Mechanochemistry of Solids: Past, Present, and Prospects
Tóm tắt
A historical retrospective is presented beginning from the early observations by alchemists to the establishment of mechanochemistry as a branch of science. The changes in structure and chemical properties of solids under three-axes loading and by combined action of pressure and shift are demonstrated. The peculiarities of the phenomena taking place upon stressing of particle assemblies in various types of energy-intensive grinding mills are discussed. Based on the contemporary concepts, the mechanism of stress field formation and relaxation is analyzed. Among decisive factors influencing the mechanochemical synthesis, the formation and renewal of contact area between reacting compounds, the explosive evolution of heat, and the feedback phenomenon are emphasized. The perspective directions of practical application in the area known as mechanical alloying, as well as in preparation of functional ceramics and catalysts, and in pharmacy are discussed. The main directions for improving research, construction of milling devices, training of specialists, and exchange of knowledge are proposed.
Tài liệu tham khảo
W. Ostwald, Lehrbuch der Allgemeinen Chemie, Bd.2 Stöchiometrie (Engelmann, Leipzig, 1891), 1163 S.
M. Carey Lea, Phil. Mag. 34, 46 (1892).
M. Carey Lea, Amer. J. Sci. 46, 413 (1893).
L. Takacs, J. Minerals Met. Mater. Soc. 52, 12 (2000).
F. M. Flavitsky, Russ. Zh. Phyz. Khim. 34, 8 (1902).
L. H. Parker, J. Chem. Soc. 105, 1504 (1914); J. Chem. Soc. 113, 396 (1918).
G. Tammann, Textbook of Metallurgy, vol. 4, Auflage. (Voss, Leipzig, 1932).
G. Tammann, and R. Kohlhaus, Z. Anorg. Allgem. Chem. 199, 209 (1931).
J. Cohen and W. Schmidt, Piezochemie, Kondensierten Systems (Akademie-Verlig, Leipzig, 1919).
P. W. Bridgeman, Rev. Modern Phys. 18, 1 (1946).
H. Muraur, Arfller. Fr. 12, 559 (1933).
F. P. Bowden, and D. Tabor, The Friction and Lubrication of Solids (Clarendon Press, Oxford, 1958), 372 p.
F. Bowden and A. Yoffe, Initiation and Growth of Explosion in Liquids and Solids (Cambridge Univ. Press, Cambridge, 1952), 104 p.
F. P. Bowden and A. Yoffe, Fast Reactions in Solids (Butterworths, London, 1958), 163 p.
N. A. Holevo, Proc. Kirov Inst. Chem. Technol. Kazan. 10, 91 (1946).
P. Wanetig, Textilforschung 4, 154 (1922), Texilforschung. 3, 66 (1925).
P. Wanetig, Kolloid Z. 41, 152 (1927).
H. Staudinger and E. Dreher, Ber. Deut. Chem. Ges. A 69, 1901 (1936).
K. Hess, E. Steurer, and E. Fromm, Kolloid Z. 98, 209 (1942).
A. A. Berlin, Uspekhi Khim. 27, 94 (1958).
P. Yu. Butyagin, Visokomolekulyarniye Soedineniya 9A, 136 (1967).
N. K. Baramboim, Mechanochemistry of Macromolecular Substances (Moscow, Khimiya, 1970), p. 357.
K. Simionesku, and K. Oprea, Mechanochemistry of Macromolecular Compounds, (Mir, Moskva, 1971), p. 357.
J. Clark, and R. J. Rovan, J. Amer. Chem. Soc. 63, 1302 (1941).
K. Peters and W. Cremer, Z. Angew. Chem. 47, 576 (1934).
K. Peters, in Proceedings of the 1st European Symposium on Comminution, H. Rumpf, ed. (Dechema Monographien, Frankfurt, 1962), p. 31.
A. H. Cottrell, The Mechanical Properties of Matter (Wiley, New York, 1964), pp. 78–98.
V. A. Karasev, N. A. Krotova, and B. V. Deryagin, Dokl. Akad. Nauk SSSR 88, 777 (1953).
P. A. Rebinder, in Proceedings of the Jubilee Session of the Academy of Sciences of USSR (Izdat. Akademii Nauk SSSR, Moskva, 1947), p. 55.
