Kinetics and mechanism of thermal decomposition of cornstarches with different amylose/amylopectin ratiosStarch/Staerke - Tập 62 Số 3-4 - Trang 139-146 - 2010
Xingxun Liu, Long Yu, Fengwei Xie, Te Li, Ling Chen, Xiaoxi Li
AbstractThermal decomposition of cornstarches with different amylose/amylopectin
ratios (waxy: 0/100, maize: 23/77, Gelose 50: 50/50, and Gelose 80: 80/20) under
nitrogen condition was investigated by thermogravimetric analysis (TGA). Various
decomposition models including Friedman, Kissinger, Flynn‐Wall‐Ozawa, and
modified Coast‐Redfern methods were used to determine the apparent activation
energ... hiện toàn bộ
Properties and Flocculation Efficiency of Highly Cationized Starch DerivativesStarch/Staerke - Tập 58 Số 3-4 - Trang 161-169 - 2006
D.-O. Krentz, Claudia A. Lohmann, Simona Schwarz, Svetlana Bratskaya, Tim Liebert, Johannes Laube, Thomas Heinze, Werner‐Michael Kulicke
AbstractIn this study the flocculation efficiency of cationic starch derivatives
of varying degrees of substitution (DS) and different amylose/amylopectin ratios
was investigated and compared to structural properties. The molar masses, Mw,
radii of gyration, RG, and the molar mass distributions of the starch samples
were determined by applying the method of flow field‐flow‐fractionation combined
w... hiện toàn bộ
Physicochemical Properties of Oxidized Cassava Starch Prepared under Various Alkalinity LevelsStarch/Staerke - Tập 61 Số 2 - Trang 92-100 - 2009
Kunruedee Sangseethong, Sirithorn Lertphanich, Klanarong Sriroth
AbstractThe physicochemical properties of hypochlorite‐oxidized cassava starch
as influenced by the alkalinity levels (pH 8 to 11) during modification process
were investigated. Hypochlorite oxidation generally increased the contents of
carbonyl and carboxyl groups in starch but decreased starch viscosity. The
formation of carbonyl and carboxyl groups was more favorable under the milder
alkaline c... hiện toàn bộ
Physicochemical Properties of Banana Starch Oxidized under Different ConditionsStarch/Staerke - Tập 61 Số 3-4 - Trang 206-213 - 2009
Mirna M. Sánchez‐Rivera, Guadalupe Méndez‐Montealvo, Carmen Núñez‐Santiago, Julián de la Rosa Millán, Ya‐Jane Wang, Luís A. Bello‐Pérez
AbstractStarch isolated from unripe bananas was oxidized under different
conditions and the physicochemical properties of the oxidized banana starches
were characterized. It was found that pH was the dominating factor in the
formation of carboxyl groups. Higher yields of carboxyl groups were found when
oxidized starch was prepared at pH 11.5 as compared with 7.5. Longer reaction
time also produced... hiện toàn bộ
Oxidation of Potato Starch by Hydrogen PeroxideStarch/Staerke - Tập 47 Số 1 - Trang 19-23 - 1995
Petteri Parovuori, Antti Hamunen, Pirkko Forssell, Karin Autio, Kaisa Poutanen
AbstractPotato starch was oxidized by hydrogen peroxide in alkaline and acidic
reaction conditions with copper, iron and tungstate catalysts in order to
introduce carboxyl and carbonyl groups to the starch molecule. Carbonyl contents
up to 6.6 per 100 glucose units could be obtained, whereas carboxyl content
remained low (up to 1.4). Starch yields in the alkaline and acidic reactions
were 90 and 9... hiện toàn bộ
Annealing and Glass Transition of StarchStarch/Staerke - Tập 38 Số 9 - Trang 289-292 - 1986
D. A. Yost, R. C. Hoseney
AbstractThe enthalpy of the order‐disorder transition of starch increased as the
starch hydration period was increased from 1 h to 24 h. This was explained as
the exothermic heat of hydration cancelling part of the endothermic heat of
melting. Annealing of starch was shown to occur at 3 to 8°K below the Tm of
starch. This would suggest that the Tg and Tm of starch does not occur at the
same temper... hiện toàn bộ