Vesuvianite: A potential U-Pb geochronometer for skarn mineralization---a case study of tungsten and tin deposits in South China

Allen, 1992, A comprehensive structure-model for vesuvianite: symmetry variations and crystal growth, Can. Mineral., 30, 1 Armbruster, 1993, Andradite crystal-chemistry dynamic X-site disorder and structure strain in silicate garnets, Eur. J. Mineral., 5, 59, 10.1127/ejm/5/1/0059 Cai, 2004, Ore-forming characteristics and prospecting significance of the Bailashui tin deposit in the Furong orefield, Geol. Explor., 40, 27 Carr, 2020, A new method for U-Pb geochronology of cassiterite by ID-TIMS applied to the Mole Granite polymetallic system, eastern Australia, Chem. Geol., 539, 119539, 10.1016/j.chemgeo.2020.119539 Chang, 2019, Skarn deposits of China, 189 Chen, 1989, 1 Chen, 2014, Origin of the fluorine-rich highly differentiated granites from the Qianlishan composite plutons (South China) and implications for polymetallic mineralization, J. Asian Earth Sci., 93, 301, 10.1016/j.jseaes.2014.07.022 Chen, 2016, Generation of late Mesozoic Qianlishan A 2 -type granite in Nanling Range, South China: implications for Shizhuyuan W-Sn mineralization and tectonic evolution, Lithos., 266, 435, 10.1016/j.lithos.2016.10.010 Chen, 2021, Precise U Pb dating of grandite garnets by LA-ICP-MS: assessing ablation behaviors under matrix-matched and non-matrix-matched conditions and applications to various skarn deposits, Chem. Geol., 572, 120198, 10.1016/j.chemgeo.2021.120198 Chew, 2011, U-Pb and Th-Pb dating of apatite by LA-ICPMS, Chem. Geol., 280, 200, 10.1016/j.chemgeo.2010.11.010 Chew, 2014, U-Pb LA-ICPMS dating using accessory mineral standards with variable common Pb, Chem. Geol., 363, 185, 10.1016/j.chemgeo.2013.11.006 Deng, 2017, Dating magmatic and hydrothermal procestases using andradite-rich garnet U–Pb geochronometry, Contrib. Mineral. Petrol., 172, 70, 10.1007/s00410-017-1389-2 Einaudi, 1982, Introduction, terminology, classification, and composition of skarn deposits, Econ. Geol., 77, 745, 10.2113/gsecongeo.77.4.745 Frost, 2001, Sphene (titanite): phase relations and role as a geochronometer, Chem. Geol., 172, 131, 10.1016/S0009-2541(00)00240-0 Fu, 2004, Zircon SHRIMP dating of the Cailing granite on the eastern margin of the Qitianling granite, Hunan, South China, and its significance, Geol. China, 31, 96 Ganguly, 1976, The energetic of nature garnet solid solution. ΙΙ. Mixing of the calcium silicate end-members, Contrib. Mineral. Petrol., 55, 81, 10.1007/BF00372756 Gaspar, 2008, REE in skarn systems: a LA-ICP-MS study of garnets from the Crown Jewel gold deposit, Geochim. Cosmochim. Acta, 72, 185, 10.1016/j.gca.2007.09.033 Gulson, 1992, Cassiterite: potential for direct dating of mineral deposits and a precise age for the Bushveld complex granites, Geology, 20, 355, 10.1130/0091-7613(1992)020<0355:CPFDDO>2.3.CO;2 Guo, 2015, Geochronological and geochemical constraints on the petrogenesis and geodynamic setting of the Qianlishan granitic pluton Southeast China, Mineral. Petrol., 109, 253, 10.1007/s00710-014-0355-1 Guo, 2016, Structure and thermodynamics of uranium-containing iron garnets, Geochim. Cosmochim. Acta, 189, 269, 10.1016/j.gca.2016.05.043 Himmelberg, 1980, Uranium- and thorium-rich vesuvianite from the Seward Peninsula, Alaska, Am. Mineral., 65, 1020 Huang, 2001, Geological characteristics and ore-controlling factors of the Furong orefield, Qitianling, Hunan, Chin. Geol., 28, 30 Jiang, 2019, Genesis of the giant Shizhuyuan W-Sn–Mo–Bi–Pb–Zn polymetallic deposit, South China: constraints from zircon geochronology and geochemistry in skarns, Ore Geol. Rev., 111, 103160, 10.1016/j.oregeorev.2019.103160 