3D‐Printed Conical Arrays of TiO2 Electrodes for Enhanced Photoelectrochemical Water Splitting

Advanced Energy Materials - Tập 7 Số 21 - 2017
Chong Lee1, Adam C. Taylor1, Stephen Beirne1, Gordon G. Wallace1
1ARC Centre of Excellence for Electromaterials Science, Intelligent Polymer Research Institute, AIIM, Innovation Campus, University of Wollongong, Wollongong, NSW 2500, Australia

Tóm tắt

AbstractControl over the topography of semiconducting materials can lead to enhanced performances in photoelectrochemical related applications. One means of implementing this is through direct patterning of metal‐based substrates, though this is inadequately developed. Conventional techniques for patterned fabrication commonly involve technologically demanding and tedious processes. 3D printing, a form of additive fabrication, enables creation of a 3D object by deposition of successive layers of material via computer control. In this work, the feasibility of fabricating metal‐based 3D printed photoelectrodes is explored. Electrodes comprised of conical arrays are fabricated and the performance for photoelectrochemical water splitting is further enhanced by the direct growth of TiO2 nanotubes on this platform. 3D metal printing provides a flexible and versatile approach for the design and fabrication of novel electrode structures.

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Tài liệu tham khảo

10.1021/cr1002326

Armaroli N. N., 2011, Energy for a Sustainable World

10.1016/S0360-3199(01)00154-9

10.1002/9783527622894

10.1002/adfm.201601581

10.2533/chimia.2015.789

10.1039/C6EE01304J

10.1021/acscatal.5b00221

10.1002/slct.201700081

10.1016/j.ijhydene.2016.01.108

10.1039/B800489G

10.1039/C2EE22618A

10.1021/cr1001645

10.1039/C3CS60378D

10.1021/jp0255482

10.1038/238037a0

Govindaraj A., 2005, , Nanotubes and Nanowires, in The Chemistry of Nanomaterials: Synthesis, Properties and Applications, 8

10.1016/B978-0-08-051557-1.50009-3

10.1021/cr500061m

10.1002/cssc.201300603

10.1016/j.elecom.2012.01.028

10.1016/j.elecom.2013.07.024

10.1039/C6SE00073H

10.1021/jp074003a

10.1002/adma.200602264

10.1021/cm0518372

10.1088/0957-4484/17/15/025

10.1021/nl048589d

10.1021/cr900056b

10.1016/j.electacta.2004.02.015

10.1016/j.elecom.2014.11.013

10.1002/smll.200600100

10.1063/1.120128

10.1002/1521-4095(200102)13:3<189::AID-ADMA189>3.0.CO;2-Z

C.‐Y. Lee P. Schmuki R. C. Alkire P. N. Bartlett J. Lipkowski 2015 Wiley‐VCH Verlag GmbH & Co. KGaA Weinheim Germany 5

10.1021/la202559h

10.1039/c1cc13342j

Gebhardt A., 2012, Understanding Additive Manufacturing: Rapid Prototyping, Rapid Tooling, Rapid Manufacturing

Barnatt C., 2014, 3D Printing: The Next Industrial Revolution

10.1016/j.elecom.2014.01.013

10.1002/anie.201504382

10.1002/adfm.201503902

10.1039/C5CS00714C

10.1021/nl102867a

10.1021/nl300713x

10.1186/1556-276X-8-391

10.1126/science.1200448

10.1021/ja3012676