n-Alkane hydroconversion over carbided molybdena supported on sulfated zirconia

Applied Petrochemical Research - Tập 1 Số 1-4 - Trang 35-43 - 2012
Ahmad Galadima1, Richard Wells1, James A. Anderson1
1Surface Chemistry and Catalysis Group Chemistry Department, University of Aberdeen, AB24 3UE, Aberdeen, UK

Tóm tắt

Từ khóa


Tài liệu tham khảo

Ahmad R, Melsheimer J, Johntoff FC, Schlogl R (2003) Isomerisation of n-butane and n-pentane in the presence of sulphated zirconia: formation of surface deposits investigated by In situ UV–vis diffuse reflectance spectroscopy. J Catal 218(2):365–374

Allain JF, Magnoux R, Schulz MPh, Guisnet M (1997) Hydroisomerization of n-hexane over platinum mazzite and platinum mordenite catalysts kinetics and mechanism. Appl Catal A: Gen 152:221–235

Anderson JA, Mordente MGV, Rochester CH (1989) Effects of oxidation/reduction on Pt/Al2O3 on catalytic activity and selectivity for hexane reforming. J Chem Soc Faraday Trans 1(85):2991–2998

Bensitel M, Saur O, Lavelley JC (1988) An infrared study of sulfated zirconia. Mater Chem Phys I 9(1988):141–156

Bussell ME, Sawhill SJ, Layman KA, Burns AW (2003) New catalysts for. hydrodesulfurization. Fuel Chem Div Prepr 48(1):177–179

Chary KVR, Reddy KR, Kishan G, Niemantsverdriet JW, Mestl G (2004) Structure and catalytic properties of molybdenum oxide catalysts supported on zirconia. J Catal 226:283–291

Cheng MF, Kumata T, Saito T, Komatsu T, Yashima   (1999) Preparation and characterization of Mo catalysts over AlMCM-41/γ-Al2O3 extruded supports. Appl Catal A: Gen 183(1):199–208

Christodoulakis A, Boghison S (2008) Molecular structure and activity of molybdena catalysts supported on zirconia for ethane oxidative dehydrogenation studied by Operando Raman Spectroscopy. J Catal 260:178–187

Comelli RA, Vera CR, Parera JM (1995) Influence of ZrO2 crystalline structure and sulfate ion concentration on the catalytic activity of SO42−- ZrO2. J Catal 151:96–101

Da Costa P, Potvin C, Manoli J, Genin B, Djega-Mariadassuo G (2004) Deep hydrodesulphurization and hydrogenation of diesel fuels on alumina-supported and bulk molybdenum carbide catalysts. Fuel 83(13):1717–1726

De Gauw, F.J.M.M (2002) Kinetic studies of alkane hydroisomerization over solid acid catalysts. PhD Thesis, Eindhoven University of Technology, Netherlands. Available from: http://alexandria.tue.nl/extra2/200210842.pdf

De Lucas A, Valverde JL, Sánchez P, Dorado F, Ramos MJ (2004) Influence of the binder on the n-octane hydroisomerization over palladium-containing zeolite catalyststs. Ind Eng Chem Res 43:8217

De Lucas A, Valverde JL, Sánchez P, Dorado F, Ramos MJ (2005) Hydroisomerization of n-octane over platinum catalysts with or without binder. Appl Catal 282:15–24

De Lucas A, Sánchez P, Dorado F, Ramos MJ, Valverde JL (2006) Kinetic model of the n-octane hydroisomerization on ptbeta agglomerated catalyst: influence of the reaction conditions. Ind Eng Chem Res 45(3):978–985

Faraldos M, Bañares MA, Anderson JA, Hu H, Wachs IE, Fierro JLG (1996) Comparison of silica supported MoO3 and V2O5 catalysts in the selective oxidation of methane. J Catal 160:214–221

Groten WA, Wojciechowski BW (1993) The kinetics of hydrocarbon cracking : the cracking of n-nonane. J Catal 140:262–280

Hanif A, Xiao T, York APE, Sloan J, Gren MLH (2002) Study on the structure and formation mechanism of molybdenum carbides. Chem Mater 14:1009–1015

Hunter KC, East ALL (2002) Properties of C–C bonds in n-Alkanes: Relevance to cracking mechanisms. J Phys Chem A 106(7):1346–1356

Iglesia E, Soled SL, Kramer GM (1993) Isomerization of alkanes on sulfated zirconia: promotion by Pt and by adamantyl hydride transfer species. J Catal 144:238–253

Jung KT, Kim WB, Rhee CH, Lee JS (2004) Effects of transition metal addition on the solid state transformation of molybdenum trioxide to molybdenum carbides. Chem Mater 16:307–314

