Uranium solution-mineral equilibria at low temperatures with applications to sedimentary ore deposits

Geochimica et Cosmochimica Acta - Tập 42 Số 6 - Trang 547-569 - 1978
Donald Langmuir1
1Department of Geosciences, The Pennsylvania State University, University Park, PA 16802 USA

Tóm tắt

Từ khóa


Tài liệu tham khảo

Abdel-Gawad, 1961, Uranoorganic mineral association, Am. Mineralogist, 46, 402

Ahrland, 1973, Solution Chemistry (of the actinides), 465

Andreyev, 1964, Reduction of uranium by natural organic substances, Geochem. Intl, 1, 3

Annual Nure Report, 1976, National Uranium Resource Evaluation

Baes, 1976

Barton, 1956, Fixation of uranium in the oxidized base metal ores of the Goodsprings District, Clark Co., Nevada, Econ. Geol, 51, 178, 10.2113/gsecongeo.51.2.178

Baturin, 1969, Migration of uranium in rivers and the time of its presence in waters of the world ocean, of seas and lakes, Geokhimiya, 6, 715

Beck, 1970

Brookins, 1975, Coffinite-uraninite stability relations in Grant Mineral Belt, New Mexico, Abs. Bull. Am. Assoc. Petrol: Geologists, 59, 905

Busey, 1977, Ionization equilibria of silica acid and polysilicate formation in aqueous sodium chloride to 300°C, Inorg. Chem, 16, 2444, 10.1021/ic50176a004

Butler, 1964

Carlisle, 1977, The distribution of calcretes and gypcretes in southwestern United States and their uranium favorability

Chukhlantsev, 1956, Solubility of uranyl and thorium phosphates, Zhur. Neorg. Khim, 1, 478

Chukhlantsev, 1961, Solubility product of uranyl, beryllium and cerium phosphates, Izvest. VUZ, Khim. Tekhnol, 4, 359

Cinnéide, 1975, Equilibria in uranyl carbonate systems—I. The overall stability constant of UO2(CO3)44−, J. Inorg. Nucl. Chem, 37, 1013, 10.1016/0022-1902(75)80689-0

1976, Recommended Key Values for Thermodynamics, 1975, J. Chem. Thermo, 8, 603, 10.1016/0021-9614(76)90010-0

1977, Recommended Key Values for Thermodynamics 1976, J. Chem. Thermo, 9, 705, 10.1016/0021-9614(77)90011-8

Cordfunke, 1964, Heats of formation of some hexavalent uranium compounds, J. Phys. Chem, 68, 3353, 10.1021/j100793a041

Dall'Aglio, 1970, Geochemistry of stream and ground waters for Western Sicily. The changes in spring water chemism after the 1968 earthquake

Dall'Aglio, 1971, A study of the circulation of uranium in the supergene environment in the Italian Alpine Range, Geochim. Cosmochim. Acta, 35, 47, 10.1016/0016-7037(71)90103-7

Dall'Aglio, 1974, Geochemical factors controlling the formation of the secondary minerals of uranium

Davis, 1964, Silica in streams and ground water, Am. J. Sci, 262, 870, 10.2475/ajs.262.7.870

Day, 1954, Extraction of uranyl ion from some aqueous solutions with 2-thenoyltrifluoracetone, J. Am. Chem. Soc, 76, 3895, 10.1021/ja01644a007

Day, 1955, Stability of complexes of uranium (IV) with chloride, sulfate and thiocyanate, J. Am. Chem. Soc, 77, 3180, 10.1021/ja01617a004

Dement'yev, 1968, Conditions of formation of a sorption barrier to the migration of uranium in an oxidizing environment, Geochem. Intl, 1–3, 394

Denson, 1956, Water sampling as a guide in the search for uranium deposits and its use in evaluating widespread volcanic units as a potential source bed for uranium, U.S. Geol. Survey Prof. Paper, 300, 673

