The interaction of water vapors with H3PO4 imbibed electrolyte based on PBI/polysulfone copolymer blends

Journal of Membrane Science - Tập 326 Số 1 - Trang 76-83 - 2009
Maria K. Daletou1, Joannis K. Kallitsis1, George A. Voyiatzis2, Stylianos G. Neophytides2
1Department of Chemistry, University of Patras, 26500 Patras, Greece
2Institute of Chemical Engineering and High Temperature Chemical Processes, ICE/HT-FORTH, P.O. Box 1414, 26504 Patras, Greece

Tóm tắt

Từ khóa


Tài liệu tham khảo

Steele, 2001, Materials for fuel-cell technologies, Nature, 414, 345, 10.1038/35104620

Li, 2003, Approaches and recent development of polymer electrolyte membranes for fuel cells operating above 100°C, Chem. Mater., 15, 4896, 10.1021/cm0310519

Kreuer, 2004, Transport in proton conductors for fuel-cell applications: simulations, elementary reactions, and phenomenology, Chem. Rev., 104, 4637, 10.1021/cr020715f

Rikukawa, 2000, Proton conducting polymer electrolyte membranes based on hydrocarbon polymers, Prog. Polym. Sci., 25, 1463, 10.1016/S0079-6700(00)00032-0

Kerres, 2001, Development of ionomer membranes for fuel cells, J. Membr. Sci., 185, 3, 10.1016/S0376-7388(00)00631-1

Aharoni, 1974, Synthesis and some properties of poly-(2,5-trimethylene benzimidazole) and poly-(2,5-trimethylene benzimidazole hydrochloride), J. Polym. Sci. Part A: Polym. Chem., 12, 639, 10.1002/pol.1974.170120314

Wainright, 1995, Acid-doped polybenzimidazoles: a new polymer electrolyte, J. Electrochem. Soc., 142, L121, 10.1149/1.2044337

Samms, 1996, Thermal stability of proton conducting acid doped polybenzimidazole in simulated fuel cell environments, J. Electrochem. Soc., 143, 1225, 10.1149/1.1836621

Savinell, 1994, A polymer electrolyte for operation at temperatures up to 200°C, J. Electrochem. Soc., 141, L46, 10.1149/1.2054875

Bouchet, 1999, Proton conduction in acid doped polybenzimidazole, Solid State Ionics, 118, 287, 10.1016/S0167-2738(98)00466-4

Kawahara, 2000, Synthesis and proton conductivity of thermally stable polymer electrolyte: poly(benzimidazole) complexes with strong acid molecules, Electrochim. Acta, 45, 1395, 10.1016/S0013-4686(99)00349-7

Ma, 2004, Conductivity of PBI membranes for high-temperature polymer electrolyte fuel cells, J. Electrochem. Soc., 151, A8, 10.1149/1.1630037

Xiao, 2005, High-temperature polybenzimidazole fuel cell membranes via a sol–gel process, Chem. Mater., 17, 5328, 10.1021/cm050831+

Wang, 1996, A H2/O2 fuel cell using acid doped polybenzimidazole as polymer electrolyte, Electrochim. Acta, 41, 193, 10.1016/0013-4686(95)00313-4

Deimede, 2000, Miscibility behaviour of polybenzimidazole/sulfonated polysulfone blends for use in fuel cell applications, Macromolecules, 33, 7609, 10.1021/ma000165s

Hasiotis, 2001, Development and characterization of acid-doped polybenzimidazole/sulfonated polysulfone blend polymer electrolytes for fuel cells, J. Electrochem. Soc., 148, A513, 10.1149/1.1366621

Hasiotis, 2001, New polymer electrolytes based on blends of sulfonated polysulfones with polybenzimidazole, Electrochim. Acta, 46, 2401, 10.1016/S0013-4686(01)00437-6

Qingfeng, 2002, A quasi-direct methanol fuel cell system based on blend polymer membrane electrolytes, Electrochem. Solid-State Lett., 5, A125, 10.1149/1.1473335

Daletou, 2005, Proton conducting membranes based on blends of PBI with aromatic polyethers containing pyridine units, J. Membr. Sci., 252, 115, 10.1016/j.memsci.2004.11.023

He, 2003, Proton conductivity of phosphoric acid doped polybenzimidazole and its composites with inorganic proton conductors, J. Membr. Sci., 226, 169, 10.1016/j.memsci.2003.09.002

Papakonstantinou, 2007, The electrokinetics of CO oxidation on Pt4Mo (20wt.%)/C interfaced with Nafion membrane, J. Electrochem. Soc., 154, B989, 10.1149/1.2761319

Qingfeng, 2004, Water uptake and acid doping of polybenzimidazoles as electrolyte membranes for fuel cells, Solid State Ionics, 168, 177, 10.1016/j.ssi.2004.02.013

Schuster, 2003, Anhydrous proton-conducting polymers, Ann. Rev. Mater. Res., 33, 233, 10.1146/annurev.matsci.33.022702.155349

Klinedinst, 1974, Oxygen solubility and diffusivity in hot concentrated H3PO4, J. Electroanal. Chem. Interfacial Electrochem., 57, 281, 10.1016/S0022-0728(74)80053-7

Gubbins, 1989, The solubility and diffusivity of oxygen in electrolytic solutions, J. Electrochem. Soc., 112, 469, 10.1149/1.2423575

He, 2006, Physicochemical properties of phosphoric acid doped polybenzimidazole membranes for fuel cells, J. Membr. Sci., 277, 38, 10.1016/j.memsci.2005.10.005

Kumbharkar, 2006, Enhancement of gas permeation properties of polybenzimidazoles by systematic architecture, J. Membr. Sci., 286, 161, 10.1016/j.memsci.2006.09.030

Gan, 1993, Determination of diffusivity and solubility of oxygen in phosphoric acid using a transit time on a rotating rind-disk electrode, J. Appl. Electrochem., 23, 452, 10.1007/BF00707621

Liu, 2006, Study of the oxygen reduction reaction (ORR) at Pt interfaced with phosphoric acid doped polybenzimidazole at elevated temperature and low relative humidity, Electrochim. Acta, 51, 3914, 10.1016/j.electacta.2005.11.019

Gourdoupi, 2003, Novel proton-conducting polyelectrolyte composed of an aromatic polyether containing main-chain pyridine units for fuel cell applications, Chem. Mater., 15, 5044, 10.1021/cm0347382