Journal of Inorganic and Organometallic Polymers

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Organic-inorganic polymers: Synthesis and characterization of cyclophosphazene-substituted polyurethanes
Journal of Inorganic and Organometallic Polymers - - 1996
Isabelle Dez, Roger De Jaeger
Erratum: A Preliminary Study of the Toxicological Properties of Selected Polymer-Ferrocene Conjugates
Journal of Inorganic and Organometallic Polymers - Tập 11 - Trang 65-65 - 2001
Bilha Schechter, Gregg Caldwell, Eberhard W. Neuse
Ca–O Binding of Poly[1-carboxylate-2-(N-t- butylcarbamoyl)ethylene-alt-ethylene] and Calcium Carbonate Composites
Journal of Inorganic and Organometallic Polymers - Tập 12 - Trang 99-108 - 2002
Kazuyuki Takahashi, Hidekazu Kozuki, Akira Onoda, Taka-aki Okamura, Hitoshi Yamamoto, Norikazu Ueyama
A novel poly(carboxylate) ligand was synthesized as a ligand for a crystalline CaCO3-organic composite. Poly[1-carboxylate-2-(N-t-butylcarbamoyl)ethylene-alt-ethylene] has a 7-membered ring with an intramolecular NH·O hydrogen bond between the carboxylate group and the neighboring amide NH proton in the anionic carboxylate form. The configuration of the polymer ligand was estimated with polymer re...... hiện toàn bộ
The DNA helical biopolymer: A template for the binding, assembly, and reactivity of metal ions and complexes
Journal of Inorganic and Organometallic Polymers - Tập 3 - Trang 3-39 - 1993
Eric C. Long
The helical DNA polymer provides many structural features that facilitate the binding of metal ions or complexes. DNA binding inorganic agents have proven invaluable, with demonstrated applications ranging from chemotherapeutic agents to probes of DNA structure. This broad range of applications attests to the utility of inorganic agents in the design of compounds which interact with the DNA helix ...... hiện toàn bộ
Morphology and Thermal Properties of Poly[bis(β-phenoxyethoxy)phosphazene]
Journal of Inorganic and Organometallic Polymers - Tập 11 - Trang 85-104 - 2001
Tetsuya Tanigami, Akio Konishi, Tetsunori Ochiai, Koji Tanaka, Manabu Takahashi, Shuji Matsuzawa
The structure and thermal properties of poly[bis(β-phenoxyethoxy)phosphazene)] (PBPEP) newly synthesized by us were investigated. The crystallization from the melt, the volumetric relaxation in the amorphous phase in the upper vicinity of the glass transition temperature (T g) and the enthalpy of relaxation of the glass in the lower vicinity of the T g were shown to be very slow. These slow rates ...... hiện toàn bộ
Characterization of Cobalt(II) Phthalocyanine Catalyst Incorporated into Poly(aminosiloxane) Matrices
Journal of Inorganic and Organometallic Polymers - Tập 9 - Trang 107-122 - 1999
T. N. Yakubovich, V. V. Teslenko, B. K. Veisov, Yu. L. Zub, R. V. Parish
Cobalt phthalocyanine (CoPc) has been incorporated into various polysiloxane matrices by adding CoPc to appropriate mixtures of tri- and tetra-alkoxysilanes during hydrolytic condensation. The matrices contained Si(CH2)3NH2 groups with alkyl or phenyl “spacer” groups between them. The cobalt content, the surface area and the pore volume all decrease as the spacer groups become larger. EPR and UV-v...... hiện toàn bộ
Chitosan–Oligo(silsesquioxane) Blend Membranes: Preparation, Morphology, and Diffusion Permeability
Journal of Inorganic and Organometallic Polymers - Tập 11 - Trang 165-182 - 2001
Adam Strachota, Galina Tishchenko, Libor Matejka, Miroslav Bleha
Preparation of the blend chitosan (CHI) membranes containing polyhedral oligomeric silsesquioxane (POSS) derivatives was investigated. POSS derivatives such as (3-aminopropyl)isobutyl-POSS (amino-POSS), [2-(3,4-epoxycyclohexyl)ethyl]isobutyl-POSS (epoxy-POSS), and octa(tetramethylammonium)-POSS were used. The blend CHI–amino-POSS membranes were predicted to be the most porous due to having the wea...... hiện toàn bộ
Multifunctional carbochain organosilicon polymers. I. A new approach to the synthesis of high molecular weight cyclolinear polycarbosiloxane
Journal of Inorganic and Organometallic Polymers - Tập 5 - Trang 123-133 - 1995
N. K. Gladkova, V. L. Khodjaeva, L. E. Gusel'nikov
Controlled synthesis of high molecular weight cyclolinear polycarbosiloxanes (PCCS) is considered, using the following reactions sequence: (1) anionic polymerization of vinyldimethylphenylsilane, (2) replacement of the Ph group in polyvinyldimethylphenylsilane (M n=83.900,M w/M n=1.48) by a Cl group to prepare polyvinyldimethylchlorosilane (PVMCS), and (3) hydrolytic intramolecular condensation of...... hiện toàn bộ
[CuL(H2O)2]{[CuL][Fe(CN)6]}2·2H2O (L=3,10-Bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane): A Novel Three-Dimensional Coordination Polymer via H-Bonded Linkages of One-Dimensional Zigzag Chain
Journal of Inorganic and Organometallic Polymers - Tập 9 - Trang 165-178 - 1999
Tongbu Lu, Hua Xiang, Shi Chen, Chengyong Su, Kaibei Yu, Zongwan Mao, Peng Cheng, Liangnian Ji
A complex with the formula [CuL(H2O)2]{[CuL][Fe(CN)6]}2·2H2O, where L=3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexaazacyclotetradecane, has been synthesized and crystallographically characterized. The structure is composed of a one-dimensional zigzag chain of $$\left\{ {[{\text{CuL}}][{\text{Fe(CN)}}_{\text{6}} ]} \right\...... hiện toàn bộ
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