The structure-directing effect of n-propylamine in the crystallization of open-framework aluminophosphates

Science in China Series B: Chemistry - Tập 57 - Trang 127-134 - 2013
HuiYing Lu1, Yan Yan1, XiaoQiang Tong1, WenFu Yan1, JiHong Yu1, RuRen Xu1
1State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, China

Tóm tắt

Using n-propylamine as a template, deioned water and secondary-butanol (butan-2-ol) as solvents, a three-dimensional (3D) open-framework aluminophosphate [C3NH10]·[HAl3P3O13] (1) and a two-dimensional layered aluminophosphate [C3NH10]3·[Al3P4O16] (2) were crystallized from the initial mixtures with compositions of Al2O3: 2.4 P2O5: 5.0 n-propylamine: 100 H2O/butan-2-ol, respectively. They are characterized by X-ray powder diffraction (XRD), thermogravimetric (TG), and elemental (CHN) analyses and structurally determined by single-crystal X-ray diffraction analysis. Compound 1 crystallizes in the monoclinic space group P21/c with a = 0.85831(13) nm, b = 1.7677(3) nm, c = 1.04353(12) nm, β = 123.887(9)°, and V = 1.3143(3) nm3. Compound 2 crystallizes in the monoclinic space group P21/c with a = 1.1313(2) nm, b = 1.4874(3) nm, c = 1.8020(6) nm, β = 125.07(2)°, and V = 2.4817(11) nm3. The results show that the properties of solvent have a significant influence on the structure-directing effect of n-propylamine in the crystallization of the open-framework aluminophosphates.