G. S. Khodakov and P. A. Rebinder, Dokl. Akad. Nauk SSSR 83, 1316 (1966).
P. A. Thiessen, K. Meyer, and G. Heinicke, Grundlagen der Tribochemie (Akademie-Verlag, Berlin, 1967).
R. Schaider and G. Tetzner, Z. Anorg. Allg. Chem. 309, 55 (1961).
T. Kubo, J. Chem. Soc. Jpn. Ind. Sec. 71, 1301 (1968).
T. J. Lin, S. Nadiv, and J. Grodzian. Mater. Sci. Eng. 7, 313 (1975).
V. V. Boldyrev and E. G. Avvakumov, Russ. Chem. Rev. 40, 847 (1971).
P. J. Butyagin, Russ. Chem. Rev. 40, 1935 (1971).
I. Hint, On Basic Problems of Mechanical Activation (Stroiizdat, Tallin, 1977).
V. V. Boldyrev and Klaus Meyer, Festkörperchemie, Beiträge aus Forschug und Praxis. (VEB Deutscher Verlag für Grundstoffindustrie, Leipzig, 1973).
G. Heinicke, Tribochemistry (Akademie-Verlag, Berlin, 1984), p. 495.
E. G. Avvakumov, Mechanicheskie Metody Activazii Chimicheskikh Prozessov (Izd. Nauka, Novosibirsk, 1986), p. 305.
K. Tkáčová, Mechanical Activation of Minerals (Elsevier, Amsterdam, 1989), p. 156.
C. Suryanarayana, ed., Non-Equilibrium Processing of Materials (Pergamon, Oxford, 1999).
K. F. Herzfeld, Phys. Rev. 29, 701 (1927).
N. F. Mott, Proc. Roy. Phys. Soc. A 62, 416 (1949).
A. Cottrell, Introduction to the Modern Theory of Metals (Institute of Metals, London, 1988), p. 260.
H. G. Drickhamer and C. W. Frank, Electronic Transition and High Pressure Chemistry and Physics of Solids (Chapman & Hall, London, 1973), p. 220.
C. D. Schmulbach, F. Dachille, and M. Bunoh, Inorg. Chem. 3, 808 (1964).
H. E. Le-May, in Comprehensive Coordination Chemistry, vol. 2, Wilkinson, ed. (Pergamon Press, Oxford, 1987), pp. 463–473.
E. V. Boldyreva, Mol. Crystallogr. Liq. Crystals Nonlinear Optics, 242, 17 (1994).
M. Rutkonen, R. Fold, C. Veller, and M. Lehmann, Acta Crystallogr. B41, 77 (1985).
E. Boldyreva, T. Shakhtscheneider, M. Vasilchenko, H. Ahsbahs, and H. Uchtmann, Acta Crystallogr. B56, 299 (2000).
E. V. Boldyreva, H. Ahsbahs, and H. Uchtmann, Ber. Bunseng. Phys. Chem. 98, 738 (1994).
E. Boldyreva, S. Kuzmina, and H. Ahsbahs, Russ. J. Struct. Chem. 39, 934 (1998).
E. Boldyreva and A. Sidel'nikov, Izv. Sib. Otd. Akad. Nauk. Ser. Khim., pp. 139–145 (1987).
H. Drickhamer and L. L. Brag, Intern. Rev. Phys. Chem. 8, 46 (1986).
E. S. Larsen and P. Bridgman, Amer. J. Sci. 36, 81 (1938).
P. Bridgman and I. Simon, J. Appl. Phys. 24, 405 (1953).
F. Dachille and R. Roy, in Reactivity of Solids, Proceedings of the 4th International Symposium on the Reactivity of Solids, van Bier, ed. (Elsevier, Amsterdam, 1961), pp. 502–510.
F. Dachille, and R. Roy, J. Geol. 72, 243 (1964).
R. Z. Zeto and R. Roy, in Reactivity of Solids, Proceedings of the 6th International Symposium on the Reactivity of Solids, J. W. Mitchell, ed. [Wiley (Interscience), New York, 1969], pp. 803–810.
A. A. Zharov, in High Pressure Chemistry and Physics of Polymers, E. Kowarsky, ed. (CRC) Press, Boca Raton, FL 1994), Chap. 7.
