Understanding the influence of the electrochemical double-layer on heterogeneous electrochemical reactions

González, 2016, Review on supercapacitors: technologies and materials, Renew Sustain Energy Rev, 58, 1189, 10.1016/j.rser.2015.12.249 Sharma, 2010, A review on electrochemical double-layer capacitors, Energy Convers Manag, 51, 2901, 10.1016/j.enconman.2010.06.031 Uddin, 2017, Influence of designed electrode surfaces on double layer capacitance in aqueous electrolyte: insights from standard models, Appl Surf Sci Bard, 2000 Bockris, 1965, On the structure of charged interfaces, 832 Grahame, 1947, The electrical double layer and the theory of electrocapillarity, Chem Rev, 41, 441, 10.1021/cr60130a002 Parsons, 1990, The electrical double layer: recent experimental and theoretical developments, Chem Rev, 90, 813, 10.1021/cr00103a008 Ito, 2008, Structures of water at electrified interfaces: microscopic understanding of electrode potential in electric double layers on electrode surfaces, Surf Sci Rep, 63, 329, 10.1016/j.surfrep.2008.04.002 Ataka, 1998, In situ infrared study of water−sulfate coadsorption on gold(111) in sulfuric acid solutions, Langmuir, 14, 951, 10.1021/la971110v Ataka, 1996, Potential-dependent reorientation of water molecules at an electrode/electrolyte interface studied by surface-enhanced infrared absorption spectroscopy, J Phys Chem, 100, 10664, 10.1021/jp953636z Dunwell, 2016, A surface-enhanced infrared absorption spectroscopic study of pH dependent water adsorption on Au, Surf Sci, 650, 51, 10.1016/j.susc.2015.12.019 Futamata, 1999, In-situ ATR-IR study of water on gold electrode surface, Surf Sci, 427–428, 179, 10.1016/S0039-6028(99)00261-7 Futamata, 2005, ATR–SEIR study of anions and water adsorbed on platinum electrode, Surf Sci, 590, 196, 10.1016/j.susc.2005.06.020 Sheng, 2010, Hydrogen oxidation and evolution reaction kinetics on platinum: acid vs alkaline electrolytes, J Electrochem Soc, 157, B1529, 10.1149/1.3483106 Sheng, 2013, Correlating the hydrogen evolution reaction activity in alkaline electrolytes with the hydrogen binding energy on monometallic surfaces, Energy Environ Sci, 6, 1509, 10.1039/c3ee00045a Strmcnik, 2009, The role of non-covalent interactions in electrocatalytic fuel-cell reactions on platinum, Nat Chem, 1, 466, 10.1038/nchem.330 Zheng, 2015, Correlating hydrogen oxidation/evolution reaction activity with the minority weak hydrogen-binding sites on Ir/C catalysts, ACS Catal, 5, 4449, 10.1021/acscatal.5b00247 Zheng, 2018, Perspective—towards establishing apparent hydrogen binding energy as the descriptor for hydrogen oxidation/evolution reactions, J Electrochem Soc, 165, H27, 10.1149/2.0881802jes Ledezma-Yanez, 2017, Interfacial water reorganization as a pH-dependent descriptor of the hydrogen evolution rate on platinum electrodes, Nat Energy, 2, 17031, 10.1038/nenergy.2017.31 Baldelli, 2005, Probing electric fields at the ionic liquid−electrode interface using sum frequency generation spectroscopy and electrochemistry, J Phys Chem B, 109, 13049, 10.1021/jp052913r Baldelli, 2008, Surface structure at the ionic liquid−electrified metal interface, Acc Chem Res, 41, 421, 10.1021/ar700185h Rosen, 2012, In situ spectroscopic examination of a low overpotential pathway for carbon dioxide conversion to carbon monoxide, J Phys Chem C, 116, 15307, 10.1021/jp210542v Anaredy, 2016, Long-range ordering of ionic liquid fluid films, Langmuir, 32, 5147, 10.1021/acs.langmuir.6b00304 Carneiro-Neto, 2016, Simulation of interfacial pH changes during hydrogen evolution reaction, J Electroanal Chem, 765, 92, 10.1016/j.jelechem.2015.09.029 Katsounaros, 2011, The effective surface pH during reactions at the