Long-Term Declining Trends in River Water pH in Central Japan

Water, Air, and Soil Pollution - Tập 200 - Trang 253-265 - 2008
Hiroki Matsubara1,2, Shingo Morimoto3, Hiroyuki Sase1, Tsuyoshi Ohizumi1,4, Hiroshi Sumida5, Makoto Nakata3, Hiromasa Ueda1
1Ecological Impact Research Department, Acid Deposition and Oxidant Research Center, Niigata, Japan
2HORIBA Ltd. Kyoto Japan
3Graduate School of Science and Technology, Niigata University, Niigata, Japan
4Niigata Prefectural Institute of Public Health and Environmental Sciences, Niigata, Japan
5Gifu Prefectural Research Institute for Health and Environmental Sciences, Gifu, Japan

Tóm tắt

pH monitoring data for public water bodies in Niigata and Gifu prefectures in central Japan were tested by the nonparametric seasonal Mann–Kendall method to evaluate long-term acidification. A significant long-term declining trend in river water pH was found in several watersheds in Niigata and Gifu prefectures. In Niigata, the declining trend was observed only in areas receiving drainage from granitic rocks, and the acid neutralizing capacity of the river waters was in fact low in those areas. In Gifu, a declining trend was observed in some remote watersheds, where there was no clear relationship between the geology and the long-term trends. Since Niigata and Gifu receive the highest level of acid loading from the atmosphere in Japan, river water acidification in several watersheds may be attributable to the effects of the acid deposition. Other factors, such as hot spring drainage, changes in land use, and natural sea salt deposition, cannot adequately explain the acidification phenomena observed in this study.

