Two-dimensional CoNi@mesoporous carbon composite with heterogeneous structure toward broadband microwave absorber

Lv, H. L.; Yang, Z. H.; Wang, P. L.; Ji, G. B.; Song, J. Z.; Zheng, L. R.; Zeng, H. B.; Xu, Z. J. A voltage-boosting strategy enabling a low-frequency, flexible electromagnetic wave absorption device. Adv. Mater. 2018, 30, e1706343. Ma, T. B.; Ma, H.; Ruan, K. P.; Shi, X. T.; Qiu, H.; Gao, S. Y.; Gu, J. W. Thermally conductive poly(lactic acid) composites with superior electromagnetic shielding performances via 3D printing technology. Chin. J. Polym. Sci. 2022, 40, 248–255. Zhang, Y. L.; Ruan, K. P.; Gu, J. W. Flexible sandwich-structured electromagnetic interference shielding nanocomposite films with excellent thermal conductivities. Small 2021, 17, 2101951. Ma, Z. L.; Xiang, X. L.; Shao, L.; Zhang, Y. L.; Gu, J. W. Multifunctional wearable silver nanowire decorated leather nanocomposites for joule heating, electromagnetic interference shielding and piezoresistive sensing. Angew. Chem., Int. Ed. 2022, 61, e202200705. Han, Y. X.; Ruan, K. P.; Gu, J. W. Janus (BNNS/ANF)-(AgNWs/ANF) thermal conductivity composite films with superior electromagnetic interference shielding and Joule heating performances. Nano Res. 2022, 15, 4747–4755. Gou, G. J.; Meng, F. B.; Wang, H. G.; Jiang, M.; Wei, W.; Zhou, Z. W. Wheat straw-derived magnetic carbon foams: In-situ preparation and tunable high-performance microwave absorption. Nano Res. 2019, 12, 1423–1429. Saini, L.; Jani, R. K.; Janu, Y.; Kumar, M.; Patra, M. K.; Dixit, A. Gamma radiation induced microwave absorption properties of ultra-thin barium titanate (BaTiO3) ceramic tiles over X-band (8.2–12.4 GHz). Ceram. Int. 2021, 47, 22397–22403. Chen, X. L.; Wang, Y.; Liu, H. L.; Jin, S.; Wu, G. L. Interconnected magnetic carbon@NixCo1−xFe2O4 nanospheres with core-shell structure: An efficient and thin electromagnetic wave absorber. J. Colloid Interface. Sci. 2022, 606, 526–536. Pan, J. L.; Guo, H. G.; Wang, M.; Yang, H.; Hu, H. W.; Liu, P.; Zhu, H. W. Shape anisotropic Fe3O4 nanotubes for efficient microwave absorption. Nano Res. 2020, 13, 621–629. Yan, J.; Huang, Y.; Zhang, X. Y.; Gong, X.; Chen, C.; Nie, G. D.; Liu, X. D.; Liu, P. B. MoS2-decorated/integrated carbon fiber: Phase engineering well-regulated microwave absorber. Nano-Micro Lett. 2021, 13, 114. Xiang, Z.; Shi, Y. Y.; Zhu, X. J.; Cai, L.; Lu, W. Flexible and waterproof 2D/1D/0D construction of MXene-based nanocomposites for electromagnetic wave absorption, EMI shielding, and photothermal conversion. Nano-Micro Lett. 2021, 13, 150. Quan, B.; Gu, W. H.; Sheng, J. Q.; Lv, X. F.; Mao, Y. Y.; Liu, L.; Huang, X. G.; Tian, Z. J.; Ji, G. B. From intrinsic dielectric loss to geometry patterns: Dual-principles strategy for ultrabroad band microwave absorption. Nano Res. 2021, 14, 1495–1501. Wang, Y. Y.; Zhou, Z. H.; Zhou, C. G.; Sun, W. J.; Gao, J. F.; Dai, K.; Yan, D. X.; Li, Z. M. Lightweight and robust carbon nanotube/polyimide foam for efficient and heat-resistant electromagnetic interference shielding and microwave absorption. ACS Appl. Mater. Interfaces. 