A. A. Zharov, Russ. Chem. Rev. 33, 236 (1984).
A. A. Politov, B. A. Fursenko, and V. V. Boldyrev, Dokl. Akad. Nauk. SSSR 371, 28–31 (2000).
V. V. Neverov and P. P. Zhitnikov, Izv. Vuzov. Phys., pp. 10–15 (1994).
V. V. Neverov, V. H. Burov, and P. P. Zhitnikov, Izv. Sib. Otd. Akad. Nauk. Ser. Khim. 5, 54 (1983).
A. E. Arinsshtein, Dokl. Akad. Nauk SSSR 364, 778 (1999).
J. J. Gilman, Czech. J. Phys. 45, 913 (1995).
J. J. Gilman, Science 274, 65 (1996).
J. J. Gilman, Phil. Mag. 67B, 207 (1993).
K. Tkáčová, H. P. Heegn, and N. Stevulová, Intern. J. Mineral Proc. 40, 17 (1993).
P. Yu. Butyagin, Russ. Chem. Rev. 63, 1031 (1994).
N. Z. Lyakhov, in Proceedings of the Second Japan-Soviet Symposium on Mechanochemistry, G. Jimbo, M. Senna, and Y. Kuwahara, eds. (Soc. Powder Technology Japan, Tokyo, 1988), pp. 59–62.
F. Kh. Urakaev and V. V. Boldyrev, Powder Technol. 107, 197 (2000).
T. H. Courtney, Mater. Trans. 36, 110 (1995).
Yu. T. Pavlukhin, Ya. Ya. Medikov, and V. V. Boldyrev, Izv. Sib. Otd. Akad. Nauk. 2, 3, (1983).
V. V. Boldyrev, Kinet. Cat. 13, 1411 (1972).
I. Lin and S. Nadiv, Mater. Sci. Eng. 39, 193 (1979).
E. Yu. Ivanov, I. G. Konstanchuk, and V. V. Boldyrev, Reactivity Solids 7, 167 (1989).
E. Yu. Ivanov, B. Bokhonov, and I. Konstanchuk, J. Mater. Sci. 6, 1440 (1990).
Yu. T. Pavlukhin, Ya. Ya. Medikov, and V. V. Boldyrev, Izv. Sib. Otd. Akad. Nauk. 5, 46 (1983).
A. E. Yermakov, E. E. Yurchikov, E. P. Ylsukov, V. A. Barinov, and Yu. G. Chukalkin, Fiz. Tverd. Tela. (Kharkov) 24, 1947 (1982).
Yu. T. Pavlukhin and V. V. Boldyrev, Rev. Solid State Sci. 2, 603 (1988).
Yu. T. Pavlukhin, and Ya. Ya. Medikov, J. Solid State Chem. 53, 155 (1984).
V. V. Boldyrev, O. V. Jakovleva, Ya. Ya. Medikov, and Y. T. Pavlukhin. Dokl. Akad. Nauk. SSSR 268, 636 (1983).
K. Tkačova, V. Šepelak, N. Števulova, and V. V. Boldyrev, J. Solid State Chem. 123, 100 (1996).
V. Šepelak, U. Steinike, D. Uecker, R. Tretin, S. Wismann, and K. D. Becker, Solid State Ionics 101, 1343 (1997).
V. V. Boldyrev, E. G. Avvakumov, H. Harenz, G. Heinicke, and L. I. Strugova, Z. Anorg. Allg. Chem. 393, 152 (1972).
V. V. Boldyrev and G. Heinicke, Z. Chem. 19, 353 (1979).
V. V. Boldyrev, Z. Phys. Chem. 256, 342 (1975).
V. V. Boldyrev, F. Kh. Urakaev, V. R. Regel, and O. F. Pozdnjakov, Dokl. Akad. Nauk. SSSR. 21, 634 (1973).
F. Kh. Urakaev, V. V. Boldyrev, O. F. Pozdhjakov, and V. R. Regel, Kinet. Cat. 18, 350 (1977).
P. P. Budnikov and A. M. Ginstling, Principles of Solid State Chemistry (Maclaren, London, 1968), 454p.
M. Poux, P. Fayolle, J. Bertrand, D. Bardroux, and J. Bousquet, Powder Technol. 68, 213 (1991).
P. Yu. Butjagin, in Mekhanokhimicheskii Sintez v Neorganicheskoi Khimii, E. G. Avvakumov, ed. (Nauka, Novosibirsk, 1991), pp. 33–52.
P. Yu. Butyagin, Mater. Sci. Forum 88–90, 711 (1992).
G. F. Hüttig, in Handbuch der Katalyse, Bd. 6, G. Schwab, ed. (Springer Verlag, Wien, 1943), pp. 472–540.
G. F. Hüttig, Z. Elektrochem. Angew. Phys. Chem. 41, 527 (1935).
W. Jander, Angew. Chem. 49, 879 (1936).
T. Watanabe, T. Isobe, and M. Senna, J. Solid State Chem. 122, 74 (1996).
Y. Fujiwara, T. Isobe, M. Senna, and J. Tanaka, Trans. Mater. Res. Soc. Jpn. 25, 139 (2000).
I. J. Lin and S. Nadiv, in Proceedings of the XVI International Mineral Processing Congress, E. Forsberg, ed. (Elsevier, Amsterdam, 1988), pp. 231–242.
