The excimer radiation system: a powerful tool for preparative organic photochemistry. A technical note

Axel G. Griesbeck1, Nesmine Maptue1, Samir Bondock1, Michael Oelgemöller2
1Institute of Organic Chemistry, University of Cologne, Köln, Germany
2Bayer Cropscience K.K., Yuki-City, Ibaraki, Japan

Tóm tắt

The XeCl excimer 308 nm radiation system is described as a powerful tool for synthetic organic photochemistry involving carbonyl and carbonyl-type chromophores. Scaleable photochemical reactions which have been tested and optimized for this system were photodecarboxylation, [2 + 2]-photocycloaddition, and Type III (electron transfer) photooxygenation reactions.

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