2020, 12, 8704–8712. Qiu, Y.; Yang, H. B.; Ma, L.; Lin, Y.; Zong, H. W.; Wen, B.; Bai, X. Y.; Wang, M. Q. In situ-derived carbon nanotube-decorated nitrogen-doped carbon-coated nickel hybrids from MOF/melamine for efficient electromagnetic wave absorption. J. Colloid Interface. Sci. 2021, 581, 783–793. Wang, L.; Ma, Z. L.; Zhang, Y. L.; Chen, L. X.; Cao, D. P.; Gu, J. W. Polymer-based EMI shielding composites with 3D conductive networks: A mini-review. SusMat 2021, 1, 413–431. Wang, Y. Y.; Zhou, Z. H.; Zhu, J. L.; Sun, W. J.; Yan, D. X.; Dai, K.; Li, Z. M. Low-temperature carbonized carbon nanotube/cellulose aerogel for efficient microwave absorption. Compos. Part B:Eng. 2021, 220, 108985. Zhao, Y. P.; Zuo, X. Q.; Guo, Y.; Huang, H.; Zhang, H.; Wang, T.; Wen, N. X.; Chen, H.; Cong, T. Z.; Muhammad, J. et al. Structural engineering of hierarchical aerogels comprised of multi-dimensional gradient carbon nanoarchitectures for highly efficient microwave absorption. Nano-Micro Lett. 2021, 13, 144. Zhang, Y. L.; Ma, Z. L.; Ruan, K. P.; Gu, J. W. Multifunctional Ti3C2Tx-(Fe3O4/polyimide) composite films with Janus structure for outstanding electromagnetic interference shielding and superior visual thermal management. Nano Res. 2022, 15, 5601–5609. Qiu, Y.; Lin, Y.; Yang, H. B.; Wang, L.; Wang, M. Q.; Wen, B. Hollow Ni/C microspheres derived from Ni-metal organic framework for electromagnetic wave absorption. Chem Eng J. 2020, 383, 123207. Xu, C. Y.; Wang, L.; Li, X.; Qian, X.; Wu, Z. C.; You, W. B.; Pei, K.; Qin, G.; Zeng, Q. W.; Yang, Z. Q. et al. Hierarchical magnetic network constructed by cofe nanoparticles suspended within “tubes on rods” matrix toward enhanced microwave absorption. Namo-Micro Lett. 2021, 13, 47. Jin, L. Q.; Yi, P. S.; Wan, L.; Hou, J. S.; Chen, P.; Zu, J. Q.; Wei, B.; Yao, Z. J.; Zhou, J. T. Thickness-controllable synthesis of MOF-derived Ni@N-doped carbon hexagonal nanoflakes with dielectric—magnetic synergy toward wideband electromagnetic wave absorption. Chem. Eng. J. 2022, 427, 130940. Tong, Z. Y.; Bi, Y. X.; Ma, M. L.; Liao, Z. J.; Huang, W. B.; Chung, K. L.; Ma, Y.; Wu, G. L.; Qu, Y. L; Pan, C. B. et al. Fabrication of flower-like surface Ni@Co3O4 nanowires anchored on RGO nanosheets for high-performance microwave absorption. Appl. Surf. Sci. 2021, 565, 150483. Shu, J. C.; Cao, W. Q.; Cao, M. S. Diverse metal-organic framework architectures for electromagnetic absorbers and shielding. Adv. Funct. Mater. 2021, 31, 2100470. Ge, J. W.; Cui, Y.; Qian, J. X.; Liu, L.; Meng, F. D.; Wang, F. H. Morphology-controlled CoNi/C hybrids with bifunctions of efficient anti-corrosion and microwave absorption. J. Mater. Sci. Technol. 