P. Baron, I. Lin, S. Nadiv, and M. Melamud, J. Thermal Anal. 42, 207 (1994).
A. E. Yermakov, E. E. Yurchikov, and V. A. Barinov, Fiz. Metal. Metalloved. 52, 1183 (1981).
K. B. Gerasimov and V. V. Boldyrev, Mater. Res. Bull. 31, 1297 (1996).
V. M. Zalkin, Nature of Eutectic Melts and the Effect of Contact Melting (Metallurgia, Moscow, 1987), p. 151.
E. G. Avvakumov, E. T. Devyatkina, and N. V. Kosova, J. Solid State Chem. 113, 379 (1994).
N. V. Kosova, E. T. Devyatkina, and E. G. Avvakumov, Siber. Chem. J. 2, 135 (1992).
M. Senna, T. Watanabe, and T. Isobe, Mater. Sci. Forum 225–227, 521 (1996).
V. V. Boldyrev, A. Kh. Khabibulin, N. V. Kosova, and E. G. Avvakumov, Inorg. Mater. 33, 1144 (1997).
N. V. Kosova, A. Kh. Khabibulin, and V. V. Boldyrev, Solid State Ionics 101–103, 53 (1997).
V. V. Boldyrev, A. Kh. Khabibulin, N. V. Kosova, and E. G. Avvakumov, J. Mater. Synthesis Proc. 4, 377 (1996).
G. Mi, F. Saito, and M. Hanada, Powder Technol. 93, 77 (1997).
J. Temunjin, K. Okada, and K. Mackenzie, J. Solid State Chem. 138, 169 (1998).
G. Tschakarov and G. Gospodinov, Z. Phys. Chem. 261, 340 (1980).
G. Tschakarov, G. Gospodinov, and V. Z. Bontsche, J. Solid State Chem. 41, 244 (1982).
L. Takacs, J. Solid State Chem. 125, 75 (1996).
L. Takacs, Mater. Sci. Forum 269–272, 513 (1998).
V. V. Boldyrev, V. A. Aleksandrov, V. I. Smirnov, K. B. Gerasimov, and E. Yu. Ivanov, Dokl. Akad. Nauk. SSSK 317, 663 (1991).
T. F. Grigorjeva, A. P. Barinova, G. N. Kryukova, V. D. Belykh, E. Yu. Ivanov, and V. V. Boldyrev, Mater. Sci. Forum. 269–272, 235 (1998).
G. B. Schaffer and P. G. MacCormick, Metal. Mater. Trans. 23A, 1285 (1996).
Ch. Gras, E. Gaffet, F. Bernard, A. Vrel, and J. C. Niepce, in Book of Abstracts of the Vth International Symposium on Self-Propagating High-Temperature Synthesis (SHS-99) (Moscow, 1999), p. 39.
O. I. Lomovsky, Computer Data Bank “Mechanochemistry” (Novosibirsk, 1993). Published by the Institute of Solid State Chemistry.
O. I. Lomovsky, in Proceedings of the 2nd International Confernce on Mechanochemistry and Mechanical Alloying, N. Z. Lyakhov, ed. (Novosibirsk, 1997), p. 140. Published by the Institute of Solid State Chemistry.
V. V. Boldyrev, Mater. Sci. Forum, 269–272, 227 (1998).
R. Roy, in Reactivity of Solids, Proceedings of the IX International Conference. Navorotsky, ed. [Wiley (Interscience), New York, 1988, pp. 1998–1921.
