Molecular orientation in sheared molten thermotropic random copolyesterRheologica Acta - Tập 46 - Trang 1139-1152 - 2007
Angel Romo-Uribe
The macromolecular alignment and texture orientation in sheared thermotropic copolyester were investigated using in situ wide-angle X-ray scattering (WAXS) and polarizing optical microscopy (POM). The molecular behavior was correlated with viscoelastic properties. The polymer is a random copolyester based on 60 mol% 1,4-hydroxybenzoic acid (B) and 40 mol% ethylene terephthalate (ET) units. X-ray s...... hiện toàn bộ
Die Viskosität niedermolekularer, unpolarer Flüssigkeiten in Abhängigkeit von Temperatur, Druck und KonzentrationRheologica Acta - Tập 2 - Trang 164-174 - 1962
M. Hoffmann, K. Rother
Flüssigkeiten mit unpolaren oder schwachpolaren Molekülen folgen gewöhnlich gleichzeitig der Gleichung vonTammann für die Temperaturabhängigkeit und der Gleichung vonArrhenius für die Konzentrationsabhängigkeit ihrer Viskosität. Hieraus ergibt sich eine bestimmte Konzentrationsabhängigkeit der Konstanten der Temperaturgleichung und damit auch eine Beziehung für die Viskositätszahl als Funktion der...... hiện toàn bộ
A note on streaming double refraction in a dilute suspension of rigid spheroids subject to weak Brownian rotationsRheologica Acta - Tập 11 Số 2 - Trang 190-198 - 1972
Leal, L. G., Hinch, E. J.
The phenomenon of streaming double refraction is examined theoretically for simple shear flow of a dilute suspension of rigid spheroids which are subject to weak Brownian rotations. In particular, we employ recently derived expressions for the statistical distribution of particle orientations in the limit of weak rotaryBrown-ian motion to calculate the corresponding limiting behavior of the extinc...... hiện toàn bộ
Age dependence of the drag force in an aqueous foamRheologica Acta - Tập 45 - Trang 803-811 - 2006
John R. de Bruyn
The drag force on a sphere moving through an aqueous foam is measured as the foam ages. After an initial period, the steady-state drag decreases with age T as T
−0.54±0.14. As the mean bubble size R in the foam coarsens as T
0.5, this implies that the drag force scales as
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Rheological properties of thin gelatin filmsRheologica Acta - Tập 10 Số 1 - Trang 158-164 - 1971
Kislalioglu, S., Shotton, E., Davis, S. S., Warburton, B.
The stability of oil-in-water emulsions depends ultimately on the physical nature of the oil-water interface. If a hydrocolloid or protein is used as an emulsifying agent an interfacial film is formed at the oil-water interface and this may be liquid or viscoelastic solid in properties. The film is formed by the two processes of diffusion from the bulk to the interface and the formation of seconda...... hiện toàn bộ
Numerical simulation of flow kinematics for suspensions containing continuously dispersed aspect ratio fibersRheologica Acta - Tập 45 - Trang 547-554 - 2005
Kunji Chiba, Francisco Chinesta
Fiber suspension flow and fiber orientation through a parallel-plate channel were numerically simulated for fiber suspensions including continuously dispersed aspect ratios from 10 to 50. In the simulations, both the fiber–fiber and fiber–wall interactions were not taken into account. A statistical scheme that proceeds by evaluating the orientation evolution of a large number of fibers from the so...... hiện toàn bộ
Avoiding waviness of relaxation spectraRheologica Acta - Tập 48 - Trang 709-713 - 2009
Joachim Kaschta, Florian J. Stadler
Spectra are material functions, whose different integral transforms yield the measurable rheological quantities in the linear viscoelastic regime. Therefore, their knowledge is of high fundamental interest. However, the calculation of spectra from experimental data is an ill-posed problem. Thus, it is hampered by the problem that a too low density of relaxation modes does not lead to a good descri...... hiện toàn bộ