Linzhou Zhuang1, Lei Ge1, Yisu Yang1, Mengran Li1, Yi Jia2, Xiangdong Yao2, Zhonghua Zhu1
1School of Chemical Engineering, The University of Queensland, Brisbane, 4072, Australia
2School of Natural Sciences and Queensland, Micro- and Nanotechnology Centre, Griffith University, Nathan Campus 4111, Australia
Tóm tắt
Electrochemical water splitting is a promising method for storing light/electrical energy in the form of H2 fuel; however, it is limited by the sluggish anodic oxygen evolution reaction (OER). To improve the accessibility of H2 production, it is necessary to develop an efficient OER catalyst with large surface area, abundant active sites, and good stability, through a low‐cost fabrication route. Herein, a facile solution reduction method using NaBH4 as a reductant is developed to prepare iron‐cobalt oxide nanosheets (FexCoy‐ONSs) with a large specific surface area (up to 261.1 m2 g−1), ultrathin thickness (1.2 nm), and, importantly, abundant oxygen vacancies. The mass activity of Fe1Co1‐ONS measured at an overpotential of 350 mV reaches up to 54.9 A g−1, while its Tafel slope is 36.8 mV dec−1; both of which are superior to those of commercial RuO2, crystalline Fe1Co1‐ONP, and most reported OER catalysts. The excellent OER catalytic activity of Fe1Co1‐ONS can be attributed to its specific structure, e.g., ultrathin nanosheets that could facilitate mass diffusion/transport of OH− ions and provide more active sites for OER catalysis, and oxygen vacancies that could improve electronic conductivity and facilitate adsorption of H2O onto nearby Co3+ sites.
