Thermodynamic model of the effect of nanoadhesion for polymeric nanocomposites

Polymer Science, Series D - Tập 1 - Trang 223-225 - 2008
G. V. Kozlov1, Z. Kh. Afashagova1, G. E. Zaikov2
1Kabardino-Balkarian State University, Nal’chik, Kabardino-Balkarian Republic, Russia
2Emanuel Institute of Biochemical Chemistry, Moscow, Russia

Tóm tắt

A thermodynamic model of the effect of nanoadhesion in filled polymeric nanocomposites is discussed. The model demonstrates good agreement with experimental data. It is shown that the effect of nanoadhesion has a dimensional origin, i.e., it is a true nanoeffect, which is greatly influenced by the aggregation of filler nanoparticles.

Tài liệu tham khảo

G. V. Kozlov, Yu. G. Yanovskii, and A. I. Burya, Mekh. Kompoz. Mater. Konstr. 13, 479 (2007). A. I. Burya, Z. Kh. Afashagova, G. V. Kozlov, and Yu. S. Lipatov, in Proceedings of IX Russia-China Symposium “New Materials and Technologies” (Interkontakt Nauka, Moscow, 2007), Vol. 1, p. 252. L. Holliday and J. Robinson, in Industrial Polymer Composite Materials, Ed. by M. Richardson (Khimiya, Moscow, 1980) [in Russian], p. 241. K. Tanaka and T. Nagamura, in Proceedings of Internatonal Conference on Polymer and Advanced Materials “POLYMEX-2006”, Huatulco, Mexico, 2006, Session 1, p. 51. T. S. Yakubov, Dokl. Akad. Nauk SSSR 303, 425 (1988). A. N. Bobryshev, V. N. Kozomazov, L. O. Babin, and V. I. Solomatov, Synergetics of Composite Materials (NPO ORIUS, Lipetsk, 1994). A. Kh. Malamatov, G. V. Kozlov, and M. A. Mikitaev, Mechanisms of Strenthening of Polymer Nanocomposites (Ross. Khim.-Tekhnol. Univ., Moscow, 2006) [in Russian]. R. A. Andrievskii, Ross. Khim. Zh. 46(5), 50 (2002).