Versatile Reactivity of Rhodium–Iminocarbenes Derived from <i>N</i>‐Sulfonyl Triazoles

For selected reviews on the reactivity of Rh carbenoids see:

10.1016/S0022-328X(00)00637-9

10.1038/nature06485

2005, Modern Rhodium Catalyzed Organic Reactions

10.1016/S0065-2725(08)60459-6

For earlier reports on the ring‐opening ofN‐sulfonyl 1 2 3‐triazoles see:

10.1021/jo00835a057

10.1002/cber.19721050919

10.1055/s-1972-21938

10.1021/ja805079v

10.1021/ja908075u

10.1021/ja910187s

For recent review on transannulation reactions of triazoles see:

10.1002/ange.201104807

10.1002/anie.201104807

10.1002/ange.200700804

10.1002/anie.200700804

10.1039/b819162j

10.1021/ol2014347

10.1021/ja202969z

10.1021/ja2104203

10.1021/ja3062453

10.1021/ol102087r

10.1021/ja308285r

10.1002/ange.201207820

10.1002/anie.201207820

For migration of different groups to Rh–carbene centers see Ref. [10] and references therein.