Doi, 1975, Uranium mineralization by ground-water in sedimentary rocks, Japan, Econ. Geol, 70, 628, 10.2113/gsecongeo.70.4.628

Dyck, 1976, Minor and trace element contents of well waters, Carboniferous Basin, Eastern Canada Federal-Provincial Uranium Reconnaissance Program: Canada Dept. of Energy Mines and Resources, Geol. Survey of Canada, Ottawa, Open File Dept. No. 340

Evans, 1958, Thermodynamic equilibria of vanadium in aqueous systems as applied to interpretation of the Colorado Plateau ore deposits, Geochim. Cosmochim. Acta, 15, 131, 10.1016/0016-7037(58)90015-2

Fix, 1956, Hydrochemical exploration for uranium, U.S. Geol. Survey Prof. Paper, 300, 667

Fournier, 1976, The solubility of amorphous silica at high temperatures and high pressures, 19

Fuchs, 1959, The preparation and properties of uranium (IV) silicate, Am. Mineralogist, 44, 1057

Fuger, 1971, Thermodynamic properties of simple actinide compounds

Fuger, 1976, The Chemical Thermodynamics of Actinide Elements and Compounds—II. The Actinide Aqueous Ions, 16

Garrels, 1965

Gayer, 1955, The solubility of uranium trioxide, UO3-H2O, in solutions of sodium hydroxide and perchloric acid of 25°C, J. Am. Chem. Soc, 77, 1448, 10.1021/ja01611a014

Gayer, 1957, Solubility of uranium (IV) hydroxide in solutions of sodium hydroxide and perchloric acid at 25°C, Can. J. Chem, 35, 5, 10.1139/v57-002

Germanov, 1968, Behavior of organic matter in ground water during infiltrational epigenesis, Intl. Geol. Rev, 10, 826, 10.1080/00206816809474941

Haji-Vassiliou, 1973, Analytic data on nature of urany-organic deposits, Bull. Am. Assoc. Petrol. Geologists, 57, 1291

Hancock, 1977, Uranium in situ leaching: its advantages, practice, problems, and computer simulation, Soc. Mining Engineers of Am. Inst. of Mining Engineers Preprint No. 77-AS-66

Harshman, 1972, Geology and uranium deposits, Shirley Basin area, Wyoming, U.S. Geol. Survey Prof. Paper, 745

Hemingway B. S. (1977) Written communication. U.S. Geol. Survey, Reston, VA.

Hostetler, 1962, Transportation and precipitation of uranium and vanadium at low temperatures, with special reference to sandstone type uranium deposits, Econ. Geol, 57, 137, 10.2113/gsecongeo.57.2.137

Israel, 1976, Vol. VI, 293

Kakihana, 1974, Potentiometric and spectrophotometric studies of fluoride complexes of uranium (IV), Bull. Chem. Soc. Japan, 47, 1665, 10.1246/bcsj.47.1665

Katz, 1957

Keller, 1973, Binary and ternary oxides, hydroxides and hydrous oxides, peroxoides phosphatea and arsenates, 219

Kilday, 1973, The enthalpy of solution of low quartz (α-quartz) in aqueous hydrofluoric acid, J. Res. Natl. Bur. Std, 77A, 205, 10.6028/jres.077A.012

Kochenov, 1965, Some features of the accumulation of uranium in peat bogs, Geochem. Intl, 1–3, 65

Kopp, 1967, Trace metals in waters of the United States. A five year summary of trace metals in rivers and lakes of the United States

Krylov, 1968, Complex formation of U(VI) with the fluoride ion in solutions of HClO4, Soviet Radiochem, 10, 708

Langmuir, 1971, Particle size effect on the reaction geothite = hematite + water, Am. J. Sci, 271, 147, 10.2475/ajs.271.2.147

Langmuir, 1972, Correction, Am. J. Sci, 272, 972, 10.2475/ajs.272.10.972

Langmuir, 1977, Refinement of the thermodynamic properties of uranium minerals and dissolved species, with application to the chemistry of ground waters in sandstone-type uranium deposits, 57

