β‐Cyclodextrin‐Modified Diphosphanes as Ligands for Supramolecular Rhodium Catalysts

Wiley - Tập 36 Số 8 - Trang 865-867 - 1997
Manfred T. Reetz1, Siegfried R. Waldvogel1
1Max‐Planck‐Institut für Kohlenforschung, Kaiser‐Wilhelm‐Platz 1, D‐45470 Mülheim an der Ruhr (Germany), Fax: Int. code (208)306‐2985

Tóm tắt

Từ khóa


Tài liệu tham khảo

10.1002/3527607439

Atwood J. L., 1996, Comprehensive Supramolecular Chemistry

Dehmlow E. V., 1993, Phase Transfer Catalysis

10.1021/om950575i

Parshall G. W., 1992, Homogeneous Catalysis: The Applications and Chemistry of Catalysis by Soluble Transition Metal Complexes

10.1002/9783527619351

10.1016/0079-6700(93)90020-D

10.1002/ange.19901020222

10.1002/anie.199001911

10.1021/ja00040a073

10.1002/9780470166345.ch2

(e)H.‐J.Schneider F.Xiao J. Chem. Soc. Perkin Trans. 21992 387;

10.1021/ja00125a005

10.1021/ic00013a003

10.1002/ange.19911031024

10.1002/anie.199113481

10.1002/ange.19941061105

10.1002/anie.199411411

(j)I.Willner Z.Goren J. Chem. Soc. Chem. Commun.1983 1469.

10.1021/ja00243a038

10.1021/ja00039a020

10.1021/la9515332

10.1002/recl.19931121003

10.1002/ange.19921040731

10.1002/anie.199209051

10.1021/ja00153a012

10.1016/S0040-4039(01)81377-0

10.1021/ja00166a021

(a)S. R.Waldvogel Dissertation Universität Bochum 1996;

(b)M. T.Reetz S. R.Waldvogel German Patent Application 196 31 322.8 August 2 1996.

Issleib K., 1974, Z. Chem., 14, 242, 10.1002/zfch.19740140618

10.1016/0022-328X(84)80245-4

(a)J.Fawcett P. A. T.Hoye R. D. W.Kemmitt D. J.Law D. R.Russell J. Chem. Soc. Dalton Trans.1993 2563;

10.1016/S0020-1693(00)80952-4

10.1002/ange.19941060804

10.1002/anie.199408031

10.1007/978-3-642-66842-5

10.1351/pac198658111529

10.1126/science.7123255

10.1039/cs9962500163

10.1016/0022-328X(95)05820-F

Papadogianakis G., 1996, New J. Chem., 20, 175

10.1002/ange.19951072024

10.1002/anie.199522691

10.1016/0040-4039(95)02073-X

10.1007/BF00769081

Typical procedure: Cyclodextrin diphosphane (2.4 × 10−5mol) and [Rh(cod)2]BF4(2 × 10−5mol) were dissolved in DMF (5 mL). H2O (15 mL) and 1‐octene (10 mL) were added and the hydroformylation was carried out in a steel autoclave (200 mL) equipped with a teflon sleeve and a magnetic stirrer at a temperature of 60 °C under a synthesis gas atmosphere (CO/H21/1; 100 bar). After completion of the reaction (Table 1) the mixture was poured into a separating funnel the aqueous catalyst solution removed and washed with H2O (10 mL) to remove residual DMF. The organic phase was then dried over MgSO4and filtered.