Tunable Colors in Opals and Inverse Opal Photonic Crystals

Advanced Functional Materials - Tập 20 Số 16 - Trang 2565-2578 - 2010
Carlos I. Aguirre1, E. Reguera1, Andreas Stein2
1CICATA-Legaria IPN
2Department of Chemistry, University of Minnesota, 207 Pleasant St., SE, Minneapolis, MN 55455, USA

Tóm tắt

AbstractColloidal photonic crystals and materials derived from colloidal crystals can exhibit distinct structural colors that result from incomplete photonic band gaps. Through rational materials design, the colors of such photonic crystals can be tuned reversibly by external physical and chemical stimuli. Such stimuli include solvent and dye infiltration, applied electric or magnetic fields, mechanical deformation, light irradiation, temperature changes, changes in pH, and specific molecular interactions. Reversible color changes result from alterations in lattice spacings, filling fractions, and refractive index of system components. This review article highlights the different systems and mechanisms for achieving tunable color based on opaline materials with close‐packed or non‐close‐packed structural elements and inverse opal photonic crystals. Inorganic and polymeric systems, such as hydrogels, metallopolymers, and elastomers are discussed.

Từ khóa


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Advanced Functional Materials

Tập 20 Số 16

2565-2578

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