Kinger G, Vinek H (2001) n-Nonane hydroconversion on Ni and Pt containing HMFI, HMOR and HBEA. Appl Catal A: Gen 218(2001):139–149

Kinger G, Majdal D, Vinek H (2002) n-Heptane hydroisomerization over Pt-containing mixtures of zeolites with inert materials. Appl Catal A: Gen 225(2002):301–312

Komatsu T (2010) Catalytic cracking of paraffins on zeolite catalysts for the production of light olefins. In: 20th Annual Saudi-Japan Symposium; Catalysts in Petroleum Refining and Petrochemicals, Dharan, Saudi-Arabia, December, 2010

Kozhevnikov IV (1998) Catalysis by heteropoly acids and multicomponent polyoxometalates in liquid-phase reactions. Chem Rev 98:171–198

Lei T, Xu JS, Gao Z (1999) Acidity enhancement of H-mordenite by sulfation. Mater Chem Phys 60(2):177–181

Lu L, Hugosson H, Eriksson O, Nordstrom L, Jansson U (2000) Chemical vapour deposition of molybdenum carbides: aspects of phase stability. Thin Solid Films 370(17):203–212 (1–2)

Lungstein A, Jentys A, Vinek H (1999) Hydroisomerization and cracking of n-octane and C8 isomers on Ni-containing zeolites. Appl Catal A: Gen 176:119–128

Meunier FC, Yasmeen A, Ross JRH (1997) Oxidative dehydrogenation of propane over molybdena-containing catalysts. Catal Today 37:33–43

Miyao T, Shishikura I, Matuoka M, Magai M, Oyama ST (1997) Preparation and characterization of alumina-supported molybdenum carbide. Appl Catal A: Gen 165:419–428

Mokaya R, Jones W, Moreno S, Poncelet G (1997) n-Heptane hydroconversion over aluminosilicate mesoporous molecular sieves. Catal Lett 49:87–94

Moushey DL, Smirniotis PG (2009) n-Heptane hydroisomerisation over mesoporous zeolites made by utilizing carbon particles as the template for mesoporosity. Catal Lett 129:20–25

Ono Y (2003) A survey of the mechanism in catalytic isomerization of alkanes. Catal Today 81:3–16

Rosenberg DJ, Bachiller-Baeza B, Dines TJ, Anderson JA (2003) Nature of surface sulfate species and the generation of active sites on silica-zirconia mixed-oxide catalysts. J Phys Chem B 107:6526

Saito M, Anderson RB (1980) The activity of several molybdenum compounds for the methanation of CO. J Catal 63:438–446

Solymosi F, Barthos R (2005) Aromatization of n-hexane on Mo2C catalysts. Catal Letters. 101(3–4):235–239

Stichert W, Schüth F, Kuba S, Knözinger H (2001) Monoclinic and tetragonal high surface area sulfated zirconias in butane isomerization: CO adsorption and catalytic results. J Catal 198:277–285

Travers C, Essayemb N, Delaga M, Quelen S (2001) Heteropolyanions based catalysts for paraffins isomerization. Catal Today 65:355–361

Vera CR, Pieck CL, Shimizu K, Querini CA, Parera JM (1999) Coking of SO42−–ZrO2 catalysts during isomerization of n-butane and its relation to the reaction mechanism. J Catal 187:39–49

Wang X, Hao H, Zhang M, Li W, Tao K (2006) Synthesis and characterization of molybdenum carbides using propane as carbon source. J Solid State Chem 179:538–543

Woltz C, Jentys A, Lercher JA (2006) Improving bifunctional zeolite catalysts for alkane hydroisomerization via gas phase sulfation. J Catal 237:337–348

Xiao T, York APE, Williams VC, Almegren H, Hani A, Zhou X, Green MLH (2000) Preparation of molybdenum carbides using butane and their catalytic performance. Chem Mater 12:3896–3905

Xu B, Sachtler WMH (1997) Reduction of SO 4 = ions in sulfated zirconia catalysts. J Catal 167(1):224–233

York APE, Pham-Huu C, Gallo PE, Ledoux MJ (1997) Molybdenum oxycarbide hydrocarbon isomerization catalysts: cleaner fuels for the future. Catal Today 35:51–57

Zdrazil M (2001) Supported MoO3 catalysts: preparation by the new “slurry impregnation” method and activity in hydrodesulphurization. Catal Today 65:301–306

Zhu Q, Chen Q, Yang X, Ke D (2007) A new method for the synthesis of molybdenum carbide. Mater Letters 61:5173–5174