Treatment of wastewater generated during the fast pyrolysis of wood waste
Tóm tắt
One of the effective methods of processing lignocellulosic biomass is pyrolysis, which allows processing it into the liquid product, regardless of the composition of the feedstock. The liquid product obtained as a result of fast pyrolysis (bio-oil) is gaining popularity worldwide as replacing fossil fuels. In the process of processing pyrolysis condensates for fuel and chemical products, wastewater (wood vinegar) is formed, containing organic acids, furans, and phenols. In a large-scale forest chemical production, this waste is formed in large quantities, and its storage or incineration is extremely expensive. Discharge into centralized sewer systems of this drain is impossible due to its high toxicity and mutagenic effect. In this regard, the purpose of this study is to use a set of methods for cleaning WW for further discharge into centralized sewer systems. On the basis of the analysis carried out, a set of methods was proposed as the main methods for the purification of wood pyrolysis by means of sequential purification stages in the form of adsorption with biochar, oxidation with ozone and hydrogen peroxide, and ultrafiltration of the effluent. A high efficiency of 94% in the course of preliminary tests was achieved by the oxidation method under the conditions of the Fenton reaction due to its greater compliance with the conditions relative to other methods, the acidic environment, and the presence of oxidizing substances in the treated wastewater.
Tài liệu tham khảo
Okolie JA, Nanda S, Dalai AK et al (2021) Chemistry and specialty industrial applications of lignocellulosic biomass. Waste Biomass Valorisation. https://doi.org/10.1007/s12649-020-01123-0
Olatunji O, Akinlabi S, Madushele N (2020) Application of lignocellulosic biomass (LCB). Valorization Biomass Value-Added Commodities. https://doi.org/10.1007/978-3-030-38032-8_1
Gupta GK, Shukla P (2020) Lignocellulosic biomass for the synthesis of nanocellulose and its eco-friendly advanced applications. Front Chem. https://doi.org/10.3389/fchem.2020.601256
Arindam K, Vinay S (2017) Lignocellulosic biomass production and industrial applications. Wiley. p 304
Parakh PD, Nanda S, Kozinski JA (2020) Eco-friendly transformation of waste biomass to biofuels. Curr Biochem Eng. https://doi.org/10.2174/2212711906999200425235946
Nanda S, Azargohar R, Dalai AK, Kozinski JA (2015) An assessment on the sustainability of lignocellulosic biomass for biorefining. Renew Sust Energ Rev. https://doi.org/10.1016/j.rser.2015.05.058
Soo-Young No (2014) Application of bio-oils from lignocellulosic biomass to transportation, heat and power generation—A review. Renewable and Sustainable Energy Reviews. https://doi.org/10.1016/j.rser.2014.07.127
Terrya LM, Lia C, Jing JC et al (2021) Bio-oil production from pyrolysis of oil palm biomass and the upgrading technologies: a review. Carbon Resour Convers. https://doi.org/10.1016/j.crcon.2021.10.002
Zhang S, Yang X, Zhang H et al (2019) Liquefaction of biomass and upgrading of bio-oil: a review. Molecules. https://doi.org/10.3390/molecules24122250/
Narayan LP, Sanjay PA (2021) An overview of recent development in bio-oil upgrading and separation techniques. Environ Eng Res. https://doi.org/10.4491/eer.2020.382
Wang S, Gu Y, Liu Q et al (2009) Separation of bio-oil by molecular distillation. Fuel Process Technol. https://doi.org/10.1016/j.fuproc.2009.02.005
Wu Q, Zhang S, Hou B, Zheng H, Deng W, Liu D et al (2015) Study on the preparation of wood vinegar from biomass residues by carbonization process. Bioresour Technol. https://doi.org/10.1016/j.biortech.2014.12.026
