Highly stretchable polymer semiconductor films through the nanoconfinement effect

American Association for the Advancement of Science (AAAS) - Tập 355 Số 6320 - Trang 59-64 - 2017
Jie Xu1, Sihong Wang1, Ging-Ji Nathan Wang1, Chenxin Zhu2, Shaochuan Luo3, Lihua Jin4,5, Xiaodan Gu1,6, Shucheng Chen1, Vivian R. Feig7, John W. F. To1, Simon Rondeau‐Gagné1, Joonsuk Park7, Bob C. Schroeder1, Chien Lu1, Jin Young Oh1, Yanming Wang7, Yun‐Hi Kim8, He Yan9, Robert Sinclair7, Dongshan Zhou3, Gi Xue3, Boris Murmann2, Christian Linder4, Wei Cai5, Jeffrey B.‐H. Tok1, Jong Won Chung1,10, Zhenan Bao1
1Department of Chemical Engineering, Stanford University, Stanford, CA 94305 USA
2Department of Electrical Engineering, Stanford University, Stanford, CA 94305 USA
3Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China
4Department of Civil and Environmental Engineering, Stanford University, Stanford, CA 94305, USA.
5Department of Mechanical Engineering, Stanford University Stanford, CA 94305, USA,
6Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, CA 94025, USA
7Department of Materials Science and Engineering, Stanford University, Stanford, CA 94305 USA
8Department of Chemistry and RINS, Gyeongsang National University, Jinju 660-701 South Korea
9Department of Chemistry and Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration & Reconstruction, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong.
10Samsung Advanced Institute of Technology Yeongtong-gu, Suwon-si, Gyeonggi-do 443-803, South Korea.

Tóm tắt

Trapping polymers to improve flexibility Polymer molecules at a free surface or trapped in thin layers or tubes will show different properties from those of the bulk. Confinement can prevent crystallization and oddly can sometimes give the chains more scope for motion. Xu et al. found that a conducting polymer confined inside an elastomer—a highly stretchable, rubber-like polymer—retained its conductive properties even when subjected to large deformations (see the Perspective by Napolitano). Science , this issue p. 59 ; see also p. 24

Từ khóa


Tài liệu tham khảo

10.1126/science.1206157

10.1038/nmat2971

10.1126/science.aaa9306

10.1038/nature12314

10.1038/nnano.2006.131

10.1038/nmat4327

10.1038/nnano.2016.38

10.1002/adma.201201795

10.1021/ja108861q

10.1021/ja405112s

10.1063/1.4947428

10.1021/acs.chemmater.6b00525

10.1021/cm502271j

10.1039/C4TC02476A

10.1002/aelm.201500250

10.1002/adma.201404602

10.1002/adma.201305462

10.1002/adfm.201100904

10.1021/acsami.6b01852

10.1021/ma060790i

10.1209/0295-5075/27/1/011

10.1103/PhysRevLett.94.127801

10.1103/PhysRevE.56.5705

10.1038/nmat980

10.1021/ma070994e

10.1002/adfm.201000436

10.1016/j.matlet.2014.05.107

10.1073/pnas.1501381112

10.1002/adma.201002313

10.1021/nn1018768

S. Napolitano Ed. Non-Equilibrium Phenomena in Confined Soft Matter (Springer 2015).

10.1038/ncomms6293

10.1021/ma8012543

10.1021/om201217r

10.1021/acs.chemmater.5b01274

10.1021/acsami.5b04082

10.1002/app.1969.070130815

10.1038/nmat1175

10.1039/C5SM02082D

10.1021/la4032267

P. Roberts D. D. Damian W. Shan T. Lu C. Majidi Soft-matter capacitive sensor for measuring shear and pressure deformation in 2013 IEEE International Conference on Robotics and Automation (ICRA) Karlsruhe Germany 6 to 10 May 2013 (IEEE 2013) pp. 3529–3534.

10.1021/acsami.5b08628

10.1002/adfm.201302646

10.1016/S1672-2515(07)60210-3

K. Z. Markov Elementary micromechanics of heterogeneous media in Heterogeneous Media K. Z. Markov L. Preziosi Eds. (Springer 2000) chap. 1.

10.1063/1.1704855

10.1038/nmat3722