The effect of unconfined mine tailings on the geochemistry of soils, sediments and surface waters of the lousal area (Iberian Pyrite Belt, Southern Portugal)

Land Degradation and Development - Tập 16 Số 2 - Trang 213-228 - 2005
Eduardo Ferreira da Silva1, E. Cardoso Fonseca1, João Xavier Matos2, Carla Patinha1, Amélia Reis3, Joana Oliveira4
1Departamento de Geociências, Universidade de Aveiro, P-3810-193 Aveiro, Portugal
2Instituto Geológico e Mineiro—INETInovação, Beja Portugal
32 CVRM/Centro de Geo-Sistemas, IST, Technical University of Lisbon, Portugal
4Instituto Geológico e Mineiro—INETInovação, Porto Portugal

Tóm tắt

AbstractThe former Lousal mine, on the SW limb of the Lousal anticline, closed in 1988. Today Lousal is a small village, with much evidence of environmental and landscape disturbance. This is largely the legacy of mining and mine tailings dumped around the site, which, in turn, caused soil contamination and acid mine drainage. Particular attention is being given by the Portuguese Government to this sort of problem, bearing in mind the State's responsibilities for the abandoned mine sites that occur in many parts of the Country.Despite the semiarid climatic conditions of the area, a visual inspection of the mine site indicates that the tailings are affected by considerable water erosion, particularly during large rainfall events.Significant amounts of Cu, Pb, Zn, As, Cd and Hg, occur within the soil collected near the tailing deposits (292–7013 mg kg−1 Cu, 871–12 930 mg kg−1 Pb, 126–7481 mg kg−1 Zn, 597–6377 mg kg−1 As, 0·2–16·4 mg kg−1 Cd and 1–130 mg kg−1 Hg) and in stream sediments downstream of the tailings site (1–1986 mg kg−1 Cu, 41‐5981 mg kg−1 Pb, 17–1756 mg kg−1 Zn, 6–1988 mg kg−1 As and 0·2–5·7 mg kg−1 Cd). All the soil samples collected in the tailings deposits exceed the permissible levels.Near the mine site, significant acid mine drainage is associated with the pyritic material and such waters show values of pH ranging from 1·9 to 2·9 and concentrations of 9249 to 20 700 mg L−1 SO, 959 to 4830 mg L−1 Fe and 136 to 624 mg L−1 A1. Meanwhile, the acid effluents and mixed stream waters also carry high contents of SO, Fe, Al, Cu, Pb, Zn, Cd, and As, generally exceeding the Fresh Water Aquatic Life Acute Criteria. Copyright © 2005 John Wiley & Sons, Ltd.

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Tài liệu tham khảo

ASTM, 1984, American Society for Testing Materials, Annual Book of ASTM Standards. Water Environmental Technology, 1403

10.1016/0269-7491(94)90139-2

10.1007/s002540100373

Cardoso Fonseca E, 1982, Emploi de l'extraction chimique sélective séquentielle et détermination des phases‐support du Pb et du Zn en milieux silico‐alumineux lors de l'altération supèrgene du prospect de Sanguinheiro (SE Aveiro—Portugal), Comunicações Serviços Geológicos Portugal, 68, 267

10.1016/S0375-6742(97)00051-4

10.1016/0016-7037(83)90213-2

10.1016/0883-2927(95)00061-5

Costello C, 2003, Acid Mine Drainage: Innovative Treatment Technologies, 52

10.1126/science.204.4390.304

10.1126/science.180.4081.71

10.1016/S0003-2670(00)00804-7

10.1007/s002540050133

10.1021/ac00137a010

10.1080/09593331908616683

Kleinmann RLP, 1981, Biogeochemistry of acid mine drainage and a method to control acid formation, Mining Engineering, 33, 300

KlokeA.1979.Contents of Arsenic Cadmium Chromium Fluorine Lead Mercury and Nickel in Plants Grown on Contaminated Soil. UN‐ECE Symposium Geneva 1979.

KwongYTJ.1991.Prediction and prevention of acid rock drainage from a geological and mineralogical perspective.Canadian National Hydrology Research Centre ContributionCS‐92054;47pp.