Lai, 2013, Compressibility of a natural P4/nnc vesuvianite, Eur. J. Mineral., 25, 631, 10.1127/0935-1221/2013/0025-2302 Li, 1996, Re–Os isotopic chronology of molybdenites in the Shizhuyuan polymetallic tungsten deposit, Southern Hunan, Geol. Rev., 42, 261 Li, 2004, Precise Sm–Nd and U–Pb isotopic dating of the supergiant Shizhuyuan polymetallic deposit and its host granite, SE China, Geol. Mag., 141, 225, 10.1017/S0016756803008823 Li, 2005, Zircon SHRIMP dating of the Qitianling granite, Chenzhou, southern Hunan, and its geological significance, Geol. Bull. China, 24, 411 Li, 2006, Dating of the rock-forming and ore-forming ages and their geological significances in the Furong ore-field, Qitian Mountain, Hunan, Geol. Rev., 52, 114 Liao, 2021, Evidence for temporal relationship between the late Mesozoic multistage Qianlishan granite complex and the Shizhuyuan W–Sn–Mo–Bi deposit, SE China, Sci. Rep., 11, 5828, 10.1038/s41598-021-84902-6 Liu, 1997, 40Ar-39Ar and Sm-Nd isotope age of Qianlishan granite and mineralization, Sci. China Ser. D, 27, 426 Liu, 2008, In situ analysis of major and trace elements of anhydrous minerals by LA-ICP-MS without applying an internal standard, Chem. Geol., 257, 34, 10.1016/j.chemgeo.2008.08.004 Liu, 2010, Reappraisement and refinement of zircon U-Pb isotope and trace element analyses by LA-ICP-MS, Chin. Sci. Bull., 55, 1535, 10.1007/s11434-010-3052-4 Liu, 2012, Re-Os dating of the molybdenite from the Jinchantang tin-bismuth deposit in Huannan Province and its geological significance, Acta Petrol. Sin., 28, 39 Lu, 2003, Mineralization and fluid inclusion study of the Shizhuyuan W-Sn-Bi-Mo-F skarn deposit, Hunan province, China, Econ. Geol., 98, 955, 10.2113/gsecongeo.98.5.955 Luck, 1982, The study of molybdenites through the 187Re-187Os chronometer, Earth Planet. Sci. Lett., 61, 291, 10.1016/0012-821X(82)90060-7 Mao, 1996, Geology and metallogeny of the Shizhuyuan skarn-greisen deposit, Hunan province, China, Int. Geol. Rev., 38, 1020, 10.1080/00206819709465379 Mao, 2004, Geological characteristics of the Furong tin orefield, Hunan, 40Ar–39Ar dating of tin ores and related granite and its geodynamic significance for rock and ore formation, Acta Petrol. Sin. (Engl. Ed.), 78, 481 Mao, 2007, Large-scale tungsten-tin mineralization in the Nanling region, South China: metallogenic ages and corresponding geodynamic processes, Acta Petrol. Sin., 23, 2329 Mao, 2013, Major types and time-space distribution of Mesozoic ore deposits in South China and their geodynamic settings, Mineral. Deposita, 48, 267, 10.1007/s00126-012-0446-z Mathur, 1999, Age and sources of the ore at Tharsis and Rio Tinto, Iberian Pyrite Belt, from Re-Os isotopes, Mineral. Deposita, 34, 790, 10.1007/s001260050239 Meagher, 1975, The crystal structures of pyrope and grossularite at elevated temperatures, Am. Mineral., 60, 218 Meinert, 2005, World skarn deposits, Econ. Geol., 299 Moiseev, 2020, Insights into crystal chemistry of the vesuvianite-group: manaevite-(Ce), a new mineral with complex mechanisms of its hydration, Phys. Chem. Miner., 47, 17, 10.1007/s00269-020-01086-7 Peng, 2006, Precise molybdenite Re–Os and mica Ar–Ar dating of the Mesozoic Yaogangxian tungsten deposit, central Nanling district, South China, Mineral. Deposita, 41, 661, 10.1007/s00126-006-0084-4 Peng, 2007, 40Ar/39Ar isotopic dating of tin mineralization in Furong deposit of Hunan Province and its geological significance, Mineral. Deposita, 26, 237 Peng, 2008, The time ranges of granitoid emplacement and related nonferrous metallic mineralization in southern Hunan, Geol. Rev., 54, 617 Rák, 2011, Role of iron in the incorporation of uranium in ferric