Ti3C2Tx MXene Conductive Layers Supported Bio‐Derived Fex−1Sex/MXene/Carbonaceous Nanoribbons for High‐Performance Half/Full Sodium‐Ion and Potassium‐Ion Batteries

Advanced Materials - Tập 33 Số 34 - 2021
Junming Cao1, Lili Wang2, Dongdong Li1, Zeyu Yuan1, Hao Xu1, Junzhi Li3, Ruoyu Chen1, V. M. Shulga1, Guozhen Shen2, Wei Han1
1Sino-Russian International Joint Laboratory for Clean Energy and Energy Conversion Technology, College of Physics, International Center of Future Science, Jilin university, Changchun, 130012, P.R. China
2State Key Laboratory for Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, Beijing, 100083, P.R. China
3Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, P.R. China

Tóm tắt

AbstractOwing to their cost‐effectiveness and high energy density, sodium‐ion batteries (SIBs) and potassium‐ion batteries (PIBs) are becoming the leading candidates for the next‐generation energy‐storage devices replacing lithium‐ion batteries. In this work, a novel Fex−1Sex heterostructure is prepared on fungus‐derived carbon matrix encapsulated by 2D Ti3C2Tx MXene highly conductive layers, which exhibits high specific sodium ion (Na+) and potassium ion (K+) storage capacities of 610.9 and 449.3 mAh g−1 at a current density of 0.1 A g−1, respectively, and excellent capacity retention at high charge–discharge rates. MXene acts as conductive layers to prevent the restacking and aggregation of Fex−1Sex sheets on fungus‐derived carbonaceous nanoribbons, while the natural fungus functions as natural nitrogen/carbon source to provide bionic nanofiber network structural skeleton, providing additional accessible pathways for the high‐rate ion transport and satisfying surface‐driven contribution ratios at high sweep rates for both Na/K ions storages. In addition, in situ synchrotron diffraction and ex situ X‐ray photoelectron spectroscopy measurements are performed to reveal the mechanisms of storage and de‐/alloying conversion process of Na+ in the Fex−1Sex/MXene/carbonaceous nanoribbon heterostructure. As a result, the assembled Na/K full cells containing MXene‐supported Fex−1Sex@carbonaceous anodes possess stable large‐ion storage capabilities.

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Advanced Materials

Tập 33 Số 34

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