Tài liệu tham khảo

Xu RR, Pang WQ, Yu JH, Huo QS, Chen JS. Chemistry of zeolites and related porous materials: Synthesis and structure. Singapore: John Wiley & Sons (Asia) Pte Ltd, 2007 Wright PA. Microporous Framework Solids. Cambridge: The Royal Society of Chemistry, 2008 Vermeiren W, Gilson JP. Impact of zeolites on the petroleum and petrochemical industry. Top Catal, 2009, 52: 1131–1161 Murugavel R, Choudhury A, Walawalkar MG, Pothiraja R, Rao CNR. Metal complexes of organophosphate esters and open-framework metal phosphates: Synthesis, structure, transformations, and application. Chem Rev, 2008, 108: 3549–3655 Wilson ST, Lok BM, Messina CA, Cannan TR, Flanigen EM. Aluminophosphate molecular sieves: A new class of microporous crystalline inorganic solids. J Am Chem Soc, 1982, 104: 1146–1147 Wilson ST, Lok BM, Flanigen EM. Crystalline metallophosphate compositions. US Patent 4310440, 1982 Yu JH, Xu RR. Rich structure chemistry in the aluminophosphate family. Acc Chem Res, 2003, 36: 481–490 Yu JH, Xu RR. Insight into the construction of open-framework aluminophosphates. Chem Soc Rev, 2006, 35: 593–604 Morgan K, Gainsford G, Milestone N. A novel layered aluminium phosphate [Co(en)3Al3P4O16·3H2O] assembled about a chiral metal complex. J Chem Soc, Chem Commun, 1 1995, 425–426 Yan WF, Yu JH, Xu RR, Zhu GS, Xiao FS, Han Y, Kazumasa S, Osamu T. [Al12P13O52]3·[(CH2)6N4H3]3+: An anionic aluminophosphate molecular sieve with bronsted acidity. Chem Mater, 2000, 12: 2517–2519 Tuel A, Gramlich V, Baerlocher C. Synthesis, crystal structure and characterization of AP2DAO, a new layered aluminophosphate templated by 1, 8-diaminooctane molecules. Micropor Mesopor Mater, 2001, 47: 217–229 Yu J, Sugiyama K, Hiraga K, Togashi N, Terasaki O, Tanaka Y, Nakata S, Qiu S, Xu R. Synthesis and characterization of new two-dimensional aluminophosphate layer and structural diversity in anionic aluminophosphates with Al2P3O12 3∮ stoichiometry. Chem Mater. 1998, 10: 3636–3642 Oliver S, Kuperman A, Lough A, Ozin GA. Aluminophosphate chain-to-layer transformation. Chem Mater, 1996, 8: 2391–2398 Yan WF, Yu JH, Shi Z, Miao P, Wang KX, Wang Y, Xu RR. An anionic framework aluminophosphate (CH2)6N4H3·H2O[Al11P12O48] and computer simulation of the template positions. Micropor Mesopor Mater, 2001, 50: 151–158 Huo QS, Xu RR, Li SG, Ma ZG, Thomas JM, Jones RH, Chippindale AM. Synthesis and characterization of a novel extra large ring of aluminophosphate JDF-20. J Chem Soc, Chem Commun, 1992, 875–876 Yu J, Sugiyama K, Zheng S, Qiu S, Chen J, Xu R, Sakamota Y, Terasaki O, Hiraga K, Light M, Hursthouse MB, Thomas JM. Al16P20O80H4·4C6H18N2: A new microporous aluminophosphate containing intersecting 12-and 8-membered ring channels. Chem Mater, 1998, 10: 1208–1211 Kongshaug KO, Fjellvåg H, Lillerud KP. Layered aluminophosphates I. Crystal structure of two novel layered aluminophosphates solved ab initio from powder diffraction data. Micropor Mesopor Mater, 1999, 32: 17–28 Xing HZ, Li JY, Yan WF, Chen P, Jin Z, Yu JH, Dai S, Xu RR. Cotemplating ionothermal synthesis of a new open-framework aluminophosphate with unique Al/P ratio of 6/7. Chem Mater, 2008, 20: 4179–4181 Yan WF, Yu JH, Shi Z, Xu RR. A novel open-framework aluminophosphate [AlP2O6(OH)2][H3O] containingpropeller-like chiral motifs. Chem Commun, 2000, 1431–1432 SAINT: Bruker AXS Inc. 5465 East Cheryl Parkway, Madison, WI 53711-5373, USA. 2000 SHELXTL: Bruker AXS Inc. 5465 East Cheryl Parkway, Madison, WI 53711-5373, USA. 2000 Bennett JM, Cohen JM, Artioli G, Pluth JJ, Smith JV. Crystal structure of AlPO4-21, a feamework aluminophosphate containing tetrahedral phosphorus and both tetrahedral and trigonal-bipyramidal aluminum in 3-, 4-, 5-, and 8-rings. Inorg Chem, 1985, 24: 188–193 Li JY, Yu JH, Wang KX, Zhu GS, Xu RR. A simulation study on the topotactic transformations from aluminophosphate AlPO4-21 to AlPO4-25. Inorg Chem, 2001, 40: 5812–5817 Lu HY, Tong XQ, Yan Y, Yan, WF, Yu JH, Xu RR. Synthesis, structure and phase transition of a new microporous aluminophosphate [C4N2H14]2+[H2Al3P3O14]2−. Chem J Chin Univ, 2013, 34: 1571–1575 Parise JB. The structure of trialuminium tris(orthophophate) hydrate, AlPO4-21, with clathrated ethylenediamine, Al3(PO4)3·C2H8N2·H2O, and pyrrolidine, Al3(PO4)3·C4H9N·H2O. Acta Cryst, 1985, C41: 515–520 Song Y, Li JY, Yu JH, Wang KX, Xu RR. Towards rational synthesis of microporous aluminophosphate AlPO4-21 by hydrothermal combinatorial approach. Top Catal, 2005, 35: 3–8 Togashi N, Yu J, Zheng S, Sugiyama K, Hiraga K, Terasaki O, Yan W, Qiu S, Xu R. Synthesis and structure of a 2-D aluminophosphate Al3P4O16·3CH3CH2CH2NH3. J Mater Chem, 1998, 8: 2827–2830 Yan WF, Song XW, Xu RR. Molecular engineering of microporous crystals: (I) New insight into the formation process of open-frame-work aluminophosphates. Micropor Mesopor Mater, 2009, 123: 50–62