XRD-based quantitative analysis of clay minerals using reference intensity ratios, mineral intensity factors, Rietveld, and full pattern summation methods: A critical review

Solid Earth Sciences - Tập 3 Số 1 - Trang 16-29 - 2018
Xiang Zhou1,2, Dong Liu1, Hongling Bu1, Liangliang Deng1,2, Hongmei Liu1, Peng Yuan1, Peixin Du1,2, Hongzhe Song1,2
1CAS Key Laboratory of Mineralogy and Metallogeny/Guangdong Provincial Key Laboratory of Mineral Physics and Materials, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Wushan, Guangzhou 510640, China
2University of Chinese Academy of Sciences, Beijing, 100049, China

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Aburto, 2016, Thermal analysis mineral quantification and applications as a relative dating tool in moraine chronosequences, Soil Sci. Soc. Am. J., 80, 502, 10.2136/sssaj2015.08.0307

Alexander, 1948, Basic aspects of X-ray absorption in quantitative diffraction analysis of powder mixtures, Anal. Chem., 20, 886, 10.1021/ac60022a002

Alves, 2009, Improving Rietveld-based clay mineralogic quantification of oxisols using Siroquant, Soil Sci. Soc. Am. J., 73, 2191, 10.2136/sssaj2008.0365

Artioli, 1995, Nature of structural disorder in natural kaolinites: a new model based on computer simulation of powder diffraction data and electrostatic energy calculation, Clay Clay Miner., 43, 438, 10.1346/CCMN.1995.0430407

Ban, 1992, Structure refinement of mullite by the Rietveld method and a new method for estimation of chemical composition, J. Am. Cera. Soc, 75, 227, 10.1111/j.1151-2916.1992.tb05473.x

Batchelder, 1998, Rapid, accurate phase quantification of clay-bearing samples using a position-sensitive X-ray detector, Clay Clay Miner., 46, 183, 10.1346/CCMN.1998.0460209

Bergaya, 2006, General introduction: clays, clay minerals, and clay science, vol. 1, 1

Bergmann, 1998, BGMN − a new fundamental parameter based Rietveld program for laboratory X-ray sources, its use in quantitative analysis and structure investigations. Commission of Powder Diffraction. International Union of Crystallography, CPD Newsl, 20, 5

Bish, 1993, Studies of clays and clay minerals using X-ray powder diffraction and the Rietveld method, vol. 5, 79

Bish, 1994, Quantitative X-ray diffraction analysis of soils, 267

Bish, 1988, Quantitative phase analysis using the Rietveld method, J. Appl. Crystallogr., 21, 86, 10.1107/S0021889887009415

Bish, 1993, Quantitative mineralogical analysis using the Rietveld full-pattern fitting method, Am. Mineral., 78, 932

Bish, 1989, Sample preparation for X-ray diffraction, 73

Bishop, 2011, Bioreduction of Fe-bearing clay minerals and their reactivity toward pertechnetate (Tc-99), Geochim. Cosmochim. Acta, 75, 5229, 10.1016/j.gca.2011.06.034

Blake, 2012, Characterization and calibration of the CheMin mineralogical instrument on Mars science laboratory, Space Sci. Rev., 170, 341, 10.1007/s11214-012-9905-1

Bleicher, 2000, Development of a graphical interface for the Rietveld refinement program DBWS, J. Appl. Crystallogr., 33, 1189, 10.1107/S0021889800005410

Bradley, 1940, The structure scheme of attapulgite, Am. Mineral., 25, 405

Brindley, 1980, Quantitative X-ray mineral analysis of clays, 411

Camilleri, 2008, Characterization of hydration products of mineral trioxide aggregate, Int. Endod. J., 41, 408, 10.1111/j.1365-2591.2007.01370.x

Carter, 1987, Quantitative analysis of quartz and cristobalite in bentonite clay based products by X-ray diffraction, Anal. Chem., 59, 513, 10.1021/ac00130a030

Cheshire, 2013, Alteration of clinoptilolite into high-silica analcime within a bentonite barrier system under used nuclear fuel repository conditions, 410

Chipera, 1995, Multireflection RIR and intensity normalizations for quantitative analyses: applications to feldspars and zeolites, Powder Diffr., 10, 47, 10.1017/S0885715600014305

Chipera, 2002, FULLPAT: a full-pattern quantitative analysis program for X-ray powder diffraction using measured and calculated patterns, J. Appl. Crystallogr., 35, 744, 10.1107/S0021889802017405

