The non-ohmic nature of intercalation materials and the consequences for charge transport limitations

Huggins, 2009, 474 Yoshio, 2009 Blomgren, 2017, The development and future of lithium ion batteries, J. Electrochem. Soc., 164, A5019, 10.1149/2.0251701jes Padhi, 1997, Phospho‐olivines as positive‐electrode materials for rechargeable lithium batteries, J. Electrochem. Soc., 144, 1188, 10.1149/1.1837571 Zhang, 2015, Direct observation of li-ion transport in electrodes under nonequilibrium conditions using neutron depth profiling, Adv. Energy Mater., 5, 1500498, 10.1002/aenm.201500498 Borong, 2011 Tarascon, 2012, Issues and challenges facing rechargeable lithium batteries, 171 Johns, 2009, How the electrolyte limits fast discharge in nanostructured batteries and supercapacitors, Electrochem. Commun., 11, 2089, 10.1016/j.elecom.2009.09.001 Yu, 2006, Effect of electrode parameters on LiFePO4 cathodes, J. Electrochem. Soc., 153, A835, 10.1149/1.2179199 Liu, 2016, Relating the 3D electrode morphology to Li-ion battery performance; a case for LiFePO4, J. Power Sources, 324, 358, 10.1016/j.jpowsour.2016.05.097 Orvananos, 2014, Architecture dependence on the dynamics of nano-LiFePO4 electrodes, Electrochim. Acta, 137, 245, 10.1016/j.electacta.2014.06.029 Zhang, 2014, Rate-induced solubility and suppression of the first-order phase transition in Olivine LiFePO4, Nano Lett., 14, 2279, 10.1021/nl404285y Yu, 2015, Dependence on crystal size of the nanoscale chemical phase distribution and fracture in LixFePO4, Nano Lett., 15, 4282, 10.1021/acs.nanolett.5b01314 Shahid, 2013, Particle size dependent confinement and lattice strain effects in LiFePO4, Phys. Chem. Chem. Phys., 15, 18809, 10.1039/c3cp52953c Orvananos, 2015, Effect of a size-dependent equilibrium potential on nano-LiFePO4 particle interactions, J. Electrochem. Soc., 162, A1718, 10.1149/2.0161509jes Strobridge, 2015, Mapping the inhomogeneous electrochemical reaction through porous LiFePO4-electrodes in a standard coin cell battery, Chem. Mater., 27, 2374, 10.1021/cm504317a Srinivasan, 2006, Existence of path-dependence in the LiFePO4 electrode, Electrochem. Solid State Lett., 9, A110, 10.1149/1.2159299 Singh, 2013, Facile micro templating LiFePO4 electrodes for high performance Li-ion batteries, Adv. Energy Mater., 3, 572, 10.1002/aenm.201200704 Fongy, 2010, Electronic and ionic wirings versus the insertion reaction contributions to the polarization in LiFePO4 composite electrodes, J. Electrochem. Soc., 157, A1347, 10.1149/1.3497353 Fongy, 2010, Ionic vs electronic power limitations and analysis of the fraction of wired grains in LiFePO4 composite electrodes, J. Electrochem. Soc., 157, A885, 10.1149/1.3432559 Li, 2014, Current-induced transition from particle-by-particle to concurrent intercalation in phase-separating battery electrodes, Nat. Mater., 13, 1149, 10.1038/nmat4084 Farkhondeh, 2017, Mesoscopic modeling of a LiFePO4 electrode: experimental validation under continuous and intermittent operating conditions, J. Electrochem. Soc., 164, E3040, 10.1149/2.0211706jes Huang, 2015, An analytical three-scale impedance model for porous electrode with agglomerates in lithium-ion batteries, J. Electrochem. Soc., 162, A585, 10.1149/2.0241504jes Huang, 2016, Theory of impedance response of porous electrodes: simplifications, inhomogeneities, non-stationarities and applications, J. Electrochem. Soc., 163, A1983, 10.1149/2.0901609jes Bergveld, 2002, Battery management systems, 1 Philipsen, 2015, A charging place to be - users' evaluation criteria for the positioning of fast-charging infrastructure for electro mobility, Procedia Manuf., 3, 2792, 10.1016/j.promfg.2015.07.742 D. Aggeler, et al. Ultra-fast DC-charge infrastructures for EV-mobility and future smart grids, in: Proceedings of the 2010 IEEE PES Innovative Smart Grid Technologies Conference Europe (ISGT Europe)., 2010. Doyle, 1997, Analysis of capacity–rate data