Journal of Solution Chemistry
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Activity Coefficients of HCl + GdCl3 + H2O System from 5 to 55°C. Application of Pitzer Formalism
Journal of Solution Chemistry - Tập 29 - Trang 619-631 - 2000
The emf of the cell
$${\text{Pt, H}}_{\text{2}} ({\text{g, 1 atm}})|{\text{HCI(}}m_{\text{A}} {\text{),GdCl}}_{\text{3}} (m_B )|{\text{AgCl, Ag}}$$
without a liquid junction was used to investigate the HCl + GdCl3 + H2O mixedelectrolyte system. The emf of the cell was measured for HCl + GdCl3 + H2Osoluti...... hiện toàn bộ
Potentiometric Cells with Liquid Junctions: A Combined Analytical and Computational Study
Journal of Solution Chemistry - Tập 45 - Trang 591-623 - 2016
It is known that the electromotive force (emf) of cells with transference is dependent on an integral involving electrical transport numbers, t
i
, and chemical potentials. However, the origin of this integral, the conditions under which it is valid, its properties and utility are not well understood. This article aims to clarify such asp...... hiện toàn bộ
Correlation of solute-solute interaction enthalpies in dimethylformamide by group additivity
Journal of Solution Chemistry - Tập 16 - Trang 367-371 - 1987
The Savage and Wood group additivity method has been applied to enthalpic pair interaction coefficients of more than 30 solutes dissolved in N,N-dimethylformamide. The results are not satisfactory. Better results are obtained by using a method which accounts for the differences in the numbers of molecular groups between solute and solvent molecules. With this excess group additivity method reasona...... hiện toàn bộ
Ionic dissociation of aqueous hydrobromic acid. V. Estimate from refractive index and density measurements
Journal of Solution Chemistry - - 1981
Mechanistic and Conformational Studies on the Interaction Between Myriocin and Human Serum Albumin by Fluorescence Spectroscopy and Molecular Docking
Journal of Solution Chemistry - Tập 48 - Trang 835-848 - 2019
The interactions between myriocin (ISP-1) and human serum albumin (HSA) were studied by fluorescence spectroscopy, synchronous fluorescence spectroscopy, three-dimensional fluorescence spectroscopy and molecular docking approach. The intrinsic fluorescence of HSA was quenched through a combination of static and dynamic quenching. The binding constants and the number of binding sites were evaluated...... hiện toàn bộ
Complex Formation Equilibria of Amine-Bridged Dinuclearpalladium(II) Complexes with DNA Constituents
Journal of Solution Chemistry - Tập 40 - Trang 2023-2031 - 2011
The complex formation equilibria involving trans-diamminepalladium(II) chloride (PdII), 1,6-hexanediamine (HDA), and DNA constituents were investigated. The formation constant of all possible mononuclear and binuclear complexes were determined at 25 °C and 0.1 mol⋅L−1 NaNO3. The speciation diagrams of the binuclear complex of PdII–HDA–DNA reveal that these complexes predominate in the physiologica...... hiện toàn bộ
Correlation of the Volumetric Properties of Uni-Univalent Electrolytes in Methanol–Water Mixed Solvent Media: A Pitzer Ion-Interaction Approach
Journal of Solution Chemistry - Tập 49 Số 6 - Trang 825-835 - 2020
Volumetric and Solvation Properties of Glycyl-Glycine and Glycyl-l-leucine in Aqueous Acetate Solutions
Journal of Solution Chemistry - Tập 44 - Trang 264-279 - 2015
The densities of glycyl-glycine (diglycine) and glycyl-l-leucine, in water and in aqueous sodium acetate, potassium acetate, magnesium acetate and calcium acetate solutions, were measured at 298.15 K. The apparent molar volumes, V
1, and the partial molar volumes,
$$ \bar{V}_{1} $$
...... hiện toàn bộ
Static Dielectric Constants and Kirkwood Correlation Factor of the Binary Mixtures of N-Methylformamide with Formamide, N,N-Dimethylformamide and N,N-Dimethylacetamide
Journal of Solution Chemistry - Tập 38 - Trang 763-769 - 2009
Static dielectric constant values of the binary mixtures of N-methylformamide with formamide, N,N-dimethylformamide and N,N-dimethylacetamide have been measured in the whole composition range at 303 K. The Kirkwood correlation factor values of the amide–amide mixtures were determined from the measured values of the static dielectric constant and high-frequency limit dielectric constant. The evalua...... hiện toàn bộ
Heat capacities of aqueous mixed electrolyte solutions at high temperatures. Application of the Pitzer equations to the mixed system K−Na−Cl−SO4
Journal of Solution Chemistry - Tập 15 - Trang 349-362 - 1986
Specific heats at constant pressure for the mixed system K/Na/Cl/SO4 in H2O have been obtained from heat content measurements by means of a drop calorimeter between 60 and 220°C over the salt concentration range 0.5–5m, with ionic strengths up to 7.5. Measurements have also been made on aqueous K2SO4 solutions in the same temperature range between 0.3 and 1.6m. The heat capacities of the quaternar...... hiện toàn bộ
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