Two new alkaloids from Crinum asiaticum var. japonicum

Journal of Natural Medicines - Tập 73 - Trang 648-652 - 2019
Yuta Endo1, Yu Sugiura1, Mariko Funasaki1, Hiroyuki Kagechika2, Masami Ishibashi3, Ayumi Ohsaki1
1College of Humanities and Sciences, Nihon University, Tokyo, Japan
2Biomaterials and Engineering, Tokyo Medical and Dental University, Kanda, Japan
3Graduate School of Pharmaceutical Sciences, Chiba University, Chiba, Japan

Tóm tắt

A new crinine-type alkaloid crijaponine A (1), a new galanthamine-type alkaloid crijaponine B (2), and 11 known alkaloids—ungeremine (3), lycorine (4), 2-O-acetyllycorine (5), 1, 2-O-diacetyllycorine (6), (−)-crinine (7), 11-hydroxyvittatine (8), hamayne (9), (+)-epibuphanisine (10), crinamine (11), yemenine A (12), and epinorgalanthamine (13)—were isolated from the rhizome and fruits of Crinum asiaticum var. japonicum. The structural elucidation of the isolated compounds was performed by spectroscopic methods including 2D NMR. The isolated compounds were evaluated for cytotoxicity against HeLa and HL-60 cells lines and were tested for acetylcholinesterase inhibition activity.

Tài liệu tham khảo

Lamoral-Theys D, Andolfi A, Goietsenoven GV, Cimmino A, Le Calvé B, Wauthoz N, Mégalizzi V, Gras T, Bruyère C, Dubois J, Mathieu V, Kornienko A, Kiss R, Evidente A (2009) Lycorine, the main phenanthridine Amaryllidaceae alkaloid, exhibits significant antitumor activity in cancer cells that display resistance to proapoptotic stimuli: an investigation of structure–activity relationship and mechanistic insight. J Med Chem 52:6244–6256 Tam NT, Chang J, Jung E, Cho C (2008) Total syntheses of (±)-crinine and (±)-buphanisine. J Org Chem 73:6258–6264 Abou-Donia AH, Toaima SM, Hammoda HM, Shawky E, Kinoshita E, Takayama H (2008) Phytochemical and biological investigation of Hymenocallis littoralis Salisb. Chem Biodivers 5:332–340 Ochi M, Otsuki H, Nagano K (1976) The structure of hamayne, a new alkaloid from Crinum asiaticum L. var. japonicum Baker. Bull Chem Soc Jpn 49:3363–3364 Viladomat F, Bastida J, Codina C, Campbell WE, Mathee S (1995) Alkaloids from Boophane flava. Phytochemistry 40:307–311 Abdel-Halim OB, Morikawa T, Ando S, Matsuda H, Yoshikawa M (2004) New crinine-type alkaloids with inhibitory effect on induction of inducible nitric oxide synthase from Crinum yemense. J Nat Prod 67:1119–1124 Bastida J, Viladomat F, Bergonon S, Fernandez JM, Codina C, Rubiralta M, Quirion JC (1993) Alkaloids from Narcissus leonensis. Phytochemistry 34:1656–1658 Wagner J, Pham HL, Doepke W (1996) Alkaloids from Hippeastrum equestre Herb.—5. Circular dichroism studies. Tetrahedron 52:6591–6600 DeAngelis GG, Wildman WC (1969) Identification of Amaryllidaceae alkaloids utilizing ORD and CD spectroscopy. Tetrahedron Lett 9:729–732 Shimada M, Ozawa M, Iwamoto K, Fukuyama Y, Kishida A, Ohsaki A (2014) A Lanostane Triterpenoid and three Cholestane Sterols from Tilia kiusiana. Chem Pharm Bull 62:937–941 Ellman GL, Courtney KD, Andres V Jr, Featherstone RM (1961) A new and rapid colorimetric determination of acetylcholinesterase activity. Biochem Pharm 7:88–90