Uses of Chloride/Bromide Ratios in Studies of Potable Water

Ground Water - Tập 36 Số 2 - Trang 338-350 - 1998
Stanley N. Davis1, Donald O. Whittemore2, J. Fabryka-Martin3
1Department of Hydrology and Water Resources, University of Arizona, Tucson, Arizona 85721. E-mail: [email protected]
2Kansas Geological Survey, University of Kansas, Lawrence, Kansas 66047. E-mail: [email protected]
3CST-7, MS-J514, Los Alamos National Laboratory, Los Alamos, New Mexico 87545. E-mail: [email protected].

Tóm tắt

Abstract

In natural ground water systems, both chlorine and bromine occur primarily as monovalent anions, chloride and bromide. Although dissolution or precipitation of halite, biological activity in the root zone, anion sorption, and exchange can affect chloride/bromide ratios in some settings, movement of the ions in potable ground water is most often conservative. Atmospheric precipitation will generally have mass ratios between 50 and 150; shallow ground water, between 100 and 200; domestic sewage, between 300 and 600; water affected by dissolution of halite, between 1000 and 10,000; and summer runoff from urban streets, between 10 and 100. These, and other distinctive elemental ratios, are useful in the reconstruction of the origin and movement of ground water, as illustrated by case studies investigating sources of salinity in ground water from Alberta, Kansas, and Arizona, and infiltration rates and pathways at Yucca Mountain, Nevada.

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