Water Isotopes as Environmental Tracers for Conceptual Understanding of Groundwater Flow: An Application for Fractured Aquifer Systems in the “Scansano-Magliano in Toscana” Area (Southern Tuscany, Italy)

MDPI AG - Tập 6 Số 8 - Trang 2255-2277
Marco Doveri1, Mario Mussi1
1National Research Council of Italy, Institute of Geosciences and Earth Resources, Via G. Moruzzi, 1, 56124, Pisa, Italy

Tóm tắt

The “Scansano-Magliano in Toscana” area is characterized by a morpho-structure chiefly made-up by sandstone and shelly-calcareous lithologies. Generally, these complexes host minor aquifers in Tuscany, since they have medium to medium-low permeability. In the area under examination, a sandstone outcrop develops with continuity along the ridge of the structure for several kilometers and above a shelly substratum. Consequently, this hydrostructural context suggested the possibility that a significant groundwater body was hosted in the sandstones. In order to verify this assumption, an isotopic study was carried out taking into account several wells and springs sited on the sandstone outcrop and its surrounding area; the samples collected over a period of two years were analyzed to obtain δ18O‰, δ2H‰ and 3H. A study of the hydrostructural and morphological condition was also performed, and minor springs were selected. The analyses of this spring-water resulted in the characterization of the isotopic features of the infiltration water in the studied area, which represents a fundamental base of work for the interpretation of the data of groundwater points which drain long flow paths. By means of this approach, the groundwater framework was defined and the presence of a significant and continuous groundwater body within the sandstone complex was verified. A preliminary conceptual hydrogeological model was also proposed.

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Tài liệu tham khảo

Panichi, 1978, Environmental isotopes in geothermal studies, Geothermics, 6, 143, 10.1016/0375-6505(77)90024-4

Fritz, 1980, Environmental Isotopes in Groundwater Hydrology, Handbook of Environmental Isotope Geochemistry, Volume 1, 75

Gat, J.R., and Gonfiantini, R. (1981). Stable Isotope Hydrology (Deuterium and Oxygen-18 in the Water Cycle), International Atomic Energy Agency (IAEA). [1st ed.]. Technical Reports 210.

Stein, J., and Starkweather, A.W. (1997). Environmental Isotopes in Hydrogeology, Lewis Publishers CRC Press. [1st ed.].

Wood, 1995, Chemical and isotopic methods for quantifying groundwater recharge in a regional, semiarid environment, Ground Water, 33, 458, 10.1111/j.1745-6584.1995.tb00302.x

Mohammad, 1998, Application of environmental isotopes in storm-discharge analysis of two contrasting stream channel in a watershed, Water Res., 32, 2959, 10.1016/S0043-1354(98)00070-0

Marfia, 2004, Isotopic and geochemical evolution of ground and surface waters in a karst dominated geological setting: A case study from Belize, Central America, Appl. Geochem., 19, 937, 10.1016/j.apgeochem.2003.10.013

Doveri, 2013, Stable water isotopes as fundamental tool in karst aquifer studies: Some results from isotopic applications in the Apuan Alps carbonatic complexes (NW Tuscany), Italian J. Eng. Geol. Environ., 1, 33

Consorzio Lamma Territorio: Geologia, Carta Geologica Regionale 1:10,000. Available online:http://www.lamma.rete.toscana.it/territorio/geologia.

Servizio Idrologico Regionale: Archivio dati. Available online:http://www.sir.toscana.it.

Vittorini, 1972, Ricerche sul clima della Toscana in base all’evapotraspirazione potenziale e al bilancio idrico, Rivista Geografica Italiana, 1, 1

Boccaletti, 1971, Plate tectonics models for the development of Western Alps and Northern Apennines, Nature, 234, 108

Boccaletti, 1981, Evoluzione dell’Appennino settentrionale secondo un nuovo modello strutturale, Memorie della Società Geologica Italiana, 21, 359

Molli, 2008, Northern Apennine-Corsica orogenic system: An updated review, Geol. Soc. Lond. Spec. Publ., 298, 413, 10.1144/SP298.19

Mongelli, 1991, Flusso di calore nella regione Toscana, Studi Geologici Camerti, 1, 91

Elter, 1975, L’ensemble ligure, Bulletin de la Société Géologique de France, 17, 984, 10.2113/gssgfbull.S7-XVII.6.984