Chipera, 2013, Fitting full x-ray diffraction patterns for quantitative analysis: a method for readily quantifying crystalline and disordered phases, Adv. Mater. Phys. Chem., 03, 47, 10.4236/ampc.2013.31A007

Christidis, 2006, Influence of layer charge and charge distribution of smectites on the flow behaviour and swelling of bentonites, Appl. Clay Sci., 34, 125, 10.1016/j.clay.2006.05.008

Chung, 1974, Quantitative interpretation of X-ray diffraction patterns of mixtures. I. Matrix-flushing method for quantitative multicomponent analysis, J. Appl. Crystallogr., 7, 519, 10.1107/S0021889874010375

Chung, 1975, Quantitative interpretation of X-ray diffraction patterns of mixtures. III. Simultaneous determination of a set of reference intensities, J. Appl. Crystallogr., 8, 17, 10.1107/S0021889875009454

Clark, 1936, Quantitative analysis of mine Dusts, Ind. Eng. Chem. Anal. Ed, 8, 36, 10.1021/ac50099a015

Clark, 1936, X-ray diffraction studies of chitin, chitosan, and derivatives, J. Phys. Chem., 40, 863, 10.1021/j150376a001

Clark, 1973, The use of calculated X-ray powder patterns in the interpretation of quantitative analysis, 45

Criado, 2007, An XRD study of the effect of the SiO2/Na2O ratio on the alkali activation of fly ash, Cem. Concr. Res, 37, 671, 10.1016/j.cemconres.2007.01.013

Deng, 2015, Quantitative phase analysis by the Rietveld method for Forensic science, J. Forensic Sci., 60, 1040, 10.1111/1556-4029.12755

Derkowski, 2009, Partial dissolution of glauconitic samples: implications for the methodology of K-Ar and Rb-Sr dating, Clay Clay Miner., 57, 531, 10.1346/CCMN.2009.0570503

Dollase, 1986, Correction of intensities for preferred orientation in powder diffractometry: application of the March model, J. Appl. Crystallogr., 19, 267, 10.1107/S0021889886089458

Drits, 1990, 371

Drits, 1994, A simple technique for identification of one-dimensional powder X-ray diffraction patterns for mixed-layer illite-smectites and other interstratified minerals, Clay Clay Miner., 42, 382, 10.1346/CCMN.1994.0420402

Eberl, 2003

Eberl, 2004, Quantitative mineralogy of the Yukon River system: changes with reach and season, and determining sediment provenance, Am. Mineral., 89, 1784, 10.2138/am-2004-11-1225

von Engelhardt, 1955, Möglichkeiten der quantitativen Röntgenanalyse von Mineralgemischen (abgekürzte Zusammenfassung), Geol. Rundsch., 43, 568, 10.1007/BF01764042

Fan, 2009, Core –shell structured iron nanoparticles well dispersed on montmorillonite, J. Magn. Magn Mater., 321, 3515, 10.1016/j.jmmm.2009.06.060

Fuentes-Montero, 2007, A simplified Rietveld code for quantitative phase analysis: development, test and application to uranium mineral So, Rev. Mexic. Fisica, 53, 108

Fujio, 1989, Rietan: a software package for the rietveld analysis and simulation of x-ray and neutron diffraction patterns, The Rigaku Jounal, 6, 10

Garrels, 1971

Gibbs, 1967, Quantitative X-ray diffraction analysis using clay minerals standards extracted from the samples to be analyzed, Clay Miner., 7, 79, 10.1180/claymin.1967.007.1.07

Griffin, 1968, The distribution of clay minerals in the world ocean, Deep Sea Res. Oceanogr. Abstr., 15, 433, 10.1016/0011-7471(68)90051-X

Gruner, 1934, The structures of vermiculite and their collapse by dehydration, Am. Mineral., 19, 557

Gruner, 1935, Structural relations of nontronites and montmorillonites, Am. Mineral., 20, 475

Gruner, 1935, The structural relationship of glauconite and mica, Am. Mineral., 20, 699

Gruner, 1939, Water layers in vermiculite, Am. Mineral., 24, 428

Gualtieri, 2010, Thermal conductivity of fired clays: effects of mineralogical and physical properties of the raw materials, Appl. Clay Sci., 49, 269, 10.1016/j.clay.2010.06.002