2022, 102, 24–35. Qiu, Y.; Yang, H. B.; Cheng, Y.; Lin, Y. MOFs derived flower-like nickel and carbon composites with controllable structure toward efficient microwave absorption. Compos. Part A-Appl. S. 2022, 154, 10677. Wen, B.; Yang, H. B.; Lin, Y.; Ma, L.; Qiu, Y.; Hu, F. F.; Zheng, Y. N. Synthesis of core-shell Co@S-doped carbon@mesoporous N-doped carbon nanosheets with a hierarchically porous structure for strong electromagnetic wave absorption. J. Mater. Chem. A 2021, 9, 3567–3575. Qiu, Y.; Yang, H. B.; Cheng, Y.; Wen, B.; Lin, Y. Structure design of Prussian blue analogue derived CoFe@C composite with tunable microwave absorption performance. Appl. Surf. Sci. 2022, 571, 151334. Yu, Y. L.; Wang, M.; Bai, Y. Q.; Zhang, B.; An, L. L.; Zhang, J. Y.; Zhong, B. Tuning the inner hollow structure of lightweight amorphous carbon for enhanced microwave absorption. Chem. Eng. J. 2019, 375, 121914. Qiu, Y.; Yang, H. B.; Cheng, Y.; Bai, X. Y.; Wen, B.; Lin, Y. Constructing a nitrogen-doped carbon and nickel composite derived from a mixed ligand nickel-based a metal-organic framework toward adjustable microwave absorption. Nanoscale 2021, 13, 9204–9216. Pan, F.; Liu, Z. C.; Deng, B. W.; Dong, Y. Y.; Zhu, X. J.; Huang, C.; Lu, W. Lotus leaf-derived gradient hierarchical porous C/MoS2 morphology genetic composites with wideband and tunable electromagnetic absorption performance. Nano-Micro Lett. 2021, 13, 43. Lv, H. L.; Zhou, X. D.; Wu, G. L.; Kara, U. I.; Wang, X. G. Engineering defects in 2D g-C3N4 for wideband, efficient electromagnetic absorption at elevated temperature. J. Mater. Chem. A 2021, 9, 19710–19718. Zhu, Y. Y.; An, S. L.; Sun, X. J.; Lan, D. W.; Cui, J. L.; Zhang, Y. Q.; He, W. X. Core-branched NiCo2S4@CoNi-LDH heterostructure as advanced electrode with superior energy storage performance. Chem. Eng. J. 2020, 383, 123206. Lan, K.; Wei, Q. L.; Wang, R. C.; Xia, Y.; Tan, S. S.; Wang, Y. X.; Elzatahry, A.; Feng, P. Y.; Mai, L. Q.; Zhao, D. Y. Two-dimensional mesoporous heterostructure delivering superior pseudocapacitive sodium storage via bottom-up monomicelle assembly. J. Am. Chem. Soc. 2019, 141, 16755–16762. Li, C.; Qi, X. S.; Gong, X.; Peng, Q.; Chen, Y. L.; Xie, R.; Zhong, W. Magnetic-dielectric synergy and interfacial engineering to design yolk-shell structured CoNi@void@C and CoNi@void@C@MoS2 nanocomposites with tunable and strong wideband microwave absorption. Nano Res. 2022, 15, 6761–6771. Wu, F.; Wan, L. Y.; Wang, T.; Tariq, M. R.; Shah, T.; Liu, P.; Zhang, Q. Y.; Zhang, B. L.; Construction of binary assembled MOF-derived nanocages with dual-band microwave absorbing properties. J. Mater. Sci. Technol. 2022, 117, 36–48. Xu, H.; Yin, X.; Zhu, M.; Han, M.; Hou, Z.; Li, X.; Zhang, L.; Cheng, L. Carbon hollow microspheres with a designable mesoporous shell for high-performance electromagnetic wave absorption. ACS Appl. Mater. Interfaces. 