10.1023/A:1006571223295

10.1007/s001260050130

10.1016/0013-9327(78)90055-1

10.1142/p022

MatosJX OliveiraV.2002.Relatório Téanico Servicas Fomento Miniur Arquior.Geologia e património mineiro da Mina do Lousal Faixa Piritosa Ibérica. Livro‐Guia excursão Geologia no Verão Instituto Geológico e Mineiro. Lisboa.

MatosJX OliveiraV.2002.Mina do Lousal (Faixa Piritosa Ibérica)—Percurso geológico e mineiro pelas cortas e galerias da antiga mina.Actas III Congresso Internacional Patrimonio Geológico y Minero UPC/SEDPGYM/ITGE; Cartagena: Espanha;11pp.

Matos JX, 2003, Environmental Geochemistry Field Course—Iberian Pyrite Belt

MatzkeK.1971.Mina do Lousal. Principais Jazigos Minerais do Sul de Portugal.Livro‐Guia No 4:25–32.

MeguellatiN RobbeD MarchandiseP AstrucM.1983.A new chemical extraction procedure in the fractionation of heavy metals in sediments—interpretation. InProceedings of the International Conference Heavy Metals in the Environment.CEP Edinburgh:1090–1093.

10.1016/0883-2927(91)90074-Y

10.1016/0143-148X(82)90010-6

Nordstrom DK, 1982, Acid sulphate weathering. Proceedings of a Symposium sponsored by Divisions S‐9, S‐2, S‐5, and S‐6 of the Soil Science Society of America in Fort Colins, 37

OreyFA.1901.Rapport sur la Mine de Pyrite de Fer Cuivreuse de Louzal. Rel. Téc. SFM Arq. Editorer: Carvellro D Grinhas JAC and Schermerhoun LJG Direuaú‐Geval de Minas e Servjos Geógicos. Lisboa. Instituto Geológico e Mineiro. Ministério da Industria e Tecnologia Lisboa.

OSHA Regulated Hazardous Substances, 1990, Health, Toxicity, Economic and Technological Data, 1146

PlumleeGS SmithS FicklinWH.1994.Geoenvironmental Models of Minerals Deposits and Geology‐based‐ Mineral–environmental Assessments of Public Lands. US Geological Survey Open‐File Report;94–203.

10.1007/BF00323110

10.1039/ap9872400260

RapinF ForstnerU.1983.Sequential leaching techniques for particulate metal speciation: the selectivity of various extractants. InProceedings of the 4th International Conference on Heavy Metals in the Environment 2. Heidelberg. Germany;1074–1077.

10.1007/978-3-642-72016-1

ReisAP.1989.Projecto de desenvolvimento para o Lousal. Antiga mina vai ser transformada em museu.http://arquivo.setubalnarede.pt/1998/41/41Lousal.html. Seminário Digital Independente da Região de Setúbal Edição 41. Setubal [Accessed 11 September 2003].

10.1016/S0160-4120(03)00006-0

Santos Oliveira JM, 2002, Diagnóstico Ambiental das Principais Áreas Mineiras Degradadas do País, Boletim de Minas, 39, 67

SchermerhornL ZbyzewskiG FerreiraV.1987.Carta Geol. Portugal 1/50 000 42D Aljustrel. SGP‐Serviços Geológicos de Portugal.

SilvaJML.1996.À laia de um esboço histórico sobre a utilização industrial contemporânea das pirites do Alentejo. Mineração do Baixo Alentejo Ed. Câm. Municipal de C. Verde;230–252.

10.1016/S0169-7722(03)00150-5

Strauss G, 1970, Sobre la geologia de la provincia piritífera del SW de la Península Ibérica y de sus yacimientos, en especial sobre la mina de pirita de Lousal (Portugal), Memónies do Instituto Tecnologico e Geominero de España (ITGE), 77, 266

10.1021/ac50043a017

USEPA (US Environmental Protection Agency).2002.National Recommended Water Quality Criteria. EPA‐822‐R‐02‐047. United States Environmental Protection Agency. Office of Water and Office of Science and Technology:33pp.

10.1002/etc.5620150622