Guggenheim, 1995, Definition of clay and clay mineral: joint report of the AIPEA nomenclature and CMS nomenclature committees, Clay Clay Miner., 43, 255, 10.1346/CCMN.1995.0430213

Haumont, 2009, Effect of high pressure on multiferroic BiFeO3, Phys. Rev. B, 79, 184110, 10.1103/PhysRevB.79.184110

He, 2010, Organoclays prepared from montmorillonites with different cation exchange capacity and surfactant configuration, Appl. Clay Sci., 48, 67, 10.1016/j.clay.2009.11.024

Hillier, 1999, Use of an air brush to spray dry samples for X-ray powder diffraction, Clay Miner., 34, 127, 10.1180/000985599545984

Hillier, 2000, Accurate quantitative analysis of clay and other minerals in sandstones by XRD: comparison of a Rietveld and a reference intensity ratio (RIR) method and the importance of sample preparation, Clay Miner., 35, 291, 10.1180/000985500546666

Hooshiar, 2012, Clay minerals in nonaqueous extraction of bitumen from Alberta oil sands: Part 2. Characterization of clay minerals, Fuel Process. Technol., 96, 183, 10.1016/j.fuproc.2011.10.010

Hubbard, 1988, RIR − measurement and use in quantitative XRD, Powder Diffr., 3, 74, 10.1017/S0885715600013257

Hubbard, 1976, The reference intensity ratio, I/Ic, for computer simulated powder patterns, J. Appl. Crystallogr., 9, 169, 10.1107/S0021889876010807

Hurst, 1997, Accurate quantification of quartz and other phases by powder X-ray diffractometry, Anal. Chim. Acta, 337, 233, 10.1016/S0003-2670(96)00425-4

Hutton, 1996, Quantitative XRD measurement of mineral matter in Gondwana coals using the Rietveld method, J. Afr. Earth Sci., 23, 61, 10.1016/S0899-5362(96)00052-8

Jacobs, 1972, Paleo-climatic events indicated by mineralogical changes in deep-sea sediments, J. Sediment. Petrol., 42, 889

Jahanbagloo, 1968, Quantitative analysis with the aid of calculated X-ray powder patterns, Anal. Chem., 40, 1739, 10.1021/ac60267a043

Järvinen, 1993, Application of symmetrized harmonics expansion to correction of the preferred orientation effect, J. Appl. Crystallogr., 26, 525, 10.1107/S0021889893001219

Ji, 2012, Experimental investigation of main controls to methane adsorption in clay-rich rocks, Appl. Geochem., 27, 2533, 10.1016/j.apgeochem.2012.08.027

Jones, 2000, Estimation of the total amorphous content of hawai'i soils by the Rietveld method, Soil Sci. Soc. Am. J., 64, 1100, 10.2136/sssaj2000.6431100x

Jordá, 2015, Mineralogical analysis of ceramic tiles by FTIR: a quantitative attempt, Appl. Clay Sci., 115, 1, 10.1016/j.clay.2015.07.005

Kaduk, 2009, The 2009 annual meeting of the american crystallographic association, Powder Diffr., 24, 365, 10.1154/1.3261736

Kahle, 2002, Review of XRD-based quantitative analyses of clay minerals in soils: the suitability of mineral intensity factors, Geoderma, 109, 191, 10.1016/S0016-7061(02)00175-1

Kaminsky, 2009, Distribution of clay minerals in the process streams produced by the extraction of bitumen from Athabasca oil sands, Can. J. Chem. Eng., 87, 85, 10.1002/cjce.20133

Keeling, 2000, Geology and characterization of two hydrothermal nontronites from weathered metamorphic rocks at the Uley graphite mine, South Australia, Clay Clay Miner., 48, 537, 10.1346/CCMN.2000.0480506

Kemper, 1972, The crystal structure of potassium hydrogeniodate (V), KIO3·HIO3, Can. J. Chem., 50, 1134, 10.1139/v72-180

Kleeberg, 2016, 48

Kleeberg, 2008, Preferred orientation of mineral grains in sample mounts for quantitative XRD measurements: how random are powder samples?, Clay Clay Miner., 56, 404, 10.1346/CCMN.2008.0560402

Kuila, 2013, Specific surface area and pore-size distribution in clays and shales, Geophys. Prospect., 61, 341, 10.1111/1365-2478.12028

Larson, 1994

Leroux, 1953, Direct quantitative X-ray analysis by diffraction-absorption technique, Anal. Chem., 25, 740, 10.1021/ac60077a017

