Gas-Phase Tropospheric Chemistry of Volatile Organic Compounds: 1. Alkanes and Alkenes

Journal of Physical and Chemical Reference Data - Tập 26 Số 2 - Trang 215-290 - 1997
Roger Atkinson1,2
1Department of Chemistry, University of California, Riverside, California, 92521
2Statewide Air Pollution Research Center, Department of Soil and Environmental Sciences

Tóm tắt

Literature data (through mid-1996) concerning the gas-phase reactions of alkanes and alkenes (including isoprene and monoterpenes) leading to their first generation products are reviewed and evaluated for tropospheric conditions. The recommendations of the most recent IUPAC evaluation [J. Phys. Chem. Ref. Data, 26, No. 3 (1997)] are used for the ⩽C3 organic compounds, unless more recent data necessitates reevaluation. The most recent review and evaluation of Atkinson [J. Phys. Chem. Ref. Data, Monograph 2, 1 (1994)] concerning the kinetics of the reactions of OH radicals, NO3 radicals, and O3 is also updated for these two classes of volatile organic compounds.

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