanta.2012.04.041 Gao, 2013, A new rapid colorimetric detection method of Mn2+ based on tripolyphosphate modified silver nanoparticles, Sens. Actuators B, 181, 288, 10.1016/j.snb.2013.01.079 Zhan, 2012, Synthesis of a pyridyl-appended calix[4]arene and its application to the modification of silver nanoparticles as an Fe3+ colorimetric sensor, New J. Chem., 36, 656, 10.1039/C2NJ20776A Pandya, 2013, A novel calix[4]arene thiol functionalized silver nanoprobe for selective recognition of ferric ion with nanomolar sensitivity via DLS selectivity in human biological fluid, Nanoscale, 5, 2364, 10.1039/c3nr33119a Yao, 2010, Cooperative binding of bifunctionalized and click-synthesized silver nanoparticles for colorimetric Co2+ sensing, ACS Appl. Mater. Interfaces, 2, 684, 10.1021/am900741h Mehta, 2013, Dopamine dithiocarbamate functionalized silver nanoparticles as colorimetric sensors for the detection of cobalt ion, Anal. Methods, 5, 1818, 10.1039/c3ay26150f Sung, 2013, Colorimetric detection of Co2+ ion using silver nanoparticles with spherical, plate, and rod shapes, Langmuir, 29, 8978, 10.1021/la401408f Shang, 2012, Highly selective colorimetric assay for nickel ion using N-acetyl-l-cysteine-functionalized silver nanoparticles, J. Nanopart. Res., 14, 1169, 10.1007/s11051-012-1169-x Ratnarathorn, 2012, Simple silver nanoparticle colorimetric sensing for copper by paper-based devices, Talanta, 99, 552, 10.1016/j.talanta.2012.06.033 Dou, 2013, Homocysteine-functionalized silver nanoparticles for selective sensing of Cu2+ ions and Lidocaine hydrochloride, Colloids Surf. A: Physicochem. Eng. Asp., 423, 20, 10.1016/j.colsurfa.2013.01.027 Ma, 2011, Colorimetric detection of copper ions in tap water during the synthesis of silver/dopamine nanoparticles, Chem. Commun., 47, 12643, 10.1039/c1cc15048k Li, 2009, Triazole-ester modified silver nanoparticles: click synthesis and Cd2+ colorimetric sensing, Chem. Commun., 4812, 10.1039/b908761c Fan, 2009, Synthesis of starch-stabilized Ag nanoparticles and Hg2+ recognition in aqueous media, Nanoscale Res. Lett., 4, 1230, 10.1007/s11671-009-9387-6 Wang, 2012, Ultrasensitive and dual functional colorimetric sensors for mercury (II) ions and hydrogen peroxide based on catalytic reduction property of silver nanoparticles, Biosens. Bioelectron., 31, 337, 10.1016/j.bios.2011.10.041 Manivannan, 2013, Silver nanoparticles embedded in cyclodextrin–silicate composite and their applications in Hg(II) ion and nitrobenzene sensing, Analyst, 138, 1733, 10.1039/c3an36488g Rameshkumar, 2013, Silver nanoparticles deposited on amine-functionalized silica spheres and their amalgamation-based spectral and colorimetric detection of Hg(II) ions, J. Nanopart. Res., 15, 1639, 10.1007/s11051-013-1639-9 Bera, 2010, Enzyme-cofactor-assisted photochemical synthesis of Ag nanostructures and shape-dependent optical sensing of Hg(II) ions, Chem. Mater., 22, 4505, 10.1021/cm1013762 Chen, 2013, Highly sensitive and selective colorimetric sensing of Hg2+ based on the morphology transition of silver nanoprisms, ACS Appl. Mater. Interfaces, 5, 284, 10.1021/am3020857 Apilux, 2012, Simple and rapid colorimetric detection of Hg(II) by a paper-based device using silver nanoplates, Talanta, 97, 388, 10.1016/j.talanta.2012.04.050 Farhadi, 2012, Highly selective Hg2+ colorimetric sensor using green synthesized and unmodified silver nanoparticles, Sens. Actuators