Lippmann, 1970, Functions describing preferred orientation in flat aggregates of flake-like clay minerals and in other axially symmetric fabrics, Contrib. Mineral. Petrol., 25, 77, 10.1007/BF00389778

Liu, 2011, Influence of heating on the solid acidity of montmorillonite: a combined study by DRIFT and Hammett indicators, Appl. Clay Sci., 52, 358, 10.1016/j.clay.2011.03.016

Liu, 2013, Quantitative characterization of the solid acidity of montmorillonite using combined FTIR and TPD based on the NH3 adsorption system, Appl. Clay Sci., 80–81, 407, 10.1016/j.clay.2013.07.006

Liu, 2013, High-pressure adsorption of methane on montmorillonite, kaolinite and illite, Appl. Clay Sci., 85, 25, 10.1016/j.clay.2013.09.009

Liu, 2013, Studies on the solid acidity of heated and cation-exchanged montmorillonite using n-butylamine titration in non-aqueous system and diffuse reflectance Fourier transform infrared (DRIFT) spectroscopy, Phys. Chem. Miner., 40, 479, 10.1007/s00269-013-0585-5

Liu, 2013, Effects of solid acidity of clay minerals on the thermal decomposition of 12-aminolauric acid, J. Therm. Anal. Calorim., 114, 125, 10.1007/s10973-012-2887-0

Liu, 2013, Thermal degradation of organic matter in the interlayer clay–organic complex: a TG-FTIR study on a montmorillonite/12-aminolauric acid system, Appl. Clay Sci., 80–81, 398, 10.1016/j.clay.2013.07.005

Lutterotti, 1990, Simultaneous structure and size-strain refinement by the Rietveld method, J. Appl. Crystallogr., 23, 246, 10.1107/S0021889890002382

Madsen, 2012, Quantitative phase analysis using the Rietveld method, 283

McCarty, 2002, 12

Mertens, 2006, Use of quantitative X-ray diffraction for academic and industrial applications. Abstracts of Industrial mineralogy, Acta Cryst., A62, s209, 10.1107/S0108767306095821

Mooney, 1952, Adsorption of water vapor by montmorillonite. II. Effect of exchangeable ions and lattice swelling as measured by X-ray diffraction, J. Am. Chem. Soc., 74, 1371, 10.1021/ja01126a002

Moore, 1997

Mumme, 1996, Improved petrological modal analyses from X-ray powder diffraction data by use of the Rietveld method; Part II, Selected sedimentary rocks, J. Sediment. Res., 66, 132

Nagelschmidt, 1938, On the atomic arrangement and variability of the members of montmorillonite group, Mineral. Mag., 25, 140, 10.1180/minmag.1938.025.162.05

Nosrati, 2012, Gelation of aqueous clay mineral dispersions leaching at low pH: effect of mineral/pulp composition and temperature, Powder Technol., 223, 98, 10.1016/j.powtec.2011.07.022

Okada, 2006, Solid acidity of 2 : 1 type clay minerals activated by selective leaching, Appl. Clay Sci., 31, 185, 10.1016/j.clay.2005.10.014

Omotoso, 2006, Some successful approaches to quantitative mineral analysis as revealed by the 3rd Reynolds Cup contest, Clay Clay Miner., 54, 748, 10.1346/CCMN.2006.0540609

Plançon, 1975, Etude des fautes d'empilement dans les kaolinites partiellement désordonnées. I. Modèle d'empilement ne comportant que des fautes de translation, J. Appl. Crystallogr., 8, 582, 10.1107/S0021889875011429

Plötze, 2014, Quantitative mineral analysis of complex mineral assemblages – the Reynolds Cup round robins in clay analysis, 8

Post, 1989, Rietveld refinement of crystal structures using powder X-ray diffraction data, 277

Quakernaat, 1970, Direct diffractometric quantitative analysis of synthetic clay mineral mixtures with molybdenite as orientation indicator, J. Sediment. Res., 40, 506, 10.1306/74D71FA5-2B21-11D7-8648000102C1865D

Rateev, 1969, The distribution of clay minerals in the oceans, Sedimentology, 13, 21, 10.1111/j.1365-3091.1969.tb01119.x

Raven, 2015, Outcomes of 12 years of the Reynolds Cup quantitative mineral analysis round robin, 171

