Factors affecting the formation of zeolite seed layers and the effects of seed layers on the growth of zeolite silicalite-1 membranesFrontiers of Chemical Engineering in China - Tập 1 - Trang 172-177 - 2007
Xiongfu Zhang, Hai’ou Liu, Anjie Wang, Jinqu Wang
The present study investigates the formation of silicalite-1 seed layers on a
porous carbon support of 0.5 μm pore size and α-A12O3 supports with different
pore sizes (0.1 μm and 4 μm) via the slip-casting technique. The effects of
support property, seed size and solvent on the formation of seed layers were
investigated in detail. The growth of silicalite-1 membranes on different seeded
supports b... hiện toàn bộ
Experimental study on bubble behavior and CFD simulation of large-scale slurry bubble column reactorFrontiers of Chemical Engineering in China - Tập 4 - Trang 515-522 - 2010
Haoyi Sun, Tao Li, Weiyong Ying, Dingye Fang
Slurry bubble column reactors (SBCR) is a three-phase fluidized reactor with
outstanding advantages compared with other reactors and is difficult to scale-up
due to lack of information on hydrodynamics and mass transfer over a wide range
of operating conditions of commercial interest. In this paper, an experiment was
conducted to investigate the bubble behavior in SBCR with a height of 5600 mm
and... hiện toàn bộ
Synthesis of ordered cerium-doped cubic mesoporous silica using long-chain ionic liquid as templateFrontiers of Chemical Engineering in China - Tập 2 - Trang 135-139 - 2008
Hongxia Yue, Hongmei Zhao, Longjiang Liu, Siping Wang, Qiong Ruan, Tongwen Wang
The long-chain ionic liquid 1-hexadecyl-3-methylimidazolium chloride (C16mimCl)
was used as a template to prepare cerium-doped MCM-48 materials in basic medium
by a hydrothermal synthesis procedure. The effect of the amount of Ce salt and
C16mimCl/Si on the synthesis were discussed in detail. This mesoporous material
exhibits a pore architecture which is cubic Ia3d gyroid and possesses a large
sur... hiện toàn bộ
Monte Carlo simulation of the diffusion-limited aggregating process of particle suspension systemsFrontiers of Chemical Engineering in China - Tập 4 - Trang 270-274 - 2009
Jiajing Xu, Wei Dai, Wenwen Shan, Lin Zhang, Yongjian Tang
The aggregating process of particle suspension systems is a very universal
phenomena and crucial for various processes both in nature and in industry. In
this paper, the aggregating process was simulated with offlattice
diffusion-limited cluster-cluster aggregation (DLCA) Monte Carlo programs. The
self-similar fractal structures of aggregates have been clearly demonstrated by
the statistical analy... hiện toàn bộ
Review of SO 2− 4 /M x O y solid superacid catalystsFrontiers of Chemical Engineering in China - Tập 3 - Trang 330-343 - 2009
Yanni Wu, Shijun Liao
Some metal oxides modified with sulfate ions form highly acidic or superacidic
catalysts. SO 2− 4 /M x O y solid superacid catalysts, play a vital role in more
and more fields such as organic synthesis, fine chemicals, pharmaceuticals, and
means for strengthening environmental safeguards. This review highlights the
recent development of solid superacid catalysts based on SO 2− 4 /M x O y ,
includi... hiện toàn bộ
Synthesis of methanol and ethanol over CuZnAl slurry catalyst prepared by complete liquid-phase technologyFrontiers of Chemical Engineering in China - Tập 4 - Trang 472-475 - 2010
Wei Huang, Linmei Yu, Wenhui Li, Zhili Ma
A new method, named the complete liquid-phase technology, has been applied to
prepare catalysts for methanol synthesis. Its main innovative thought lies in
preparing slurry catalysts directly from raw solution. Activity tests indicate
that the CuZnAl slurry catalyst prepared by the new method can efficiently
catalyze conversion of syngas to ethanol in a slurry reactor, while CO
conversion reaches ... hiện toàn bộ
The effect of capping with natural and modified zeolites on the release of phosphorus and organic contaminants from river sedimentFrontiers of Chemical Engineering in China - Tập 5 - Trang 308-313 - 2011
Shujuan Sun, Lei Wang, Suiliang Huang, Teng Tu, Hongwen Sun
A microcosm system that included river sediment, water and different zeolite
capping materials (natural zeolite, surfactant-modified zeolite (SMZ), or
aluminum modified zeolite (AMZ)) was designed to study the effect of capping on
the release of phosphorus and three organic pollutants (phenol, pyridine, and
pyrene) from the sediment to the overlying water over the course of three month.
For the sa... hiện toàn bộ