Crystallographic Study of Chromium Spinels

Journal of Applied Physics - Tập 37 Số 3 - Trang 1436-1437 - 1966
P. M. Raccah1, R.J. Bouchard2, A. Wold2
1Lincoln Laboratory, Massachusetts Institute of Technology Lexington, Massachusetts
2Engineering Department, Brown University, Providence, Rhode Island

Tóm tắt

Several chromium spinels have been prepared and regular x-ray diffraction intensities were measured on the powders. A Fortran program was developed in order to process the data. It appeared that the results, so obtained, were comparable to those from neutron diffraction techniques. A plot of the U parameter versus a0 for the thiochromites shows that metallic CuCr2S4 is exceptional. For its value of U, it has a much lower a0 than would be expected from a comparison of Mn, Fe, Co, and Zn thiochromites.

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Tài liệu tham khảo

1965, Inorg. Chem., 4, 685, 10.1021/ic50027a019

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