Montecarlo calculations of ionic structure in silicate and alumino-silicate meltsMetallurgical Transactions B - Tập 10 - Trang 21-25 - 1979
C. Borgianni, P. Granati
Results on structures of molten silicates and alumino-silicates calculated with the Montecarlo method are reported. The structure of the ions is in agreement with Masson’s hypotheses; in fact ions of the type SinO
(3n+1
with chains even 30 + 35 atoms long have been found. The spatial configurations of the polyme...... hiện toàn bộ
The reduction of zinc from slags by an iron-carbon meltMetallurgical Transactions B - Tập 21 - Trang 885-897 - 1990
W. J. Rankin, S. Wright
An experimental investigation was undertaken to study the mechanism of reduction of zinc from slags in the presence of a carbon-saturated iron melt. Batch tests were performed at 1400 °C, and the variation of the zinc and iron concentration in the slag during reduction was determined by sampling the slag at intervals during the test. In graphite crucibles, zinc in slags containing iron was reduced...... hiện toàn bộ
Reducibility of laterite oresMetallurgical Transactions B - Tập 19 - Trang 181-186 - 1988
M. Kawahara, J. M. Toguri, R. A. Bergman
The reducibility of several types of lateritic nickel bearing ores was investigated. The ores were reduced with hydrogen over a temperature range of 673 to 1273 K and reaction times from 5 to 80 minutes. The fraction of nickel, iron, and cobalt reduced to the metallic state was determined by leaching the reacted samples with a bromine-methanol solution followed by atomic absorption analysis for th...... hiện toàn bộ
Thermodynamic behavior of phosphorus in CaO-CaF2-SiO2 and CaO-Na2O-SiO2 systemsMetallurgical Transactions B - Tập 22 - Trang 499-502 - 1991
Atsuko Tagaya, Hiroyuki Chiba, Fumitaka Tsukihashi, Nobuo Sano
In order to understand the thermodynamic behavior of phosphorus, such as the polymerization of phosphate ions in slag melts, the influence of phosphorus content of slag melts on the partition of phosphorus between slags and carbon-saturated iron or silver was investigated for the CaO-CaF2-SiO2 and CaO-Na2O-SiO2 systems at 1573 and 1473 K, respectively. The predominant species changes from PO
...... hiện toàn bộ
An analytical technique for the determination of the thermal contact resistance between a solidifying metal and moldMetallurgical Transactions B - Tập 8 - Trang 619-624 - 1977
S. R. Robertson, E. F. Fascetta
In the classical solution to one-dimensional solidifications Schwarz showed that in the case of perfect thermal contact the interface temperature between the mold and solidifying material is constant. Adams hypothesized that in the case of real casting problems where there is imperfect thermal contact, that one could still use the interface temperature computed by Schwarz’s solution but now acting...... hiện toàn bộ
Acid dissolution of willemite (Zn, Mn)2 SiO4) and hemimorphite (Zn4Si2O7(OH)2 H2O)Metallurgical Transactions B - Tập 14 - Trang 335-346 - 1983
B. Terry, A. J. Monhemius
The influence of temperature, pH, acid type, and surface area on the kinetics of the acid dissolution of natural and synthetic willemites and natural hemimorphites has been investigated. Specific rate constants, based upon areas determined by krypton adsorption measurements, were estimated from the experimental data obtained. For both willemite and hemimorphite, the rates of dissolution in differe...... hiện toàn bộ