Tuning Fe-spin state of FeN4 structure by axial bonds as efficient catalyst in Li-S batteries

Energy Storage Materials - Tập 55 - Trang 490-497 - 2023
Gan Qu1, Kai Guo1, Jichen Dong2, Haojie Huang2,3, Pengfei Yuan4, Yajin Wang1, Huiyu Yuan1, Lirong Zheng5, Jia-Nan Zhang1
1School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, PR China
2Beijing National Laboratory for Molecular Sciences, Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China
3University of Chinese Academy of Sciences, Beijing 100049, PR China
4School of Physics and Microelectronics, Zhengzhou University, Zhengzhou, 450001, PR China
5Institute of High Energy Physics, Chinese Academy of Sciences, No. 19B Yuquan Road, Beijing 100049, PR China

Tài liệu tham khảo

Bai, 2016, Metal-organic framework-based separator for lithium-sulfur batteries, Nat. Energy, 1, 16094, 10.1038/nenergy.2016.94 Yin, 2013, Lithium-sulfur batteries: electrochemistry, materials, and prospects, Angew. Chem. Int. Ed., 52, 13186, 10.1002/anie.201304762 Li, 2018, Revisiting the role of polysulfides in lithium-sulfur batteries, Adv. Mater., 30 Song, 2022, Cationic lithium polysulfides in lithium-sulfur batteries, Chem, 8, 3031, 10.1016/j.chempr.2022.07.004 Wang, 2022, Design rules of a sulfur redox electrocatalyst for lithium-sulfur batteries, Adv. Mater., 34 Li, 2022, Finely-dispersed Ni2Co nanoalloys on flower-like graphene microassembly empowering a Bi-service matrix for superior lithium-sulfur electrochemistry, Adv. Funct. Mater., 32 Wang, 2022, Nickel-platinum alloy nanocrystallites with high-index facets as highly effective core catalyst for lithium-sulfur batteries, Adv. Funct. Mater., 32 Chen, 2022, Toward practical high-energy-density lithium-sulfur pouch cells: a review, Adv. Mater., 34 Liu, 2018, Catalytic effects in lithium-sulfur batteries: promoted sulfur transformation and reduced shuttle effect, Adv. Sci., 5 Peng, 2020, A fundamental look at electrocatalytic sulfur reduction reaction, Nat. Catal., 3, 762, 10.1038/s41929-020-0498-x Zhao, 2021, Semi-immobilized molecular electrocatalysts for high-performance lithium-sulfur batteries, J. Am. Chem. Soc., 143, 19865, 10.1021/jacs.1c09107 Xiao, 2022, Electronic structure adjustment of lithium sulfide by a single-atom copper catalyst toward high-rate lithium-sulfur batteries, Energy Storage Mater., 51, 890, 10.1016/j.ensm.2022.07.024 Peng, 2022, Boosting sulfur redox kinetics by a pentacenetetrone redox mediator for high-energy-density lithium-sulfur batteries, Nano Res., 10.1007/s12274-022-4584-z Pang, 2019, Lightweight metallic MgB2 mediates polysulfide redox and promises high-energy-density lithium-sulfur batteries, Joule, 3, 136, 10.1016/j.joule.2018.09.024 Qiao, 2021, Anchoring polysulfides and accelerating redox reaction enabled by Fe-based compounds in lithium-sulfur batteries, Adv. Funct. Mater., 31, 10.1002/adfm.202100970 Zhao, 2020, Electrochemical phase evolution of metal-based pre-catalysts for high-rate polysulfide conversion, Angew. Chem. Int. Ed., 59, 9011, 10.1002/anie.202003136 Guo, 2022, Single Mo-N4 atomic sites anchored on N-doped carbon nanoflowers as sulfur host with multiple immobilization and catalytic effects for high-performance lithium-sulfur batteries, Adv. Funct. Mater., 32, 10.1002/adfm.202204458 Kim, 2022, Atomic structure modification of Fe-N-C catalysts via morphology engineering of