Seawater Sulfur Isotope Fluctuations in the Cretaceous

American Association for the Advancement of Science (AAAS) - Tập 304 Số 5677 - Trang 1663-1665 - 2004
Adina Paytan1,2, Miriam Kastner1,2, Douglas A. Campbell1,2, M. H. Thiemens1,2
1Department of Geological and Environmental Sciences, Stanford University, Stanford, CA 94305 2115, USA
2University of California, San Diego, La Jolla, CA 92093, USA.

Tóm tắt

The exogenic sulfur cycle is tightly coupled with the carbon and oxygen cycles, and therefore a central component of Earth's biogeochemistry. Here we present a high-resolution record of the sulfur isotopic composition of seawater sulfate for the Cretaceous. The general enrichment of isotopically light sulfur that prevailed during the Cretaceous may have been due to increased volcanic and hydrothermal activity. Two excursions toward isotopically lighter sulfur represent periods of lower rates of pyrite burial, implying a shift in the location of organic carbon burial to terrestrial or open-ocean settings. The concurrent changes in seawater sulfur and inorganic carbon isotopic compositions imply short-term variability in atmospheric oxygen partial pressure.

Từ khóa


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The authors thank L. Kump for discussion and comments. Samples provided by the Ocean Drilling Program. The work was supported by an NSF grant to A.P.