Tribochemistry and antiwear mechanism of organic–inorganic nanoparticles as lubricant additives

B. Li1, X. Wang1, W. Liu1, Q. Xue1
1State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, P.R. China

Tóm tắt

Lubricant-dispersible nanoparticles are prepared via a surface modification synthetic way and characterized by state of the art tools such as TEM. The tribological properties of the nanoparticles as lubricant additives were studied and the results show that the addition of nanoparticles as additives reduced wear and increased load-carrying capacity of base oil remarkably, indicating nanoparticles can be used as anti-wear and extreme-pressure additives with excellent performances. The boundary lubrication mechanism of nanoparticles was discussed that probably an ultra thin film, which is formed by the melting and elongation of nanoparticles under tribological heat and shear force, attributed to good tribological performance of nanoparticulate as additives.

Từ khóa


Tài liệu tham khảo

Mortier R.M., Orxaulik S.T., 1992 Chemistry and Technology of Lubricants VCH Publishers Inc. New York

Gansheimer J., Holinski R., (1973) J. Lubr. Tech. ASME Trans. 95:242

Bartz W.J., Muller K., (1972) Wear 20:377

Chakravorty D., Giri A.K., 1993 Chemistry for the 21st Century, “Chemistry of Advanced Materials” Oxford Blackwell Scientific Publication London

Henglein A., (1989) Chem. Rev. 89:1861

Zhang Z., Zhang J., Xue Q., (1994) J. Phys. Chem. 98:12973

Xue Q., Liu W., Zhang Z., (1997) Wear 213:29

Zhang Z.F., Liu W.M., Xue Q.J., (1998) Wear 215:40

Chen S., Liu W.M., (1998) Wear 218:153

Chen S., Liu W.M., (1999) Langmuir 15:8100

Liu W.M., Zhang Z.F., Chen S., Xue Q.J., (2000) J. Disper. Sci Tech. 21:469

Yongjian G., Sun R., Zhang Z., Xue Q., (2000) Mater. Sci. Eng, A 286:149

Zhou J.F., Wu Z.S, Zhang Z.J., Liu W.M., Xue Q.J., (2000) Tribol. Lett. 8:213

Chen S., Liu W.M., (2001) Mater. Res. Bull. 36:137

Zhang Z.F., Liu W.M., Xue Q.J., (2001) Tribol. Int. 34:83

Zhou J.F., Wu Z.S., Zhang Z.J., Liu W.M., Dang H.X., (2001) Wear 249:333

Chinas-Castillo F., Spikes H.A., (2003) J. Tribol. 125:552

Bakunin V.N., Yu A., Suslov, Kuzmina G.N., Parenage O.P., Topchiev A.V., (2004) J. Nanoparticle Res. 6:273

Tzhayik O., Sawant P., Efrima S., Kovalev E., Klug J.T., (2002) Langmuir, 18:3364

Templeton A.C., Wuelfing W.P., Murray R.W., (2000) Acc. Chem. Res. 33:27

Xiaobo W., Liu W., Yan F., Zhang Z., Xu B., 2004 Chem. Lett. 2:196

Severin K.G., Ledford J.S., Torgerson B.A., Berglund K.A., (1994) Chem. Mater. 6:890