graphene for enhanced conversion kinetics of lithium-sulfur batteries, Adv. Funct. Mater., 32 Wang, 2021, Atomic tungsten on graphene with unique coordination enabling kinetically boosted lithium-sulfur batteries, Angew. Chem. Int. Ed., 60, 15563, 10.1002/anie.202104053 Du, 2019, Cobalt in nitrogen-doped graphene as single-atom catalyst for high-sulfur content lithium-sulfur batteries, J. Am. Chem. Soc., 141, 3977, 10.1021/jacs.8b12973 Yao, 2022, Dynamic intercalation-conversion site supported ultrathin 2D mesoporous SnO2/SnSe2 hybrid as bifunctional polysulfide immobilizer and lithium regulator for lithium-sulfur chemistry, ACS Nano, 16, 10783, 10.1021/acsnano.2c02810 Hutchison, 2022, Multilevel computational studies reveal the importance of axial ligand for oxygen reduction reaction on Fe-N-C materials, J. Am. Chem. Soc., 144, 16524, 10.1021/jacs.2c05779 Benjamin, 2018, Controlled doping of transition metal dichalcogenides by metal work function tuning in phthalocyanine compounds, Nanoscale, 10, 5148, 10.1039/C7NR08497H Chen, 2009, Unraveling oxygen reduction reaction mechanisms on carbon-supported Fe-phthalocyanine and co-phthalocyanine catalysts in alkaline solutions, J. Phys. Chem. C, 113, 20689, 10.1021/jp906408y Yang, 2021, Recent advances in electrocatalysis with phthalocyanines, Chem. Soc. Rev., 50, 12985, 10.1039/D0CS01605E Huang, 2022, Altering local chemistry of single-atom coordination boosts bidirectional polysulfide conversion of Li-S batteries, Adv. Funct. Mater. Lu, 2020, Single-atom catalytic materials for lean-electrolyte ultrastable lithium-sulfur batteries, Nano Lett., 20, 5522, 10.1021/acs.nanolett.0c02167 Qiu, 2020, Precise synthesis of Fe-N2 sites with high activity and stability for long-life lithium-sulfur batteries, ACS Nano, 14, 16105, 10.1021/acsnano.0c08056 Kim, 2021, Cobalt(II)-centered fluorinated phthalocyanine-sulfur SNAr chemistry for robust lithium-sulfur batteries with superior conversion kinetics, Adv. Funct. Mater., 31, 10.1002/adfm.202106679 Yang, 2021, Regulating Fe-spin state by atomically dispersed Mn-N in Fe-N-C catalysts with high oxygen reduction activity, Nat. Commun., 12, 1734, 10.1038/s41467-021-21919-5 Cheng, 1997, Control of spin state by ring conformation of Iron(III) porphyrins. A novel model for the quantum-mixed intermediate spin state of ferric cytochrome c‘ from photosynthetic bacteria, J. Am. Chem. Soc., 119, 2563, 10.1021/ja962474x Dobbelaar, 2022, Thermal and magnetic field switching in a two-step hysteretic MnIII spin crossover compound coupled to symmetry breakings, Angew. Chem. Int. Ed., 61, 10.1002/anie.202114021 Mondal, 2013, On/off photoswitching in a cyanide-bridged {Fe2Co2} magnetic molecular square, J. Am. Chem. Soc., 135, 1653, 10.1021/ja3087467 Chen, 2017, Delocalized spin states in 2D atomic layers realizing enhanced ectrocatalytic oxygen evolution, Adv. Mater., 29 Tsukahara, 2009, Adsorption-induced switching of magnetic anisotropy in a single Iron(II) phthalocyanine molecule on an oxidized Cu(110) surface, Phys. Rev. Lett., 102, 10.1103/PhysRevLett.102.167203 Gutiérrez-Ceron, 2019, Molecular conductance versus inductive effects of axial ligands on the electrocatalytic activity of self-assembled iron phthalocyanines: the oxygen reduction reaction, Electrochim. Acta, 327, 10.1016/j.electacta.2019.134996 Cao, 2013, Promotion of oxygen reduction by