Marroni, 1998, Hidden terranes in the northern Apennines, Italy: A record of Late Cretaceous-Oligocene transpressional tectonics, J. Geol., 106, 149, 10.1086/516013

Nirta, 2005, The Ligurian Units of Southern Tuscany, Bollettino della Società Geologica Italiana, 3, 29

Jolivet, 1994, Exhumation of deep crustal metamorphic rocks and crustal extension in back-arc regions, Lithos, 33, 3, 10.1016/0024-4937(94)90051-5

Carmignani, 1995, Relationships between the Sardinia-Corsica-Provencal Domain and the Northern Apennines, Terra Nova, 7, 128, 10.1111/j.1365-3121.1995.tb00681.x

Brunet, 2000, Migration of compression and extension in the Tyrrhenian Sea: Insights from 40Ar/39Ar ages on micas along a transect from Corsica to Tuscany, Tectonophysics, 321, 127, 10.1016/S0040-1951(00)00067-6

Carmignani, 1990, Crustal extension in the Northern Apennines: Transition from compression to extension in the Alpi Apuane core complex, Tectonics, 9, 1275, 10.1029/TC009i006p01275

Brogi, 2003, Extensional shear zones as imaged by reflection seismic lines: The Larderello geothermal field (Central Italy), Tectonophysics, 363, 127, 10.1016/S0040-1951(02)00668-6

Francese, 2009, A structural and geophysical approach to the study of fractured aquifers in the Scansano-Magliano in Toscana Ridge, southern Tuscany, Italy, Hydrogeol. J., 17, 1233, 10.1007/s10040-009-0435-1

Fritz, 1980, Introduction, Handbook of Environmental Isotope Geochemistry, Volume 1, 1

Epstein, 1953, Variation of O18 content of waters from natural sources, Geochim. Cosmochim. Acta, 4, 213, 10.1016/0016-7037(53)90051-9

Coleman, 1982, Reduction of water with zinc for hydrogen isotope analysis, Anal. Chem., 54, 993, 10.1021/ac00243a035

Longinelli, 2003, Isotopic composition of precipitation in Italy: A first overall map, J. Hydrogeol., 270, 75

Mussi, 1998, Isotopic geochemistry of natural water from the Alpi Apuane-Garfagnana area, Northern Tuscany, Italy, Mineral. Petrogr. Acta, 41, 163

Doveri, 2011–2012, Geological, hydrodynamic and geochemical features of the volcanic aquifer of Mt. Amiata (Tuscany, central Italy): An overview, Acta Vulcanol., 23–24, 51

International Atomic Energy Agency and World Meteorological Organization Available online:http://isohis.iaea.org.

Doveri, 2005, Composizione isotopica di acque ipogee nell’Antro del Corchia (Alpi Apuane, Toscana nord-occidentale), Memorie dell’Istituto Italiano di Speleologia Serie 2, 18, 119

Barazzuoli, 1994, The aquifer of Mount Amiata: Evaluation of the perennial yield and its quality, Memorie della Società Geologica Italiana, 48, 825

Craig, 1961, Isotopic Variation in meteoric waters, Science, 133, 1702, 10.1126/science.133.3465.1702

Carmi, 1970, Evolution of the isotopic composition of atmosferic waters in the Mediterranean area, J. Geophys. Res., 75, 3039, 10.1029/JC075i015p03039

Minissale, 1997, Geochemistry of water and gas discharges from the Mt. Amiata silic complex and surrounding areas (central Italy), J. Volcanol. Geotherm. Res., 79, 223, 10.1016/S0377-0273(97)00028-0

Hauser, 1980, Composizione isotopica delle piogge in Sicilia. Riferimenti di base per studi idrogeologici e relazioni con altre aree mediterranee, Rendiconti della Società Italiana di Mineralogia e Petrologia, 36, 671

Leone, 2004, Gli isotopi ambientali nelle acque di sorgenti e pozzi e nelle emergenze sulfuree sottomarine di Capo Palinuro, Salerno, Geologia tecnica e ambientale, 3, 35

Celati, 1991, The low temperature hydrothermal system of Campiglia, Tuscany (Italy): A geochemical approach, Geothermics, 20, 67, 10.1016/0375-6505(91)90006-H