Using soil knowledge for the evaluation of mid‐infrared diffuse reflectance spectroscopy for predicting soil physical and mechanical properties

European Journal of Soil Science - Tập 59 Số 5 - Trang 960-971 - 2008
Budiman Minasny1, Alex B. McBratney1, Grant Tranter1, Brian Murphy1
1aFaculty of Agriculture, Food and Natural Resources, University of Sydney, New South Wales 2006, Australia, and 
 bDepartment of Environment and Climate Change, Cowra, New South Wales 2794, Australia

Tóm tắt

Summary

Mid‐infrared diffuse reflectance spectroscopy can provide rapid, cheap and relatively accurate predictions for a number of soil properties. Most studies have found that it is possible to estimate chemical properties that are related to surface and solid material composition. This paper focuses on prediction of physical and mechanical properties, with emphasis on the elucidation of possible mechanisms of prediction. Soil physical properties that are based on pore‐space relationships such as bulk density, water retention and hydraulic conductivity cannot be predicted well using MIR spectroscopy. Hydraulic conductivity was measured using a tension‐disc permeameter, excluding the macropore effect, but MIR spectroscopy did not give a good prediction. Properties based on the soil solid composition and surfaces such as clay content and shrink‐swell potential can be predicted reasonably well. Macro‐aggregate stability in water can be predicted reasonably as it has a strong correlation with carbon content in the soil. We found that most of the physical and mechanical properties can be related back to the fundamental soil properties such as clay content, carbon content, cation exchange capacity and bulk density. These connections have been explored previously in pedotransfer functions studies. The concept of a spectral soil inference system is reiterated: linking the spectra to basic soil properties and connecting basic soil properties to other functional soil properties via pedotransfer functions.

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