a bio-inspired tethered iron phthalocyanine carbon nanotube-based catalyst, Nat. Commun., 4, 2076, 10.1038/ncomms3076 Chen, 2020, Iron phthalocyanine with coordination induced electronic localization to boost oxygen reduction reaction, Nat. Commun., 11, 4173, 10.1038/s41467-020-18062-y Coleman, 2011, Two-dimensional nanosheets produced by liquid exfoliation of layered materials, Science, 331, 568, 10.1126/science.1194975 Babu, 2017, Transition metal dichalcogenide atomic layers for lithium polysulfides electrocatalysis, J. Am. Chem. Soc., 139, 171, 10.1021/jacs.6b08681 Kwon, 2019, Two-dimensional MoS2/Fe-phthalocyanine hybrid nanostructures as excellent electrocatalysts for hydrogen evolution and oxygen reduction reactions, Nanoscale, 11, 14266, 10.1039/C9NR04156G Haldar, 2018, Comparative study of electronic and magnetic properties of iron and cobalt phthalocyanine molecules physisorbed on two-dimensional MoS2 and graphene, Phys. Rev. B, 98, 10.1103/PhysRevB.98.085440 Meng, 2022, Hybridization of iron phthalocyanine and MoS2 for high-efficiency and durable oxygen reduction reaction, J. Energy Chem., 71, 528, 10.1016/j.jechem.2022.04.031 Xu, 2015, One-pot, facile, and versatile synthesis of monolayer MoS2/WS2 quantum dots as bioimaging probes and efficient electrocatalysts for hydrogen evolution reaction, Adv. Funct. Mater., 25, 1127, 10.1002/adfm.201403863 Liu, 2007, Theoretical investigation of the molecular, electronic structures and vibrational spectra of a series of first transition metal phthalocyanines, Spectrochim. Acta Part A, 67, 1232, 10.1016/j.saa.2006.10.013 Li, 2018, The marriage of the FeN4 moiety and MXene boosts oxygen reduction catalysis: fe 3d electron delocalization matters, Adv. Mater., 30 Funke, 2005, Wavelet analysis of extended x-ray absorption fine structure data, Phys. Rev. B, 71, 10.1103/PhysRevB.71.094110 Ravel, 2005, Athena, artemis, hephaestus: data analysis for x-ray absorption spectroscopy using IFEFFIT, J. Synchrotron Radiat., 12, 537, 10.1107/S0909049505012719 Liu, 2020, Dual redox mediators accelerate the electrochemical kinetics of lithium-sulfur batteries, Nat. Commun., 11, 5215, 10.1038/s41467-020-19070-8 Li, 2021, Amorphization-induced surface electronic states modulation of cobaltous oxide nanosheets for lithium-sulfur batteries, Nat. Commun., 12, 3102, 10.1038/s41467-021-23349-9 Tian, 2021, Basal-plane-activated molybdenum sulfide nanosheets with suitable orbital orientation as efficient electrocatalysts for lithium-sulfur batteries, ACS Nano, 15, 16515, 10.1021/acsnano.1c06067 Yao, 2021, ZnS-SnS@NC heterostructure as robust lithiophilicity and sulfiphilicity mediator toward high-rate and long-life lithium-sulfur batteries, ACS Nano, 15, 7114, 10.1021/acsnano.1c00270 Ye, 2019, Stepwise electrocatalysis as a strategy against polysulfide shuttling in Li-S batteries, ACS Nano, 13, 14208, 10.1021/acsnano.9b07121 Jiang, 2021, Li2S-based Li-ion sulfur batteries: progress and prospects, Small, 17, 10.1002/smll.201903934 Yao, 2020, A dual-functional conductive framework embedded with TiN-VN heterostructures for highly efficient polysulfide and lithium regulation toward stable Li-S full batteries, Adv. Mater., 32, 10.1002/adma.201905658 Hossain, 2019, Rational design of graphene-supported single atom catalysts for hydrogen evolution reaction, Adv. Energy Mater., 9, 10.1002/aenm.201803689