B, 161, 880, 10.1016/j.snb.2011.11.052 Ravi, 2013, Green synthesized silver nanoparticles for selective colorimetric sensing of Hg2+ in aqueous solution at wide pH range, Analyst, 138, 4370, 10.1039/c3an00320e Gao, 2013, Old tree with new shoots: silver nanoparticles for label-free and colorimetric mercury ions detection, J. Nanopart. Res., 15, 1385, 10.1007/s11051-012-1385-4 Ramesh, 2011, A universal sensor for mercury (Hg, HgI, HgII) based on silver nanoparticle-embedded polymer thin film, ACS Appl. Mater. Interfaces, 3, 988, 10.1021/am200023w Lodeiro, 2010, Light and color as analytical detection tools: a journey into the periodic table using polyamines to bio-inspired systems as chemosensors, Chem. Soc. Rev., 39, 2948, 10.1039/b819787n Fernández-Lodeiro, 2013, Steady-state and time-resolved investigations on pyrene-based chemosensors, Inorg. Chem., 52, 121, 10.1021/ic301365y Ovejero, 2013, Silver-pyrazole complexes as hybrid multifunctional materials with metallomesogenic and photoluminescent behaviour, Dalton Trans., 42, 2107, 10.1039/C2DT31750H Fernández-Lodeiro, 2012, Novel emissive podands based on 8-OH-quinoline: synthesis, fluorescence materials, DFT and complexation studies, Inorg. Chim. Acta, 381, 218, 10.1016/j.ica.2011.09.018 Oliveira, 2011, Bioinspired systems for metal-ion sensing: new emissive peptide probes based on benzo[d]oxazole derivatives and their gold and silica nanoparticles, Inorg. Chem., 50, 8834, 10.1021/ic200792t Oliveira, 2011, Novel small stable gold nanoparticles bearing fluorescent cysteine-coumarin probes as new metal-modulated chemosensors, Inorg. Chem., 50, 8797, 10.1021/ic200664z López-Cortés, 2012, Fast human serum profiling through chemical depletion coupled to gold-nanoparticle-assisted protein separation, Talanta, 100, 239, 10.1016/j.talanta.2012.08.020 Fernández-Lodeiro, 2013, 1D chain fluorescein-functionalized gold and silver nanoparticles as new optical mercury chemosensor in aqueous media, J. Nanopart. Res., 15, 1828, 10.1007/s11051-013-1828-6 Wang, 2010, Colorimetric detection of mercury(II) ion using unmodified silver nanoparticles and mercury-specific oligonucleotides, ACS Appl. Mater. Interfaces, 2, 339, 10.1021/am9007243 Fernández-Lodeiro, 2013, Polyamine ligand-mediated self-assembly of gold and silver nanoparticles into chainlike structures in aqueous solution: towards new nanostructured chemosensors, ChemistryOpen, 2, 200, 10.1002/open.201300023 Duan, 2014, Facile colorimetric detection of Hg2+ based on anti-aggregation of silver nanoparticles, Biosens. Bioelectron., 57, 139, 10.1016/j.bios.2014.02.007 Zhang, 2012, Mononucleotide-modified metal nanoparticles: an efficient colorimetric probe for selective and sensitive detection of aluminum(III) on living cellular surfaces, Chem. Euro. J., 18, 2507, 10.1002/chem.201102529 Qi, 2012, Colorimetric detection of lead(II) based on silver nanoparticles capped with iminodiacetic acid, Microchim. Acta, 178, 221, 10.1007/s00604-012-0832-3 Cao, 2013, Dithiocarbamate-capped silver nanoparticles as a resonance light scattering probe for simultaneous detection of lead(II) ions and cysteine, Analyst, 138, 2420, 10.1039/c3an36868h Fan, 2011, A review on the fabrication of substrates for surface enhanced Raman spectroscopy and their applications in analytical chemistry, Anal. Chim. Acta, 693, 7, 10.1016/j.aca.2011.03.002 Li, 2011, Highly