2017, 9, 6332–6341. Qiu, X.; Wang, L. X.; Zhu, H. L.; Guan, Y. K.; Zhang, Q. T. Lightweight and efficient microwave absorbing materials based on walnut shell-derived nano-porous carbon. Nanoscale 2017, 9, 7408–7418. Peng, L.; Peng, H. R.; Hung, C. T.; Guo, D. Y.; Duan, L. L.; Ma, B.; Liu, L. L.; Li, W.; Zhao, D. Y. Programmable synthesis of radially gradient-structured mesoporous carbon nanospheres with tunable core-shell architectures. Chem 2021, 7, 1020–1032. Liu, P. B.; Gao, S.; Wang, Y.; Zhou, F. T.; Huang, Y.; Huang, W. H.; Chang, N. H. Core-shell Ni@C encapsulated by N-doped carbon derived from nickel-organic polymer coordination composites with enhanced microwave absorption. Carbon 2020, 170, 503–516. Huang, W. H.; Zhang, X. X.; Zhao, Y. N.; Zhang, J.; Liu, P. B. Hollow N-doped carbon polyhedra embedded Co and Mo2C nanoparticles for high-efficiency and wideband microwave absorption. Carbon 2020, 167, 19–30. Luo, J. H.; Feng, M. N.; Dai, Z. Y.; Jiang, C. Y.; Jiang, C. Y.; Yao, W.; Zhai, N. X. MoS2 wrapped MOF-derived N-doped carbon nanocomposite with wideband electromagnetic wave absorption. Nano Res. 2022, 15, 5781–5789. Duan, Y. P.; Liu, Z.; Jing, H.; Zhang, Y. H.; Li, S. Q. Novel microwave dielectric response of Ni/Co-doped manganese dioxides and their microwave absorbing properties. J. Mater. Chem. 2012, 22, 18291–18299. Liu, Y.; Jia, Z. R.; Zhan, Q. Q.; Dong, Y. H.; Xu, Q, M.; Wu, G. L. Magnetic manganese-based composites with multiple loss mechanisms towards broadband absorption. Nano Res. 2022, 15, 5590–5600. Zhao, Y. Z.; Wang, W.; Wang, J. N.; Zhai, J. J.; Lei, X. Y.; Zhao, W.; Li, J. N.; Yang, H. W.; Tian, J. X.; Yan, J. F. Constructing multiple heterogeneous interfaces in the composite of bimetallic MOF-derivatives and rGO for excellent microwave absorption performance. Carbon 2021, 173, 1059–1072. Zhang, C. W.; Peng, Y.; Song, Y.; Li, J. J.; Yin, F. X.; Yuan, Y. Periodic three-dimensional nitrogen-doped mesoporous carbon spheres embedded with Co/Co3O4 nanoparticles toward microwave absorption. ACS Appl. Mater. Inter. 2020, 12, 24102–24111. Zhang, R. X.; Wang, L.; Xu, C. Y.; Liang, C. Y.; Liu, X. H.; Zhang, X. F.; Che, R. C. Vortex tuning magnetization configurations in porous Fe3O4 nanotube with wide microwave absorption frequency. Nano Res. 2022, 15, 6743–6750. Wang, Y. C.; Yao, L. H.; Zheng, Q.; Cao, M. S. Graphene-wrapped multiloculated nickel ferrite: A highly efficient electromagnetic attenuation material for microwave absorbing and green shielding. Nano Res. 2022, 15, 6751–6760. Wang, Y. Y.; Sun, W. J.; Lin, H.; Gao, P. P.; Gao, J. F.; Gai, K.; Yan, D. X.; Li, Z. M. Steric stabilizer-based promotion of uniform polyaniline shell for enhanced electromagnetic wave absorption of carbon nanotube/polyaniline hybrids. Compos Part B-Eng. 2020, 199, 108309. Liu, J.; Tao, L. L.; Gao, X. X.; He, X. X.; Wei, B.; Gu, Y. S.; Yao, Z. J.; Zhou, J. T. Morphology-size synergy strategy of SiC@C nanoparticles towards lightweight and efficient microwave absorption. Chem. Eng. J. 2022, 