Tài liệu tham khảo

Charles, D. F., Whitehead, D. R., Engstrom, D. R., Fry, B. D., Hites, R. A., Norton, S. A., et al. (1987). Paleolimnological evidence for recent acidification of Big Moose Lake, Adirondack Mountains, N.Y. (USA). Biogeochemistry, 3, 267–296. doi:10.1007/BF02185196. Christophersen, N., Seip, H. M., Quenild, C., & Tollan, O. (1982). Sodium mobility in a mini-catchment, studied with radioactive tracers and artificial precipitation. Nordic Hydrology, 13, 105–114. Committee for Acid Deposition Measures (2004). Comprehensive report on acid deposition survey. Ministry of the Environment, Japan (in Japanese). Committee of Acid Deposition Survey (2005). Results of acid deposition survey 2003 by Japanese Environmental Laboratories Association. Journal of Environmental Laboratories Association, 30, 177. in Japanese. EMEP (2008). EMEP measurement online. EMEP Chemical Coordinating Centre at NILU. http://www.nilu.no/projects/ccc/emepdata.html. Fukuzaki, N., Ohizumi, T., & Matsuda, K. (2001). Geographical and temporal variations of chemical constituents in winter precipitation collected in the areas along the coast of the Sea of Japan. Water, Air, and Soil Pollution, 130, 1673–1678. doi:10.1023/A:1013925600809. Geller, W., Klapper, H., & Salomons, W. (1998). Acidic mining lakes. Heidelberg: Springer. Hirsch, R. M., Slack, J. R., & Smith, R. A. (1982). Technique of trend analysis for monthly water quality data. Water Resources Research, 18(1), 107–121. doi:10.1029/WR018i001p00107. Ishikawa, T. (1970). Geothermal fields in Japan considered from the geological and petrological view point. Geothermics, 2(2), 1205–1211. doi:10.1016/0375-6505(70)90433-5. Jensen, K. W., & Snekvik, E. (1972). Low pH levels wipe out salmon and trout populations in southernmost in southernmost Norway. Ambio, 1, 223–225. Kamisako, M., Sase, H., Matsui, T., Suzuki, H., Takahashi, A., Oida, T., et al. (2008). Seasonal and annual fluxes of inorganic constituents in a small catchment of a Japanese cedar forest near the Sea of Japan. Water, Air, and Soil Pollution, 195, 51–61. doi:10.1007/s11270-008-9726-8. Kitada, T., Okamura, K., Nakanishi, H., & Mori, H. (2000). Production and transport of ozone in local flows over central Japan—Comparison of numerical calculation with airborne observation. Air pollution modeling and its application XIII pp. 95–106. New York: Plenum. Komai, Y., Umemoto, S., & Inoue, T. (2001). Influence of acid deposition on inland water chemistry—A case study from Hyogo Prefecture, Japan. Water, Air, and Soil Pollution, 130, 1535–1540. doi:10.1023/A:1013910324974. Krug, E. C., & Frink, C. R. (1983). Acid rain on acid soil: A new perspective. Science, 221, 520–525. doi:10.1126/science.221.4610.520. Kurita, H., & Ueda, H. (2006). Long-term decrease of pH of river and lake water in the upper-most stream part of the mountainous region in Central Japan—Decrease of pH in past 30 years in relation with acid rain. Journal of Japan Society for Atmospheric Environment, 41(2), 45–64. In Japanese. Lefohn, A. S., Husar, J. D., & Husar, R. B. (1999). Estimating historical anthropogenic glob al sulfur emission patterns for the period 1850–1990. Atmospheric Environment, 33(21), 3435–3444. doi:10.1016/S1352-2310(99)00112-0. Malhi, S. S., Nyborg, M., & Harapiak, J. T. (1998). Effects of long-term N fertilizer-induced acidification and liming on micronutrients in soil and in bromegrass hay. Soil & Tillage Research, 48(1–2), 91–101. doi:10.1016/S0167-1987(98)00097-X. Ministry of Land, Infrastructure and Transport Japan (1997). National-Land Information Download Service. National-Land Information Office. http://nlftp.mlit.go.jp/ksj/index.html (in Japanese). Ministry of the Environment of Japan (2004). Monitoring data of Acid Deposition Surveys. http://www.env.go.jp/earth/acidrain/index.html (in Japanese). NADP (2008). Data access. National Atmospheric Deposition Program (NADP). http://nadp.sws.uiuc.edu/sites/ntnmap.asp? Network Center for EANET (2004). Data report on the Acid Deposition in the East Asian Region 2003. Acid Deposition and Oxidant Research Center, Niigata, Japan. http://www.eanet.cc/product.html. Ohizumi, T., Take, N., Moriyama, N., Suzuki, O., & Kusakabe, M. (2001). Seasonal and spatial variations in the chemical and sulfur isotopic composition of acid deposition in Niigata Prefecture, Japan. Water, Air, and Soil Pollution, 130, 1679–1684. doi:10.1023/A:1013977619465. Ohte, N., Tokuchi, N., Shibata, H., Tsujimura, M., Tanaka, T., & Mitchell, M. J. (2001). Hydrobiogeochemistry of forest ecosystems in Japan: major themes and research issues. Hydrological Processes, 15, 1771–1789. doi:10.1002/hyp.239. Sase, H., Takahashi, A., Sato, M., Kobayashi, H., Nakata, M., & Totsuka, T. (2008). Seasonal variation in the atmospheric deposition of inorganic constituents and canopy interactions in a Japanese cedar forest. Environmental Pollution, 152, 1–10. doi:10.1016/j.envpol.2007.06.023. Satow, K. (1993). Chemical characteristics of snow in the region along the Sea of Japan. Annals of Glaciology, 18, 227–233. Second, I.S.A.G. Meeting of EANET (2000). Technical documents for monitoring on inland aquatic environment in East Asia. Network Center for EANET, Acid Deposition and Oxidant Research Center, Niigata, Japan. Skjelkvale, B. L., Stoddard, J. L., & Andersen, T. (2001). Trend in surface water acidification in Europe and North America (1989–1988). Water, Air, and Soil Pollution, 130, 787–792. doi:10.1023/A:1013806223310. Stoddard, J. L., Jeffries, D. S., Lukewille, A., Clair, T. A., Dilon, P. J., Driscoll, C. T., et al. (1999). Regional trends in aquatic recovery from acidification in North America and Europe. Nature, 401, 575–578. doi:10.1038/44114. Suzuki, K. (1991). Diurnal variation of the chemical characteristics of meltwater. Seppyo, 53(1), 21–31. In Japanese. Tonooka, Y. (1997). Status and prediction of acid deposition and pollutant emission. Acid rain: Direction of Global Environment pp. 29–38. Tokyo: National Environmental Agency. (In Japanese). Watt, W. D., Scott, C. D., & White, W. J. (1983). Evidence of acidification of some Nova Scotia Rivers and its impact on Atlantic Salmon. Canadian Journal of Fisheries and Aquatic Sciences, 40, 462–473. Wright, R. F., Dale, T., Gjessing, E. R., Hendrey, G., Henriksen, A., Johannessen, M., et al. (1976). Impact of acid precipitation on freshwater ecosystems in Norway. Water, Air, and Soil Pollution, 6, 483–499. doi:10.1007/BF00182887. Yamada, T., Inoue, T., Fukuhara, H., Nakahara, O., Izuta, T., Suda, R., et al. (2007). Long-term trend in surface water quality of five lakes in Japan. Water Air and Soil Pollution Focus, 7, 259–266. doi:10.1007/s11267-006-9076-8.