Latimer, 1952

Lewis, 1961

Lietzke, 1960, The solubility of silver sulfate in electrolyte solutions—VII. Solubility in uranyl sulfate solutions, J. Phys. Chem, 64, 816, 10.1021/j100835a028

Lisitsin, 1962, Form a occurrence of uranium in ground waters and conditions of its precipitation as UO2, Geokhimiya, 9, 763

Lisitsin, 1971, Ratio of the redox equilibria of uranium and iron in stratiform aquifers, Intl. Geol. Rev, 13, 744, 10.1080/00206817109475493

Lisitsin, 1967, Role of microorganisms in development of geochemical reduction barriers where limonitization bedded zones wedge-out, Intl. Geol. Rev, 9, 1180, 10.1080/00206816709474543

Lopatkina, 1964, Characteristics of migration of uranium in the natural waters of humid regions and their use in the determination of the geochemical background for uranium, Geochem. Intl, 4–6, 788

Mann, 1974, Chemical ore genesis models for the precipitation of carnotite in calcrete, CSIRO Minerals Res. Labs., Div. of Mineralogy, Rept. No. FP 7

Marcus, 1958, Anion Exchange of metal complexes: the uranyl phosphate system, 3, 465

Martin, 1966, Sur les acids humiques extraits d'une tourbe acid: étude de leurs propriétes, et de leur aptitude à fixer et transporter l'uranium, 165

Masaki, 1972, Analysis of the superstructure of U409 by neutron diffraction, Acta Cryst, 28, 785, 10.1107/S0567740872003206

McKelvey, 1955, Origin of uranium deposits—I, 50th Anniversary Vol., Econ. Geol, 404

Miller, 1958, The chemical environment of pitchblende, Econ. Geol, 53, 521, 10.2113/gsecongeo.53.5.521

Moench, 1962, Properties and paragenesis of coffinite from the Woodrow Mine, New Mexico, Am. Mineralogist, 47, 26

Morey, 1962, The solubility of quartz in water in the temperature interval from 25 to 300°C, Geochem. Cosmochim. Acta, 26, 1029, 10.1016/0016-7037(62)90027-3

Moskvin, 1975, Mechanism of the interchange of ligands in actinide coordination compounds, Koord. Khim, 1, 83

Moskvin, 1967, The formation of thorium (IV) and uranium (IV) complexes in phosphate solutions, Russian J. Inorg. Chem, 12, 1794

Moskvin, 1967, Solubility product of uranyl phosphate and the. composition and dissociation constants of uranyl phosphato-complexes, Russian J. Inorg. Chem, 12, 1756

Muto, 1965, Thermochemical stability of nigyoite, Min. J, 4, 245, 10.2465/minerj1953.4.245

Muto, 1968, Some aspects of fixation of uranium from natural waters, 15, 287

Nancollas, 1966

Naumov, 1974

Nikitin, 1972, Uranyl hydrolysis in a hydrothermal region, Geokhimiya, 3, 297

Nininger, 1954

Nord, 1977, Characteristics of fine-grained black uranium ores by transmission electron microscopy, 753, 29

Osborne, 1955, Heat capacity of UF4 from 5 to 300 K, J. Am. Chem. Soc, 77, 2737, 10.1021/ja01615a016

Palache, 1944

Parker, 1977

Parker, 1971, Selected values of chemical thermodynamic properties, Natl. Bureau Standards Tech. Note 270-6

Parker, 1976, Selected thermochemical data compatible with the CODATA recommendations, 10.6028/NBS.IR.75-968

Pauli, 1975, Heavy metal humates and their behavior against hydrogen sulfide, Soil Sci, 119, 98, 10.1097/00010694-197501000-00014

Phoenix, 1959, Occurrence and chemical character of ground water in the Morrison Formation, U.S. Geol. Survey Prof. Paper, 320, 55