Reynolds, 1985

Rietveld, 1969, A profile refinement method for nuclear and magnetic structures, J. Appl. Crystallogr., 2, 65, 10.1107/S0021889869006558

Rodriguez-Carvajal, 1990, Fullprof: a program for Rietveld refinement and pattern matching analysis

Ross, 1931, The clay minerals and their identity, J. Sediment. Petrol., 1, 55

Salyn, 1972, On the method of X-ray quantitative phase analysis of clays, 797

Santini, 2015, Application of the Rietveld refinement method for quantification of mineral concentrations in bauxite residues (alumina refining tailings), Int. J. Miner. Process., 139, 1, 10.1016/j.minpro.2015.04.004

Scarlett, 2002, Outcomes of the International Union of Crystallography Commission on powder diffraction round robin on quantitative phase analysis: samples 2, 3, 4, synthetic bauxite, natural granodiorite and pharmaceuticals, J. Appl. Crystallogr., 35, 383, 10.1107/S0021889802008798

Schneider, 1991, GUFI-WYRIET: an integrated PC powder pattern analysis package, Mater. Sci. Forum, 79-82, 277, 10.4028/www.scientific.net/MSF.79-82.277

Scrivener, 2004, Quantitative study of Portland cement hydration by X-ray diffraction/Rietveld analysis and independent methods, Cem. Concr. Res, 34, 1541, 10.1016/j.cemconres.2004.04.014

Singer, 1984, The paleoclimatic interpretation of clay minerals in sediments- a review, Earth Sci. Rev., 21, 251, 10.1016/0012-8252(84)90055-2

Sleight, 1979, Crystal growth and structure of BiVO4, Mater. Res. Bull., 14, 1571, 10.1016/0025-5408(72)90227-9

Smith, 1987, Quantitative X-Ray powder diffraction method using the full diffraction pattern, Powder Diffr., 2, 73, 10.1017/S0885715600012409

Snyder, 1989, Quantitative analysis, vol. 20, 101

Środoń, 2002, Quantitative mineralogy of sedimentary rocks with emphasis on clays and with applications to K-Ar dating, Mineral. Mag., 66, 677, 10.1180/0026461026650055

Środoń, 2013, Identification and quantitative analysis of clay minerals, 25, 10.1016/B978-0-08-098259-5.00004-4

Środoń, 2012, Mineral compositional trends and their correlations with petrophysical and well-logging parameters revealed by Quanta + Bestmin analysis: miocene of the Carpathian Foredeep, Poland, Clay Clay Miner., 60, 63, 10.1346/CCMN.2012.0600106

Środoń, 2008, Surface area and layer charge of smectite from CEC and EGME/H2O retention measurements, Clay Clay Miner., 56, 155, 10.1346/CCMN.2008.0560203

Środoń, 2001, Quantitative X-ray diffraction analysis of clay-bearing rocks from random preparations, Clay Clay Miner., 49, 514, 10.1346/CCMN.2001.0490604

Środoń, 2006, Diagenetic history of the Podhale-Orava Basin and the underlying Tatra sedimentary structural units (Western Carpathians): evidence from XRD and K-Ar of illite-smectite, Clay Miner., 41, 751, 10.1180/0009855064130217

Szczerba, 2009, Extraction of diagenetic and detrital ages and of the 40Kdetrital/40Kdiagenetic ratio from K-Ar dates of clay fractions, Clay Clay Miner., 57, 93, 10.1346/CCMN.2009.0570109

Tanaka, 1980, X-ray diffraction profile analysis for the determination of the crystal structure of BaTiO3, Jpn. J. Appl. Phys., 19, 1757, 10.1143/JJAP.19.1757

Taut, 1998, Seifert Software: The new Seifert Rietveld program BGMN and its application to quantitative phase analysis, Mater. Struct., 5, 57

Taylor, 1978

Taylor, 1991, Computer programs for standardless quantitative analysis of minerals using the full powder diffraction profile, Powder Diffr., 6, 2, 10.1017/S0885715600016778

Taylor, 1994, A new method for Rietveld clay analysis. Part I. Use of a universal measured standard profile for Rietveld quantification of montmorillonites, Powder Diffr., 9, 119, 10.1017/S0885715600014093

Taylor, 1992, Simultaneous use of observed and calculated standard profiles in quantitative XRD analysis of minerals by the multiphase Rietveld method: the determination of pseudorutile in mineral sands products, Powder Diffr., 7, 152, 10.1017/S0885715600018510

