Thermophysical Properties and Phase Behavior of Fluids for Application in Carbon Capture and Storage Processes

Annual Review of Chemical and Biomolecular Engineering - Tập 8 Số 1 - Trang 381-402 - 2017
J. P. Martin Trusler1
1Department of Chemical Engineering, Imperial College London, London, SW7 2AZ, United Kingdom

Tóm tắt

Phase behavior and thermophysical properties of mixtures of carbon dioxide with various other substances are very important for the design and operation of carbon capture and storage (CCS) processes. The available empirical data are reviewed, together with some models for the calculation of these properties. The systems considered in detail are, first, mixtures of carbon dioxide, water, and salts; second, carbon dioxide–rich nonelectrolyte mixtures; and third, mixtures of carbon dioxide with water and amines. The empirical data and the plethora of available models permit the estimation of key fluid properties required in the design and operation of CCS processes. The engineering community would benefit from the further development, and delivery in convenient form, of a small number of these models sufficient to encompass the component slate and operating conditions of CCS processes.

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