ABSTRACTIn this paper, a novel heterogeneous complex of zinc with
N,N‐bis(2‐hydroxyphenyl)pyridine‐2,6‐dicarboxamide(BHPPDAH) was synthesized. The
catalyst was found to be a highly effective catalyst for the three‐component
coupling reactions of aldehydes, alkynes, and amines (A3 coupling) via C–H
activation. The reactions could be applied to both aromatic and aliphatic
aldehydes and alkynes. Near... hiện toàn bộ
Zita Rádai, Petra Szeles, Nóra Zsuzsa Kiss, László Hegedűs, Tímea Windt, Véronika Nagy, György Keglevich
AbstractA series of dibenzyl α‐hydroxyphosphonates and the corresponding
α‐hydroxyphosphonic acids, mostly new compounds, have been synthesized. The
dibenzyl α‐hydroxyphosphonates have been obtained in the Pudovik reaction of
substituted benzaldehydes and dibenzyl phosphite in the presence of
triethylamine as the catalyst. The amount of the solvent was minimized during
the reaction, and the workup... hiện toàn bộ
AbstractHalogenation of 1,1,2,3,4,5‐hexaphenylstannole was reinvestigated.
Reaction of the stannole with 2 equiv. of bromine gave
1‐bromo‐4‐dibromophenylstannyl‐1,2,3,4‐tetraphenyl‐1,3‐butadiene. Reaction of
the stannole with iodine gave similar results. Reaction of the stannole with 1
equiv. of bromine or iodine afforded
1‐halo‐4‐halodiphenylstannyl‐1,2,3,4‐tetraphenyl‐1,3‐butadiene, resulting fr... hiện toàn bộ