solid–liquid interface, Electrochem Commun, 13, 634, 10.1016/j.elecom.2011.03.032 Hori, 2008, Electrochemical CO2 reduction on metal electrodes, 89, 10.1007/978-0-387-49489-0_3 Hori, 1989, Formation of hydrocarbons in the electrochemical reduction of carbon dioxide at a copper electrode in aqueous solution, J Chem Soc Farad Trans 1: Phys Chem Condens Phases, 85, 2309, 10.1039/f19898502309 Gupta, 2006, Calculation for the cathode surface concentrations in the electrochemical reduction of CO2 in KHCO3 solutions, J Appl Electrochem, 36, 161, 10.1007/s10800-005-9058-y Raciti, 2018, Mass transport modelling for the electroreduction of CO2 on Cu nanowires, Nanotechnology, 29, 10.1088/1361-6528/aa9bd7 Dunwell, 2018, Examination of near-electrode concentration gradients and kinetic impacts on the electrochemical reduction of CO2 using surface-enhanced infrared spectroscopy, ACS Catal, 3999, 10.1021/acscatal.8b01032 Murata, 1991, Product selectivity affected by cationic species in electrochemical reduction of CO2 and CO at a Cu electrode, Bull Chem Soc Jpn, 64, 123, 10.1246/bcsj.64.123 Thorson, 2013, Effect of cations on the electrochemical conversion of CO2 to CO, J Electrochem Soc, 160, F69, 10.1149/2.052301jes Matanovic, 2014, density functional theory study of the alkali metal cation adsorption on Pt(111), Pt(100), and Pt(110) surfaces, ECS Trans, 61, 47, 10.1149/06113.0047ecst Mills, 2014, Alkali cation specific adsorption onto fcc(111) transition metal electrodes, Phys Chem Phys, 16, 13699, 10.1039/C4CP00760C McCrum, 2016, pH and alkali cation effects on the Pt cyclic voltammogram explained using density functional theory, J Phys Chem C, 120, 457, 10.1021/acs.jpcc.5b10979 Chen, 2017, Co-adsorption of cations as the cause of the apparent pH dependence of hydrogen adsorption on a stepped platinum single-crystal electrode, Angew Chem Int Ed, 56, 15025, 10.1002/anie.201709455 Akhade, 2016, The impact of specifically adsorbed ions on the copper-catalyzed electroreduction of CO2, J Electrochem Soc, 163, F477, 10.1149/2.0581606jes Singh, 2016, Hydrolysis of electrolyte cations enhances the electrochemical reduction of CO2 over Ag and Cu, J Am Chem Soc, 138, 13006, 10.1021/jacs.6b07612 Dunwell, 2017, Surface enhanced spectroscopic investigations of adsorption of cations on electrochemical interfaces, Phys Chem Phys, 19, 971, 10.1039/C6CP07207K Dunwell, 2017, The central role of bicarbonate in the electrochemical reduction of carbon dioxide on gold, J Am Chem Soc, 139, 3774, 10.1021/jacs.6b13287 Ong, 2013, Impact of 1mmoldm–3 concentrations of small molecules containing nitrogen-based cationic groups on the oxygen reduction reaction on polycrystalline platinum in aqueous KOH (1moldm–3), Phys Chem Phys, 15, 18992, 10.1039/c3cp50556a Woodroof, 2015, Exchange current density of the hydrogen oxidation reaction on Pt/C in polymer solid base electrolyte, Electrochem Commun, 61, 57, 10.1016/j.elecom.2015.09.027 Ayato, 2006, Study of Pt electrode/nafion ionomer interface in HClO4 by in situ surface-enhanced FTIR spectroscopy, J Electrochem Soc, 153, A203, 10.1149/1.2137648 Hanawa, 2012, In situ ATR-FTIR analysis of the structure of Nafion–Pt/C and Nafion–Pt3Co/C interfaces in fuel cell, J Phys Chem C, 116, 21401, 10.1021/jp306955q Kunimatsu, 2010, In situ ATR-FTIR study of oxygen reduction at the Pt/Nafion interface, Phys Chem Phys: PCCP, 12, 621, 10.1039/B917306D Kunimatsu, 2015, Analysis of the gold/polymer electrolyte membrane interface by polarization-modulated ATR-FTIR spectroscopy, J Phys Chem C, 119, 16754, 10.1021/acs.jpcc.5b04622 Zimudzi, 2015, Signal enhanced FTIR analysis of alignment in Nafion thin films at SiO2 and Au INTERFACES, ACS Macro Lett, 83