Tebbens, 1998, The impact of climate change on the bulk and clay geochemistry of fluvial residual channel infillings: the Late Weichselian and Early Holocene river Meuse sediments (the Netherlands), J. Quat. Sci., 13, 345, 10.1002/(SICI)1099-1417(199807/08)13:4<345::AID-JQS384>3.0.CO;2-B

Toby, 2001, EXPGUI, a graphical user interface for GSAS, J. Appl. Cryst, 34, 210, 10.1107/S0021889801002242

Tributh, 1991, Qualitative und "quantitative" Bestimmung der Tonminerale in Bodentonen, 37

Ufer, 2004, Description of X-ray powder pattern of turbostratically disordered layer structures with a Rietveld compatible approach, Z. Kristallogr., 219, 519

Ufer, 2008, Quantitative phase analysis of bentonites by the Rietveld method, Clay Clay Miner., 56, 272, 10.1346/CCMN.2008.0560210

Ufer, 2012, Rietveld refinement of disordered illite-smectite mixed-layer structures by a recursive algorithm. II: powder-pattern refinement and quantitative phase analysis, Clay Clay Miner., 60, 535, 10.1346/CCMN.2012.0600508

Ufer, 2015, Quantification of stacking disordered Si–Al layer silicates by the Rietveld method: application to exploration for high-sulphidation epithermal gold deposits, Powder Diffr., 30, S111, 10.1017/S0885715615000111

Van der Marel, 1966, Quantitative analysis of clay minerals and their admixtures, Contrib. Mineral. Petrol., 12, 96, 10.1007/BF02651130

Vaniman, 2014

Viani, 2002, The nature of disorder in montmorillonite by simulation of X-ray powder patterns, Am. Mineral., 87, 966, 10.2138/am-2002-0720

Viennet, 2015, Investigation of clay mineralogy in a temperate acidic soil of a forest using X-ray diffraction profile modeling: beyond the HIS and HIV description, Geoderma, 241–242, 75, 10.1016/j.geoderma.2014.11.004

Visser, 1964

Wang, 2013, Clay mineralogy indicates the Holocene monsoon climate in the Changjiang (Yangtze River) Catchment, China, Appl. Clay Sci., 74, 28, 10.1016/j.clay.2012.08.011

Ward, 2006, Determination of glass content and estimation of glass composition in fly ash using quantitative X-ray diffractometry, Fuel, 85, 2268, 10.1016/j.fuel.2005.12.026

Weidler, 1998, The Rietveld method applied to the quantitative mineralogical and chemical analysis of a ferralitic soil, Eur. J. Soil Sci., 49, 95, 10.1046/j.1365-2389.1998.00138.x

Yuan, 2008, A combined study by XRD, FTIR, TG and HRTEM on the structure of delaminated Fe-intercalated/pillared clay, J. Colloid Interface Sci., 324, 142, 10.1016/j.jcis.2008.04.076

Yuan, 2009, Montmorillonite-supported magnetite nanoparticles for the removal of hexavalent chromium [Cr(VI)] from aqueous solutions, J. Hazard Mater., 166, 821, 10.1016/j.jhazmat.2008.11.083

Yuan, 2013, From platy kaolinite to aluminosilicate nanoroll via one-step delamination of kaolinite: effect of the temperature of intercalation, Appl. Clay Sci., 83–84, 68, 10.1016/j.clay.2013.08.027

Zanoni, 2016, Clay mineral diagenesis in Cretaceous clastic reservoirs from West African passive margins (the South Gabon Basin) and its impact on regional geology and basin evolution history, Appl. Clay Sci., 10.1016/j.clay.2016.09.032

Zeelmaekers, 2012, Presence of bentonite beds in the earliest eocene Tienen formation in Belgium as evidenced by clay mineralogical analyses, Austin J. Earth Sci., 105, 110

Zwell, 1975, Applications of X-ray diffraction methods to quantitative chemical analysis, Appl. Spectrosc. Rev., 9, 167, 10.1080/05704927508081490

Navias, 1925, Quantitative determination of the development of mullite in fired clays by an X-ray method, J. Am. Ceram. Soc., 8, 296, 10.1111/j.1151-2916.1925.tb16409.x

Reynolds, 2002, The effects of grinding on the structure of a low-defect kaolinite, Am. Mineral., 87, 1626, 10.2138/am-2002-11-1212