Plummer, 1976

Porter, 1971, The interaction of silicic acid with iron(III) and uranyl ions in dilute aqueous solution, J. Inorg. Nucl. Chem, 33, 2443, 10.1016/0022-1902(71)80219-1

Rich, 1977, Hydrothermal uranium deposits, 6

Robie, 1968, Thermodynamic properties of minerals and related substances at 298.15 K and one atmosphere pressure and at higher temperatures, U.S. Geol. Survey Bull, 1259

Robins, 1966, Hydrolysis of uranyl nitrate solutions at elevated temperatures, J. Inorg. Nucl. Chem, 28, 119, 10.1016/0022-1902(66)80234-8

Rogers, 1970, Uranium, II-2

Rose, 1977, Geochemical exploration for uranium, 303

Rosenzweig, 1975, Refinement of the crystal structure of cuprosklodowskite, Cu[(UO2)2(SiO3OH)2].6H2O, Am. Mineralogist, 60, 448

Savage, 1960, The solubility of uranium (IV) fluoride in aqueous fluoride solutions, J. Am. Chem. Soc, 82, 4817, 10.1021/ja01503a016

Scanlan, 1977, Equilibria in uranyl carbinate systems-II. The overall stability constant of UO2(CO3)22−and the third formation constant of UO2(CO3)34−, J. Inorg. Nucl. Chem, 39, 635, 10.1016/0022-1902(77)80578-2

Schmidt-collérus, 1967, Research in uranium geochemistry. Investigations of the relationship between organic matter and uranium deposits—I

Scott, 1962, Data on uranium and radium in ground water in the United States, U.S. Geol. Survey Prof. Paper, 426

Sergeyeva, 1972, Experimental investigation of equilibria in the system UO3-CO2- H2O in 25–200°C temperature interval, Geochem. Intl, 9, 900

Sillén, 1964, Stability constants of metal-ion complexes

Sillén, 1971, Stability constants of metal-ion complexes

Smith, 1977

Stieff, 1956, Coffinite, a uranous silicate with hydroxyl substitution—a new mineral, Am. Mineralogist, 41, 675

Swanson, 1953, Standard X-ray diffraction patterns, Natl. Bur. Stds. Circ. 539, 2

Szalay, 1964, Cation exchange properties of humic acids and their importance in the geochemical enrichment of UO22+ and other cations, Geochim. Cosmochim. Acta, 28, 1605, 10.1016/0016-7037(64)90009-2

Szalay, 1969, Investigation of the leaching of uranium from crushed magmatic rock, Geochem. Intl, 6, 613

Tsymbal, 1969, Contribution to the solution chemistry of uranium (VI), Nucl. Sci. Abs, 23

Van Der Weiiden, 1976, Sorption of uranyl by hematite: theoretical and geochemical implications

Van Der Weiiden, 1976

Van Lierde, 1970, On the phase limits of U409, J. Nucl. Mater, 37, 276, 10.1016/0022-3115(70)90157-1

Wagman, 1968, Selected values of chemical thermodynamic properties, Natl. Bur. Standards Tech. Note 270-3

Wagman, 1969, Selected values of chemical thermodynamic properties, Nat. Bur. Standards Tech. Note 270-4

Wagman, 1971, Selected values of chemical thermodynamic properties, Natl. Bur. Standards Tech. Note 270-5

Wagman, 1977

Weeks, 1959, Summary of the ore mineralogy-V, 66

Weeks, 1959, Geologic setting of the Colorado Plateau areas-I, 3

Weigel, 1976, The phosphates and arsenates of hexavalent actinides—I. Uranium, J. LessCommon Metals, 44, 99, 10.1016/0022-5088(76)90121-1

Westrum, 1963, Chemical thermodynamics of the actinide element chalcogenides. Thermodynamics of nuclear materials, 3

White, 1963, Chemical composition of sub-surface waters, Data of Geochemistry, 6th Edn. U.S. Geol. Survey of Prof. Paper, 440-F