Utilization of toxic slimes produced during the chemical regeneration of complexes of heavy metals after the baromembrane water purification

Journal of Water Chemistry and Technology - Tập 31 - Trang 316-323 - 2009
L. N. Puzyrnaya1, A. P. Krivoruchko1, L. Yu. Yurlova1, E. V. Terlikovskii1
1Dumanskii Institute of Colloid and Water Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

Tóm tắt

A method has been developed for the utilization of salts of heavy metals generated due to chemical regeneration of complexes of concentrates after the baromembrane treatment of polluted waters. This method implies the immobilization in glass-ceramic matrices. The optimal composition of matrices was determined and their physico-mechanical properties were investigated. The matrices featuring good performance characteristics and good decorative effect were also obtained. On the basis of investigations performed a production process was developed and proposed for manufacturing the glass-ceramic materials used in construction and paint-and-varnish industries.

Tài liệu tham khảo

Goncharuk, V.V., Radovenchyk, V.M., and Gomelya, M.D., Otrymannya ta vykorystannya vysokodyspersnykh sorbentiv z magnitnymy vlastyvostyamy (Preparation and Application of Highly Dispersed Sorbents with Magnetic Properties), Shepetivka: Shepetivs’ka mizhraionna drukarnya, 2003. Timofeeva, S.S., Khimiya i Tekhnologiya Vody, 1990, vol. 12, no. 3, pp. 237–245. Grinevich, V.I., Kostrov, V.V., and Chesnokova, T.A., Inzhener. Ekologiya, 1994, no. 5, pp. 53–56. Timofeeva, S.S., Baranov, A.A., Balayan, A.E., et al., Khimiya i Tekhnologiya Vody, 1991, vol. 13, no. 1, pp. 68–71. Brosnan, D.A. and Hochlejtner, W., Can. Ceram. Quart., 1997, vol. 61, no. 2, pp. 1288–1294. Surzhko, O.A., Rat’kova, V.P., and Semenov, V.I., Tekhnologiya obrabotki osadkov prirodnykh i stochnykh vod (Sludge Treatment Technology of Natural and Waste Waters), Moscow: MDNTP, 1990. Olefirenko, N.G., Pirusyan, Yu.L., Trusoda, Yu.D., et al., Steklo i Keramika, 1986, no. 6, pp. 3–4. Kudryashov, N.I., Ekologiya i Promyshlennost’ Rossii, 2002, no. 2, pp. 37–38. Levitskii, I.A. and Dyatlova, E.M., Steklo i Keramika, 1992, nos. 11/12, pp. 9–11. Lyasin, V.F. and Sarkisov, P.D., Novye oblitsovochnye materially na osnove stekla (New Facing Materials Based on Glass), Moscow: Stroiizdat, 1987. Bobkova, N.M., Barantseva, S.E., and Zalygina, O.S., Steklo i Keramika, 1995, no. 3, pp. 14–15. Alekhin, Yu.A. and Naidus, G.G., Ibid., 1983, no. 3, pp. 5–6. Delalio, A., Goncharuk, V.V., Kornilovich, B.Yu., Krivoruchko, A.P., Yurlova, L.Yu., and Pshinko, G.N., Khimiya i Tekhnologiya Vody, 2003, vol. 25, no. 6, pp. 564–573. Puzyrnaya, L.N., Krivoruchko, A.P., and Terlikovskii, E.V., Ibid., 2008, vol. 30, no. 6, pp. 654–674. Komokhov, P.G., Maslennikova, L.L., and Abu-Khasan, M., Stroit. Materialy, 2003, no. 12, pp. 44–45. GOST (State Standard) 7025-91: Brick and Stones Ceramic and Silicate. Methods for Determination of Water Absorption, Density, and Freeze-Thaw Resistance Control, Put into effect on July 1, 1991. Bespamyatnov, G.P. and Krotov, Yu.A., Predel’no dopystimye kontsentratsii khimicheskikh veschestv v okruzhayushchei srede (Maximum Permissible Concentrations of Chemical Substances in the Environment), Put into effect in 1991. RD 52. 24.377-95. Metodicheskie ukazaniya po atomno-absorrbtzionnomy elektrotermicheskomy opredeleniyo tyazhelykh metallov [Cd, Pb, Zn, Ag, Cu, Mn, Cr, Co, Ni] i berilliua v poverkhnostnykh i ochischenykh stochnykh vodakh (Procedural Guidelines on Atomic Absorption and Electrothermal Determination of Heavy Metals [Cd, Pb, Zn, Ag, Cu, Mn, Cr, Co, Ni] and Beryllium in Surface and Purified Waste Waters), Put into effect in 1991. Shvartsenbakh, G. and Flashka, G., Kompleksometricheskoe titrirovaniye (Complexometric Titration), Moscow: Khimiya, 1970. Chalyi, V.P., Gidrookist metallow (Metal Hydroxides), Kiev: Nauk. Dumka, 1972. Budnikov, P.P. and Gistling, A.M., Reaktsii v smesyakh tverdykh veshchestv (Reactions in Mixtures of Solid Substances), Moscow: Stroiizdat, 1971. Andriets’, Ya. and Kosyi, O., Ukr. Keramol. Zhurn., 2001, no. 2, pp. 35–36.