Ahmad M, Rajapaksha AU, Lim JE et al (2014) Biochar as a sorbent for contaminant management in soil and water: a review. Chemosphere. https://doi.org/10.1016/j.chemosphere.2013.10.071
Luo X, Wang Z, Meki K et al (2019) Effect of co-application of wood vinegar and biochar on seed germination and seedling growth. J Soils Sediments. https://doi.org/10.1007/s11368-019-02365-9
Rasrendra CB, Girisuta B et al (2011) Recovery of acetic acid from an aqueous pyrolysis oil phase by reactive extraction using tri-n-octylamine. Chem Eng J. https://doi.org/10.1016/j.cej.2011.08.082
Ilyas M, Ahmad W et al (2019) Environmental and health impacts of industrial wastewater effluents in Pakistan: a review. Rev Environ Health. https://doi.org/10.1515/reveh-2018-0078
Palma LDI, Bavasso I et al (2019) Biological treatment of WW from pyrolysis plant: effect of organics concentration, pH and temperature. Water. https://doi.org/10.3390/w11020336
Fazullin DD, Mavrin GV, Savelyeva AV et al (2017) Sewage treatment from heavy metal ions by the method of deposition, using sulfur-alkaline WW as a reagent. Int J Green Pharm 11(4):831-S835
Mehrjouei M, Müller S, Möller D (2013) Treatment of pyrolysis WW using heterogeneous advanced oxidation processes. Environ Prog Sustain Energy. https://doi.org/10.1002/ep.11778
Silva JS, Dara SS et al (2017) Electrochemical and/or microbiological treatment of pyrolysis wastewater. Chemosphere. https://doi.org/10.1016/j.chemosphere.2017.06.133
Zhelovitskaya AV, Dresvyannikov AF, Chudakova OG (2015) Application of promising oxidative processes for WW treatment, pharmaceuticals (review). Bullet Kazan Technol Univ 20:73–79 (in Russian)
Zainullin AM, Zainullina LF, Shafigullina GM et al (2017) Influence of pH of the medium on the efficiency of WW treatment in the production of lead trinitroresorcinate under the conditions of the Fenton reaction. Technol Univ in 20(13):123–127 (in Russian)
Fedotova AV, Shaikhiev IG, Dryakhlov VO et al (2017) Intensification of separation of oil-in-water emulsions using polysulfonamide membranes modified with low-pressure radiofrequency plasma. Pet Chem. https://doi.org/10.1134/S0965544117020025
Fazullin DD, Mavrin GV, Fedotov AV et al (2016) Treatment of waste water containing waste oil. Int J Pharm Technol 8(2):14366–14374
Fedotova AV, Dryakhlov VO, Shaikhiev IG et al (2018) Effect of radiofrequency plasma treatment on the characteristics of polysulfonamide membranes and the intensity of separation of oil-in-water emulsions. Surf Eng Appl Electrochem. https://doi.org/10.3103/S1068375518020059
Caprariis B, Filippis P et al (2017) Pyrolysis wastewater treatment by adsorption on biochars produced by poplar biomass. J Environ Manage. https://doi.org/10.1016/j.jenvman.2017.04.007
Othaman R, Susilo A et al (2009) Treatment of wastewater containing wood waste pyroligneous acid preservative by activated carbon in rubberwood manufacturing process. Am J Chem Eng. https://doi.org/10.22146/ajche.50100
Zabelkin SA, Grachev AN et al (2018) Resole-type phenol–formaldehyde resin with neutralized liquid products of fast pyrolysis of birch wood. Polym Sci Ser D. https://doi.org/10.1134/S1995421218020223
Grachev AN, Zabelkin SA, Burenkov SV et al (2019) Pyrolysis of fresh and deposited sewage sludge and investigation of the products. Waste Biomass Valorization. https://doi.org/10.1007/s12649-017-0096-6
Zabelkin SA, Valeeva AR et al (2022) Neutrals influence on the water resistance coefficient of phenol-formaldehyde resin modified by wood pyrolysis liquid products. Biomass Convers Biorefinery. https://doi.org/10.1007/s13399-020-01025-0
Zhevitskaya AV, Ermolaeva EA, Dresventikov AA (2008) Oxidation of organic compounds using hydroxide radical generated in solutions by chemical and electrochemical methods. Bullet Kazan Technol Univ 6(21)211–229 (in Russian)