Phase-specific magnetic ordering in BiFeO3−PbTiO3

Applied Physics Letters - Tập 93 Số 23 - 2008
Tim P. Comyn1, Tim Stevenson1, Maisoon Al‐Jawad2, Stuart L. Turner1, Ronald I. Smith3, William G. Marshall3, Andrew J. Bell1, R. Cywiński4
1University of Leeds 1 Institute for Materials Research, , Leeds LS2 9JT, United Kingdom
2University of Leeds 2 Leeds Dental Institute, , Leeds LS2 9LU, United Kingdom
3STFC Rutherford Appleton Laboratory 3 ISIS Facility, , Harwell Science & Innovation Campus, Chilton, Didcot, Oxfordshire OX11 OQX, United Kingdom
4University of Huddersfield 4 School of Applied Sciences, , Huddersfield HD1 3DH, United Kingdom

Tóm tắt

The multiferroic 0.7 BiFeO3–0.3 PbTiO3 has been fabricated in both sintered ceramic and powder form using conventional mixed oxide synthesis. Rietveld’s analysis of neutron powder diffraction data has shown that the sintered ceramic and powder are predominantly R3c and P4mm phases, respectively. It is shown explicitly that magnetic ordering does not occur for the P4mm phase at room temperature.

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