Synthesis of ordered cerium-doped cubic mesoporous silica using long-chain ionic liquid as templateFrontiers of Chemical Engineering in China - Tập 2 - Trang 135-139 - 2008
Hongxia Yue, Hongmei Zhao, Longjiang Liu, Siping Wang, Qiong Ruan, Tongwen Wang
The long-chain ionic liquid 1-hexadecyl-3-methylimidazolium chloride (C16mimCl) was used as a template to prepare cerium-doped MCM-48 materials in basic medium by a hydrothermal synthesis procedure. The effect of the amount of Ce salt and C16mimCl/Si on the synthesis were discussed in detail. This mesoporous material exhibits a pore architecture which is cubic Ia3d gyroid and possesses a large sur...... hiện toàn bộ
Monte Carlo simulation of the diffusion-limited aggregating process of particle suspension systemsFrontiers of Chemical Engineering in China - Tập 4 - Trang 270-274 - 2009
Jiajing Xu, Wei Dai, Wenwen Shan, Lin Zhang, Yongjian Tang
The aggregating process of particle suspension systems is a very universal phenomena and crucial for various processes both in nature and in industry. In this paper, the aggregating process was simulated with offlattice diffusion-limited cluster-cluster aggregation (DLCA) Monte Carlo programs. The self-similar fractal structures of aggregates have been clearly demonstrated by the statistical analy...... hiện toàn bộ
Spectrokinetics study of probable effects of diverse inorganic ions on bleaching of dyeFrontiers of Chemical Engineering in China - Tập 5 - Trang 131-138 - 2010
Rafia Azmat, Masooda Qadri, Fahim Uddin
Toluidine blue (TB) is an important anticoagulant metachromasia molecule showing a pronounced variation in the visible spectrum due to the aggregation phenomenon and electrostatic interaction with the charged synthetic and biologic polymers. The current study describes the interactive role of diverse inorganic material ions on the bleaching of toluidine blue (tolonium chloride) (TB+) with urea in ...... hiện toàn bộ
CO2 and H2 selectivity properties of PDMS/PSf membrane prepared at different conditionsFrontiers of Chemical Engineering in China - Tập 5 - Trang 500-513 - 2011
S. A. A. Mansoori, M. Pakizeh, A. Jomekian
The effects of different solvent/water coagulation mediums, different coagulation bath temperatures (CBT) and different coagulants on the performance, morphology and thermal stability of polysulfone membranes were investigated. The CO2/CH4, H2/CH4 and H2/N2 separation performance of the membranes were studied by gas permeation. Changing the N,N-dimethyl acetamide (DMAc)/water coagulation medium ra...... hiện toàn bộ
Protein microspheres for pulmonary drug deliveryFrontiers of Chemical Engineering in China - Tập 4 - Trang 82-86 - 2010
Yongda Sun
A new supercritical fluid (SCF) technique was developed for the preparation of microspheres for pulmonary drug delivery (PDD). This technique, based on the anti-solvent process, has incorporated advanced engineering design features to enable improved control of the particle formation process. Human recombinant insulin (HRI) was used as a model compound to evaluate the efficiency of this SCF proces...... hiện toàn bộ
Regioselective acylation of pyridoxine catalyzed by immobilized lipase in ionic liquidFrontiers of Chemical Engineering in China - Tập 2 - Trang 301-307 - 2008
Shu Bai, Mengyuan Ren, Lele Wang, Yan Sun
The regioselective acylation of pyridoxine catalyzed by immobilized lipase (Candida Antarctica) in 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM]PF6) has been investigated, and compared with that in acetonitrile (ACN). The acetylation of pyridoxine using acetic anhydride in [BMIM]PF6 gave comparable conversion of pyridoxine to 5-monoacetyl pyridoxine with considerably higher regioselectiv...... hiện toàn bộ
A review on research and development of iron-based sorbents for removal of hydrogen sulfide from hot coal gasesFrontiers of Chemical Engineering in China - Tập 4 - Trang 529-535 - 2010
Jianglong Yu, Liping Chang, Fan Li, Kechang Xie
In poly-generation and integrated gasification-combined cycle (IGCC) systems for clean energy conversion, it is essential to remove impurities such as sulfur species from hot coal gases prior to entering the subsequent units. This paper provides a comprehensive review on previous studies on high temperature removal of hydrogen sulfide from high temperature coal gases using iron-based sorbents. A t...... hiện toàn bộ
Sensitivity analysis of a methanol and power polygeneration system fueled with coke oven gas and coal gasFrontiers of Chemical Engineering in China - Tập 4 - Trang 491-497 - 2010
Guoqiang Zhang, Lin Gao, Hongguang Jin, Rumou Lin, Sheng Li
The sensitivity analysis of a polygeneration energy system fueled with duo fuel of coke oven gas and coal gas is performed in the study, and the focus is put on the relations among syngas composition, conversation rate and performance. The impacts of the system configuration together with the fuel composition on the performance are investigated and discussed from the point of cascading utilization...... hiện toàn bộ
Kinetic model for hydroisomerization reaction of C8-aromaticsFrontiers of Chemical Engineering in China - Tập 2 - Trang 10-16 - 2008
Ouguan Xu, Hongye Su, Xiaoming Jin, Jian Chu
Based on the reported reaction networks, a novel six-component hydroisomerization reaction network with a new lumped species including C8-naphthenes and C8-paraffins is proposed and a kinetic model for a commercial unit is also developed. An empirical catalyst deactivation function is incorporated into the model accounting for the loss in activity because of coke formation on the catalyst surface ...... hiện toàn bộ
Studies on the liquid-liquid interfacial mass transfer process using holographic interferometryFrontiers of Chemical Engineering in China - Tập 2 - Trang 1-4 - 2008
Chaofan Zhao, Youguang Ma, Chunying Zhu
This paper aims at the interfacial phenomena of liquid-liquid mass transfer and its characteristic. By using the real-time holographic technique, the concentration distributions on the aqueous side were obtained according to holographic diagrams of mass transfer of ethanol through the interface of oil and water at different initial concentrations. Furthermore, the concentrations near the interface...... hiện toàn bộ