for lithium batteries using simplified models of the discharge process, J. Appl. Electrochem., 27, 846, 10.1023/A:1018481030499 Srinivasan, 2004, Discharge model for the lithium iron-phosphate electrode, J. Electrochem. Soc., 151, A1517, 10.1149/1.1785012 Thomas, 2002 Botte, 2000, Mathematical modeling of secondary lithium batteries, Electrochim. Acta, 45, 2595, 10.1016/S0013-4686(00)00340-6 Gomadam, 2002, Mathematical modeling of lithium-ion and nickel battery systems, J. Power Sources, 110, 267, 10.1016/S0378-7753(02)00190-8 Prada, 2012, Simplified electrochemical and thermal model of LiFePO4-Graphite Li-ion batteries for fast charge applications, J. Electrochem. Soc., 159, A1508, 10.1149/2.064209jes Ferguson, 2012, Nonequilibrium thermodynamics of porous electrodes, J. Electrochem. Soc., 159, A1967, 10.1149/2.048212jes Cogswell, 2012, Coherency strain and the kinetics of phase separation in LiFePO4 nanoparticles, ACS Nano, 6, 2215, 10.1021/nn204177u Cahn, 1958, Free energy of a nonuniform system. I. Interfacial free energy, J. Chem. Phys., 28, 258, 10.1063/1.1744102 Farkhondeh, 2014, Mesoscopic modeling of Li insertion in phase-separating electrode materials: application to lithium iron phosphate, Phys. Chem. Chem. Phys., 16, 22555, 10.1039/C4CP03530E Park, 2010, A review of conduction phenomena in Li-ion batteries, J. Power Sources, 195, 7904, 10.1016/j.jpowsour.2010.06.060 Wang, 2007, Ionic/electronic conducting characteristics of LiFePO4 cathode materials: the determining factors for high rate performance, Electrochem. Solid-State Lett., 10, A65, 10.1149/1.2409768 Reddy, 2001, 27.23 Wagemaker, 2011, Dynamic solubility limits in nanosized Olivine LiFePO4, J. Am. Chem. Soc., 133, 10222, 10.1021/ja2026213 Wagemaker, 2013, Properties and promises of nanosized insertion materials for Li-ion batteries, Acc. Chem. Res., 46, 1206, 10.1021/ar2001793 Bagotsky, 2005, 722 A. Bard, L. Faulkner, Electrochemical Methods. Fundamentals and applications. 2nd ed., John Wiley&Sons, New York. 864. Neamen, 2003, 784 Zeghbroeck, 2011 Boylestad, 2013 Kasap, 2005, 768 Dickinson, 2011, The electroneutrality approximation in electrochemistry, J Solid State Electrochem., 15 Danilov, 2008, Mathematical modelling of ionic transport in the electrolyte of Li-ion batteries, Electrochim. Acta, 53, 5569, 10.1016/j.electacta.2008.02.086 Ledovskikh, 2016, Lattice-gas model for energy storage materials: phase diagram and equilibrium potential as a function of nanoparticle size, J. Phys. Chem. C, 120, 11192, 10.1021/acs.jpcc.6b00914 Meethong, 2007, Size-dependent lithium miscibility gap in nanoscale Li1 − x FePO4, Electrochem. Solid-State Lett., 10, A134, 10.1149/1.2710960 Castellan, 1983 Kasap, 2005 Wu, 2012, Effects of current collectors on power performance of Li4Ti5O12 anode for Li-ion battery, J. Power Sources, 197, 301, 10.1016/j.jpowsour.2011.09.014 Wang, 2013, Effects of current collectors on electrochemical performance of FeS2 for Li-ion battery, Int. J. Electrochem. Sci., 8, 8, 10.1016/S1452-3981(23)14448-8 Li, 2018, Orientation-dependent lithium miscibility gap in LiFePO4, Chem. Mater., 30, 874, 10.1021/acs.chemmater.7b04463 ChiuHuang, 2014, In situ imaging of lithium-ion batteries via the secondary Ion Mass Spectrometry, J. Nanotechnol. Eng. Med., 5, 021002, 10.1115/1.4028010 Gallagher, 2016, Optimizing areal capacities through understanding the limitations of lithium-ion electrodes, J. Electrochem. Soc., 163, A138, 10.1149/2.0321602jes Bunde, 2005, Diffusion and conduction in percolation systems –theory and applications Deprez, 1988, The analysis of the electrical conductivity of graphite conductivity of graphite powders during compaction, J. Phys. D: Appl. Phys., 21, 101, 10.1088/0022-3727/21/1/015 Krishnan, 1939, Large anisotropy of the electrical conductivity of graphite, Nature, 144, 667, 10.1038/144667a0 Solvay, Solef® 5130 Polyvinylidene Fluoride, Solvay, Brussels 2014, p. 3.