sensitive SERS detection of As3+ ions in aqueous media using glutathione functionalized silver nanoparticles, ACS Appl. Mater. Interfaces, 3, 3936, 10.1021/am200810x Dulkeith, 2004, Plasmon emission in photoexcited gold nanoparticles, Phys. Rev. B, 70, 205424, 10.1103/PhysRevB.70.205424 Link, 2002, Visible to infrared luminescence from a 28-atom gold cluster, J. Phys. Chem. B, 106, 3410, 10.1021/jp014259v Wang, 2005, Near-IR luminescence of monolayer-protected metal clusters, J. Am. Chem. Soc., 127, 812, 10.1021/ja0452471 Wang, 2006, NIR luminescence intensities increase linearly with proportion of polar thiolate ligands in protecting monolayers of Au38 and Au140 quantum dots, J. Phys. Chem. B, 110, 20282, 10.1021/jp0640528 Montalti, 2007, Enhanced sensitized NIR luminescence from gold nanoparticles via energy transfer from surface-bound fluorophores, J. Am. Chem. Soc., 129, 2418, 10.1021/ja068095d Velu, 2010, Colorimetric and fluorometric chemosensors for selective signaling toward Ca2+ and Mg2+ by aza-crown ether acridinedione-functionalized gold nanoparticles, Tetrahedron Lett., 51, 4331, 10.1016/j.tetlet.2010.06.041 Muhammed, 2010, Luminescent quantum clusters of gold in bulk by albumin-induced core etching of nanoparticles: metal ion sensing, metal-enhanced luminescence, and biolabeling, Chem. Euro. J., 16, 10103, 10.1002/chem.201000841 Zhang, 2013, Glutathione-protected fluorescent gold nanoclusters for sensitive and selective detection of Cu2+, Sens. Actuators B: Chem., 183, 583, 10.1016/j.snb.2013.04.023 Chen, 2009, Fluorescent gold nanoparticles-based fluorescence sensor for Cu2+ ions, Chem. Commun., 1736, 10.1039/b820145e Huang, 2006, Selective gold-nanoparticle-based “turn-on” fluorescent sensors for detection of mercury(II) in aqueous solution, Anal. Chem., 78, 8332, 10.1021/ac061487i Darbha, 2007, Gold nanoparticle-based miniaturized nanomaterial surface energy transfer probe for rapid and ultrasensitive detection of mercury in soil, water, and fish, ACS Nano, 1, 208, 10.1021/nn7001954 Pyne, 2011, FRET based ultra sensor for detection of Hg (II) in water: a comparative study using citrate and marcapto propanoic acid as stabilizer of AuNPs, Sens. Actuators B, 160, 1141, 10.1016/j.snb.2011.09.039 Lee, 2007, Colorimetric detection of mercuric ion (Hg2+) in aqueous media using DNA-functionalized gold nanoparticles, Angew. Chem. Int. Ed., 46, 4093, 10.1002/anie.200700269 Liu, 2008, Detection of mercury(II) based on Hg2+-DNA complexes inducing the aggregation of gold nanoparticles, Chem. Commun., 2242, 10.1039/b719856f Liu, 2008, Control over surface DNA density on gold nanoparticles allows selective and sensitive detection of mercury(II), Langmuir, 24, 8346, 10.1021/la800589m Wang, 2008, Gold nanoparticle-based colorimetric and “turn-on” fluorescent probe for mercury(II) ions in aqueous solution, Anal. Chem., 80, 9021, 10.1021/ac801382k Huang, 2007, Synthesis of highly fluorescent gold nanoparticles for sensing mercury(II), Angew. Chem., 119, 6948, 10.1002/ange.200700803 Yuan, 2011, Functionalized fluorescent gold nanodots: synthesis and application for Pb2+ sensing, Chem Commun., 47, 11981, 10.1039/c1cc14872a Wu, 2013, Fluorescent detection of lead in environmental water and urine samples using enzyme mimics of catechin-synthesized Au nanoparticles, ACS Appl. Mater. Interfaces, 5, 1503, 10.1021/am3030454 Roy, 2012, The