garnet matrices, Phys. Rev. B, 84, 155128, 10.1103/PhysRevB.84.155128 Romer, 1992, Vesuvianite-new tool for the U-Pb dating of skarn ore deposits, Mineral. Petrol., 46, 331, 10.1007/BF01173571 Seman, 2017, U-Pb geochronology of grossular-andradite garnet, Chem. Geol., 460, 106, 10.1016/j.chemgeo.2017.04.020 Shannon, 1976, Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides, Acta Crystallogr., A32, 751, 10.1107/S0567739476001551 Shu, 2006, Principal geological features of Nanling tectonic belt, South China, Geol. Rev., 52, 269 Shu, 2020, Pre-Jurassic tectonics of the South China, Acta Geol. Sin., 94, 333 Smith, 2004, The rare earth elements and uranium in garnets from the Beinnan Dubhaich aureole, Skye, Scotland, UK: constraints on processes in a dynamic hydrothermal system, J. Petrol., 45, 467, 10.1093/petrology/egg087 Stein, 2000, Re-Os dating of low-level highly radiogenic (LLHR) sulfides: the Harnas Gold Deposit, Southwest Sweden, records continental-scale tectonic events, Econ. Geol., 95, 1657 Sun, 1989, Chemical and isotopic systematics of oceanic basalt: implications for mantle composition and processes, 313 Tang, 2021, In situ low-U garnet U-Pb dating by LA-SF-ICP-MS and its application in constraining the origin of Anji skarn system combined with Ar-Ar dating and Pb isotopes, Ore Geol. Rev., 130, 103970, 10.1016/j.oregeorev.2020.103970 Tera, 1972, U-Th-Pb systematics in three Apollo 14 basalt and the problem of initial Pb in lunar rocks, Earth Planet. Sci. Lett., 14, 281, 10.1016/0012-821X(72)90128-8 Tilton, 1968, Sphene: uranium-lead ages, Science, 159, 1458, 10.1126/science.159.3822.1458 Wang, 1987 Wang, 2011, The Pb isotope geochemistry of Shizhuyuan deposite, Hunan Province, Acta Mineral. Sin., 31, 645 Wang, 2020, Regional metallogeny of Tungsten-tin-polymetallic deposits in Nanling region, South China, Ore Geol. Rev., 120, 103305, 10.1016/j.oregeorev.2019.103305 Wei, 2022, In situ U–Pb geochronology of vesuvianite by LA-SF-ICP-MS, J. Anal. At. Spectrom., 37, 69, 10.1039/D1JA00303H Wiedenbeck, 1995, Three natural zircon standards for U-Th-Pb, Lu-Hf, trace element and REE analyses, Geostand. Geoanal. Res., 19, 1, 10.1111/j.1751-908X.1995.tb00147.x Williams, 1998, U–Th–Pb geochronology by ion microprobe, 7, 1 Wu, 2016, 618, 4 Yu, 2005, Re-Os dating of gold-bearing arsenopyrite of the Maoling gold deposit, Liaoning Province, Northeast China and its geological significance, Chin. Sci. Bull., 50, 1509, 10.1360/04wd0229 Yuan, 2011, In situ LA-MC-ICP-MS and ID-TIMS U–Pb geochronology of cassiterite in the giant Furong tin deposit, Hunan Province, South China: new constraints on the timing of tin–polymetallic mineralization, Ore Geol. Rev., 43, 235, 10.1016/j.oregeorev.2011.08.002 Zhang, 2013, Tectonics of South China continent and its implications, Sci. China Earth Sci., 56, 1804, 10.1007/s11430-013-4679-1 Zhang, 2019, Unveiling growth histories of multi-generational garnet in a single skarn deposit via newly-developed LA-ICP-MS U-Pb dating of grandite, Gondwana Res., 73, 65, 10.1016/j.gr.2019.04.003 Zhao, 2006, SHRIMP U–Pb dating of the Furong unit of Qitianling granite from southeast Hunan Province and their geological implications, Acta Petrol. Sin., 22, 2611 Zhao, 2018, Constraints on the timing and genetic link of the large-scale accumulation of proximal W-Sn-Mo-Bi and distal Pb-Zn-Ag mineralization of the world-class Dongpo orefield, Nanling Range, South China, Ore Geol. Rev., 95, 1140, 10.1016/j.oregeorev.2017.12.005 Zhu, 2009, Zircon U-Pb geochronological framework of Qitianling granite batholith, middle part of Nanling range, South China, Sci. China Ser. D Earth Sci., 52, 1279, 10.1007/s11430-009-0154-4