V. V. Boldyrev, A. S. Kolosov, M. V. Chaikina, and E. G. Avvakumov, Dokl. Akad. Nauk. SSSR 233, 892 (1977).
R. Pothig, L. Dunkel, and R. Paudert, Kristallogr. Technik. 13, 879 (1978).
M. Chaikina, G. Kryukov, and M. Tatarinzeva, Proc. Siber. Br. Acad. Sci. 5, 134 (1989).
V. Boldyrev, M. Chaikina, G. Kryukova, G. Litvak, and V. Zaikovskii, Dokl. Akad. Nauk SSSR 286, 1426 (1986).
R. Poudert, H. Harenz, and G. Heinicke, DDR-Patent WP 119569 (1976).
H. P. Heegn, K. Tkačová, G. Ludwig, C. Bernhardt, and K. Husemann, Chem. Technol. 30, 348 (1978).
I. Berkhin, I. Naumenko, and L. Pasashnikova, Siber. J. Agric., pp. 7–14 (1979).
K. Tkáčová, Mechanical Activation in Mineral Processing and Treatment (Veda Vydavatel'stvo SAV, Bratislav, 1984).
K. Tkáčová and P. Baláz, Hydrometallurgy 21, 103 (1988).
R. Paudert, H. Harenz, G. Heinicke, L. Dunkel, L. Bottig, A. Kolosov, V. Boldyrev, and M. Chaikina, DDR-Patent. CO5B/205660, (1985).
K. Tkáčová, and N. Števulová, Thermochim. Acta 93, 713 (1985).
K. Tkáčová, P. Baláž, and T. A. Korneva, J. Therm. Anal. 34, 1031 (1988).
V. P. Chuev. L. A. Lyagina, E. Yu. Ivanov, and V. V. Boldyrev, Dokl. Akad. Nauk SSSR 307, 1429 (1989).
V. P. Chuev, L. A. Lyagina, S. N. Kovalenko, and E. Yu. Ivanov, Siberian J. Chem. 5, 158 (1991).
E. Ivanov, T. Grigorjeva, G. Golubkova, V. V. Boldyrev, and A. Fasman, Mater. Lett. 7, 51 (1988).
E. Ivanov, G. Grigoreva, and G. Golubkova, Reactions Solids 8, 77 (1990).
A. Fasman, S. Mikhailenko, O. Kalinina, E. Ivanov, and G. Golubkova, in Scientific Basis for the Preparation of Catalysis, 5th International Symposium B. Delmon, ed. (Louvain la Neuve, 1990), pp. 10–21.
K. Tkáčová, P. Baláž, and Z. Bastl, Thermochim. Acta 170, 277 (1990).
K. Tkáčová, P. Baláž, B. Mišura, and V. A. Chanturiya, Hydrometallurgy 33, 291 (1993).
J. Bade and H. Hoffmann, Chem. Eng. Commun. 143, 169 (1996).
M. Umemoto, Mater. Trans. Jpn. Inst. Met. 36, 373 (1995).
V. Boldyrev, N. Lyakhov, and M. Chaikina, Chem. Sustainable Develop. 4, 97 (1996).
E. Yu. Belyaev, O. I. Lomovsky, A. I. Ancharov, and B. P. Tolochko, Nucl. Instr. Methods Phys. Res. A405, 435 (1998).
E. Belyaev, S. Mamyloz, and O. Lomovsky, J. Mater. Sci. 35, 2029 (2000).
E. Belyaev, G. Suchkova, A. Ancharov, S. Avramchuk, N. Slavnikh, S. Mamylov, and O. Lomovsky, in Proceedings of the 4th Korea-Russia International Symposium on Science and Technology (Ulsan, Korea, 2000), pp. 357–360.
A. V. Dushkin, Z. Yu. Rykova, V. V. Boldyrev, E. A. Vinogradov, F. V. Guss, and V. P. Chetverikov, Patent RF N 2099058 (20.12.97).
A. Ellis, M. Geselbracht, M. Greenblat, B. Johnson, G. Lisensky, and R. S. Whittinham, J. Chem. Educ. 69, 1075 (1992).
A. B. Ellis, M. Geselbracht, M. Greenblat, B. Johnson, G. Lisensky, and R. S. Whittinham, Material Science Companion (Publ. Amer. Chem. Soc., Washington, D.C., 1993).
K. Tkáčová et al., Powder Technol. 83, 163 (1995).
K. Tkáčová et al., J. Mater. Res. 10, 2728 (1995).
V. V. Zyryanov and O. B. Isakova, Izv. Sib. Otd. Akad. Nauk. 3, 50 (1988).
N. Števulová, K. Tkáčová, and J. Lipka, Keram. Z. 44, 609 (1992).
G. Cocco, G. Mulas, and L. Shiffini, Mater. Trans. Jpn. Inst. Met. 36, 150 (1995).
K. Tkáčová and N. Števulová, Keram. Z. 45, 400 (1993).
J. Bade and H. Hoffmann, Chem. Eng. Commun. 143, 169 (1996).
E. M. Gutman, Mechanochemistry of Solid Surfaces (World Scientific, Singapore, 1994), 332 pp.