As-prepared gold cluster-based fluorescent sensor for the selective detection of AsIII ions in aqueous solution, Nanoscale, 4, 2734, 10.1039/c2nr11786j Sun, 2013, 11-Mercaptoundecanoic acid directed one-pot synthesis of water-soluble fluorescent gold nanoclusters and their use as probes for sensitive and selective detection of Cr3+ and Cr6+, J. Mater. Chem. C, 1, 138, 10.1039/C2TC00021K Tharmaraj, 2013, A highly selective ratiometric fluorescent chemosensor for Cu(II) based on dansyl-functionalized thiol stabilized silver nanoparticles, J. Mater. Chem. B, 1, 1962, 10.1039/c3tb00534h Liu, 2012, Fluorescent silver nanoclusters for user-friendly detection of Cu2+ on a paper platform, Analyst, 137, 2406, 10.1039/c2an35051c Shang, 2008, Silver nanocluster-based fluorescent sensors for sensitive detection of Cu(II), J. Mater. Chem., 18, 4636, 10.1039/b810409c Zhang, 2011, Label-free fluorescent detection of copper(II) using DNA-templated highly luminescent silver nanoclusters, Analyst, 136, 5139, 10.1039/c1an15891k Adhikari, 2010, Facile synthesis of water-soluble fluorescent silver nanoclusters and HgII sensing, Chem. Mater., 22, 4364, 10.1021/cm1001253 Wang, 2012, Fluorescent silver nanoclusters as effective probes for highly selective detection of mercury(II) at parts-per-billion levels, Chem. Asian J., 7, 1652, 10.1002/asia.201200033 Guo, 2011, Fluorescent Ag clusters via a protein-directed approach as a Hg(II) ion sensor, Anal. Chem., 83, 2883, 10.1021/ac1032403 Guo, 2009, Oligonucleotide-stabilized Ag nanoclusters as novel fluorescence probes for the highly selective and sensitive detection of the Hg2+ ion, Chem. Commun., 3395, 10.1039/b821518a Vasimalai, 2012, Ultrasensitive fluorescence-quenched chemosensor for Hg(II) in aqueous solution based on mercaptothiadiazole capped silver nanoparticles, J. Hazard. Mater., 213–214, 193, 10.1016/j.jhazmat.2012.01.079 Tyagi, 2012, Inorganic–organic Ag-rhodamine 6G hybrid nanorods: “Turn on” fluorescent sensors for highly selective detection of Pb2+ ions in aqueous solution, Analyst, 137, 760, 10.1039/C1AN15604G Tharmaraj, 2011, Alginate stabilized silver nanocube-Rh6G composite as a highly selective mercury sensor in aqueous solution, Nanoscale, 3, 1166, 10.1039/c0nr00749h Roy, 2011, Selective colorimetric sensing of mercury(II) using turn off-turn on mechanism from riboflavin stabilized silver nanoparticles in aqueous medium, Analyst, 136, 3605, 10.1039/c1an15459a Tao, 2012, Poly(acrylic acid)-templated silver nanoclusters as a platform for dual fluorometric turn-on and colorimetric detection of mercury (II) ions, Talanta, 88, 290, 10.1016/j.talanta.2011.10.043 Fernández-Lodeiro, 2014, New-coated fluorescent silver nanoparticles with a fluorescein thiol esther derivative: fluorescent enhancement upon interaction with heavy metal ions, J. Nanopart. Res., 16, 2315, 10.1007/s11051-014-2315-4 Lou, 2011, Colorimetric detection of trace copper ions based on catalytic leaching of silver-coated gold nanoparticles, ACS Appl. Mater. Interfaces, 3, 4215, 10.1021/am2008486 Gui, 2013, Aqueous synthesis of human serum albumin-stabilized fluorescent Au/Ag core/shell nanocrystals for highly sensitive and selective sensing of copper(II), Analyst, 138, 7197, 10.1039/c3an01397a Guha, 2011, Fluorescent Au@Ag core-shell nanoparticles with controlled shell thickness and HgII sensing, Langmuir, 27, 13198, 10.1021/la203077z