Thermal decomposition of potassium carbonatooxoperoxovanadate(V)
Tóm tắt
The thermal decomposition of K3[V(CO3)O(O2)2] was studied under isothermal, dynamic and quasi-isobaric-isothermal condition. A mixture of K4V2O7 and K2CO3 was identified as the primary product of thermal decomposition. Under experimental conditions not allowing a continuous loss of volatile products, the reaction of K4V2O7 with CO2 gives KVO3 and K2CO3.
Tài liệu tham khảo
citation_journal_title=J. Fluorine Chem.; citation_author=J. K. Ghosh, G. V. Jere; citation_volume=35; citation_publication_date=1987; citation_pages=669; citation_id=CR1
citation_journal_title=J. Fluorine Chem.; citation_author=M. C. Chakravorti, A. R. Sarkar; citation_volume=8; citation_publication_date=1976; citation_pages=255; citation_id=CR2
citation_journal_title=Z. Anorg. Allg. Chem.; citation_author=G. Pausewang, R. Schmidt; citation_volume=523; citation_publication_date=1985; citation_pages=213; citation_id=CR3
citation_journal_title=Acta F. R. N. Univ. Comen., Chimia; citation_author=D. Joniaková, P. Schwendt; citation_volume=32; citation_publication_date=1984; citation_pages=93; citation_id=CR4
citation_journal_title=Acta F. R. N. Univ. Comen., Chimia; citation_author=D. Joniaková, P. Schwendt; citation_volume=30; citation_publication_date=1982; citation_pages=1; citation_id=CR5
P. Schwendt and D. Joniaková, Proc. 8th Conf. Coord. Chem., Smolenice, SCCR, 1980, p. 369.
citation_journal_title=Thermochim. Acta; citation_author=P. Schwendt, D. Joniaková; citation_volume=68; citation_publication_date=1983; citation_pages=297; citation_id=CR7
citation_journal_title=Thermochim. Acta; citation_author=D. Joniaková, P. Schwendt; citation_volume=92; citation_publication_date=1985; citation_pages=701; citation_id=CR8
citation_journal_title=Acta F. R. N. Univ. Comen., Chimia; citation_author=D. Joniaková, P. Schwendt; citation_volume=34; citation_publication_date=1986; citation_pages=97; citation_id=CR9
citation_journal_title=Chem. Zvesti; citation_author=P. Schwendt, D. Úskert; citation_volume=35; citation_publication_date=1981; citation_pages=229; citation_id=CR10
citation_journal_title=Z. Anorg. Allg. Chem.; citation_author=P. Schwendt, D. Úskert, P. Petrovic; citation_volume=466; citation_publication_date=1980; citation_pages=232; citation_id=CR11
citation_title=Spravotchnik po rentgenostrukturnomu analizu polikristallov; citation_publication_date=1961; citation_id=CR12; citation_author=L. I. Mirkin; citation_publisher=Nauka