Vapor deposition of technetium coatings by thermolysis of volatile carbonyl complexes: I. Conditions and efficiency of coating deposition from various starting compounds

Radiochemistry - Tập 51 - Trang 576-582 - 2009
G. V. Sidorenko1, A. E. Miroslavov1, D. N. Suglobov1
1Khlopin Radium Institute, Research and Production Association, Federal State Unitary Enterprise, St. Petersburg, Russia

Tóm tắt

Technetium carbonyl complexes [TcBr(CO)5], [TcI(CO)5], [TcX(CO)3]4 (X = Cl, Br, I), [TcBr(CO)3en] (en = ethylenediamine), [Tc(RCOCHCOR′)(CO)3(Et2NH)] [R = CH3 or C(CH3)3, R′ = CF3], Tc2(CO)10, and [Tc(C5H5)(CO)3] were tested as starting compounds for chemical vapor deposition of technetium coatings. The conditions of deposition of technetium coatings were determined, and the deposition yields were evaluated.

Tài liệu tham khảo

Spitsyn, V.I. and Kuzina, A.F., Tekhnetsii (Technetium), Moscow: Nauka, 1981. Spitsyn, V.I., Strekalov, P.V., and Balakhovskii, O.A., Dokl. Akad. Nauk SSSR, 1982, vol. 266, no. 4, pp. 921–924. Syrkin, V.G., Karbonil’nye metally (Metals from Carbonyls), Moscow, 1978. Schwohau, K., Technetium. Chemistry and Radiopharmaceutical Applications, Weinheim: Wiley-VCH, 2000. Miroslavov, A.E., Sidorenko, G.V., Borisova, I.V., et al., Radiokhimiya, 1990, vol. 32, no. 4, pp. 6–14. Miroslavov, A.E., Sidorenko, G.V., Borisova, I.V., et al., Radiokhimiya, 1990, vol. 32, no 6, pp. 14–21. Borisova, I.V., Miroslavov, A.E., Sidorenko, G.V., and Suglobov, D.N., Radiokhimiya, 1991, vol. 33, no. 3, pp. 1–8. Baturin, N.A., Grigor’ev, M.S., Kryuchkov, S.V., et al., Radiokhimiya, 1994, vol. 36, no. 3, pp. 202–204. Borisova, I.V., Miroslavov, A.E., Sidorenko, G.V., et al., Radiokhimiya, 1991, vol. 33, no. 4, pp. 27–38. Borisova, I.V., Miroslavov, A.E., Sidorenko, G.V., and Suglobov, D.N., Radiokhimiya, 1991, vol. 33, no. 6, pp. 1–8. Borisova, I.V., Miroslavov, A.E., Sidorenko, G.V., and Suglobov, D.N., Radiokhimiya, 1991, vol. 33, no. 6, pp. 9–13. Miroslavov, A.E., Borisova, I.V., Sidorenko, G.V., and Suglobov, D.N., Radiokhimiya, 1991, vol. 33, no. 6, pp. 20–26. Adamov, V.M., Belyaev, B.N., Borisova, I.V., et al., Radiokhimiya, 1991, vol. 33, no. 4, pp. 38–53. Gribov, B.G., Domrachev, G.A., Zhuk, B.V., et al., Osazhdenie plenok i pokrytii razlozheniem metalloorganicheskikh soedinenii (Deposition of Films and Coatings by Decomposition of Organometallic Compounds), Moscow: Nauka, 1981. Spencer, L.F., Metal Finish., 1968, vol. 66, no. 8, pp. 52–58. Miroslavov, A.E., Lumpov, A.A., Sidorenko, G.V., et al., J. Organomet. Chem., 2008, vol. 693, pp. 4–10. Adamov, V.M., Belyaev, B.N., Sidorenko, G.V., and Suglobov, D.N., Radiokhimiya, 1987, vol. 29, no. 4, pp. 454–460. Miroslavov, A.E., Borisova, I.V., Sidorenko, G.V., and Suglobov, D.N., Radiokhimiya, 1991, vol. 33, no. 6, pp. 14–19. Nekrasov, B.V., Osnovy obshchei khimii (Fundamentals of General Chemistry), Moscow: Khimiya, 1974, vol. 1. Spravochnik khimika (Chemist’s Handbook), Nikol’skii, B.P., Ed., Moscow: Khimiya, 1971. Metody elementoorganicheskoi khimii. Podgruppy medi, skandiya, titana, vanadiya, khroma, margantsa. Lantanoidy i aktinoidy (Methods of Organometallic Chemistry. Subgroups of Copper, Scandium, Titanium, Vanadium, Chromium, and Manganese. Lanthanides and Actinides), Moscow: Nauka, 1974, book 2.