433, 134484. Pan, J. J.; Sun, X.; Jin, Z. Z.; Wang, T.; Zhao, Q. L.; Qu, H. J.; He, J. P. Constructing two-dimensional lamellar monometallic carbon nanocomposites by sodium chloride hard template for lightweight microwave scattering and absorption. Compos. Pt. B-Eng. 2022, 228, 109422. Li, X.; You, W. B.; Xu, C. Y.; Wang, L.; Yang, L. T.; Li, Y. S.; Che, R. C. 3D seed-germination-like mxene with in situ growing CNTs/Ni heterojunction for enhanced microwave absorption via polarization and magnetization. Nano-Micro Lett. 2021, 13, 157. Xiang, Z.; Zhang, X.; Shi, Y. Y.; Cai, L.; Cheng, J.; Jiang, H.; Zhu, X.; Dong, Y.; Lu, W. Efficient microwave absorption of MOFs derived laminated porous Ni@C nanocomposites with waterproof and infrared shielding versatility. Carbon 2021, 185, 477–490. Wei, B.; Zhou, C. Y.; Yao, Z. J.; Chen, P.; Wang, M. Q.; Li, Z. J.; Zhou, J. T.; Hou, J. S.; Li, W. Encapsulation of high specific surface area red blood cell-like mesoporous carbon spheres by magnetic nanoparticles: A new strategy to realize multiple electromagnetic wave loss mechanism. Carbon 2021, 184, 232–244. Tao, J. Q.; Xu, L. L.; Wan, L.; Hou, J. S.; Yi, P. S.; Chen, P.; Zhou, J. T.; Yao, Z. J. Cubic-like Co/NC composites derived from ZIF-67 with a dual control strategy of size and graphitization degree for microwave absorption. Nanoscale 2021, 13, 12896–12909. Lei, L.; Yao, Z. J.; Zhou, J. T.; Zheng, W. J.; Wei, B.; Zu, J. Q.; Yan, Y. K. Hydrangea-like Ni/NiO/C composites derived from metal-organic frameworks with superior microwave absorption. Carbon 2021, 173, 69–79. Li, J. J.; Zhang, F.; Lu, H. B.; Guo, W. B.; He, X. D.; Yuan, Y. Heterogeneous rod-like Ni@C composites toward strong and stable microwave absorption performance. Carbon 2021, 181, 358–369. Liu, D. W.; Du, Y. C.; Xu, P.; Wang, F. Y.; Wang, Y. H.; Cui, L. R.; Zhao, H. H.; J., H. X. Rationally designed hierarchical N-doped carbon nanotubes wrapping waxberry-like Ni@C microspheres for efficient microwave absorption. J. Mater. Chem. A 2021, 9, 5086–5096. Xu, X. Q.; Ran, F. T.; Fan, Z. M.; Cheng, Z. J.; Lv, T.; Shao, L.; Liu, Y. Y. Bimetallic metal-organic framework-derived pomegranate-like nanoclusters coupled with CoNi-doped graphene for strong wideband microwave absorption. ACS Appl. Mater. Inter. 2020, 12, 17882–17892. Wang, Y. Q.; Wang, H. G.; Ye, J. H.; Shi, L. Y.; Feng, X. Magnetic CoFe alloy@C nanocomposites derived from ZnCo-MOF for electromagnetic wave absorption. Chem. Eng. J. 2020, 383, 123096. Zhou, J.; Guo, F.; Luo, J. L.; Hao, G. Z.; Liu, G. G.; Hu, Y. B.; Zhang, G. P.; Guo, H.; Zhou, H.; Jiang, W. Designed 3D heterostructure with 0D/1D/2D hierarchy for low-frequency microwave absorption in the S-band. J. Mater. Chem. C. 2022, 10, 1470–1478. Di, X. C.; Wang, Y.; Fu, Y. Q.; Wu, X. M.; Wang, P. Wheat flour-derived nanoporous carbon@ZnFe2O4 hierarchical composite as an outstanding microwave absorber. Carbon 2021, 173, 174–184.