The bimetal synergistic bifunctional electrocatalysts for hydrogen evolution and oxygen evolution reactions

Ionics - Tập 27 - Trang 2139-2150 - 2021
Pengxin Che1, Yanhong Wang1, Xiaoshuang Zhang2, Xiaoqiang Du1
1School of Chemical Engineering and Technology, North University of China, Taiyuan, People’s Republic of China
2School of Science, North University of China, Taiyuan, People’s Republic of China

Tóm tắt

In the development of renewable energy systems, finding low-cost and high-performance electrocatalysts for hydrogen evolution reaction and oxygen evolution reaction under the synergistic action of bimetals is a challenge. This paper firstly describes the growth of Zn-Ni-M/NF (M = O/P/Se/S) nanostructured samples on nickel foam through thermal decomposition, phosphating, selenization, and sulfidation. A current density of 50 mA cm−2 is driven at an overpotential of 160 mV for oxygen evolution reaction, and a current density of 10 mA cm−2 is driven at an overpotential of 117 mV for hydrogen evolution reaction. In a two-electrode system, only a cell voltage of 1.49 V is required to drive a current density of 10 mA cm−2, which is almost one of the best catalysts reported so far. In addition, the work also provides a wide range of possibilities for the development of the earth’s abundant resources and that of cheap and efficient catalyst materials.

Tài liệu tham khảo

Wang Z, Liu H, Ge R, Ren X, Ren J, Yang D, Zhang L, Sun X (2018) Phosphorus-doped Co3O4 nanowire array: a highly efficient bifunctional electrocatalyst for overall water splitting. ACS Catal 8:2236–2241 Babar PT, Lokhande AC, Pawar BS, Gang MG, Jo E, Go C, Suryawanshi MP, Pawar SM, Kim JH (2018) Electrocatalytic performance evaluation of cobalt hydroxide and cobalt oxide thin films for oxygen evolution reaction. Appl Surf Sci 427:253–259 Babar P, Lokhande A, Karade V, Pawar B, Gang MG, Pawar S, Kim JH (2019) Bifunctional 2D electrocatalysts of transition metal hydroxide nanosheet arrays for water splitting and urea electrolysis. ACS Sustain Chem Eng 7:10035–10043 Bai L, Wen X, Guan J (2019) Amorphous FeCoNi oxide for oxygen evolution reaction. Mater Today Energy 12:311–317 Cai Z, Bu X, Wang P, Su W, Wei R, Ho JC, Yang J, Wang X (2019) Simple and cost effective fabrication of 3D porous core–shell Ni nanochains@NiFe layered double hydroxide nanosheet bifunctional electrocatalysts for overall water splitting. J Mater Chem A 7:21722–21729 Cao S, You N, Wei L, Huang C, Fan X, Shi K, Yang Z, Zhang W (2020) CoP Microscale prism-like superstructure arrays on Ni Foam as an efficient bifunctional electrocatalyst for overall water splitting. Inorg Chem 59:8522–8531 Chaturvedi P, Sarker S, Chen X, Das S, Luo H, Smirnov SN (2019) Enhancing the cooperative catalytic effect in Ni/Co Hydr(oxy)oxide porous electrodes for overall water splitting and glucose sensing. ACS Sustain Chem Eng 7:11303–11312 Che Q, Li Q, Chen X, Tan Y, Xu X (2020) Assembling amorphous (Fe-Ni)Cox-OH/Ni3S2 nanohybrids with S-vacancy and interfacial effects as an ultra-highly efficient electrocatalyst: inner investigation of mechanism for alkaline water-to-hydrogen/oxygen conversion. Appl Catal B Environ 263:118338 Chen W, Fang J, Zhang Y, Chen G, Zhao S, Huang R, Zhou Y (2018) Morphological and structure dual modulation of cobalt-based layer double hydroxides by Ni doping and 2-methylimidazole inducting as bifunctional electrocatalysts for overall water splitting. J Power Sources 400:172–182 Ma M, Ge R, Ji X, Ren X, Liu Z, Asiri AM, Sun X (2017) Benzoate anions-intercalated layered nickel hydroxide nanobelts array: an earth-abundant electrocatalyst with greatly enhanced oxygen evolution activity. ACS Sustain Chem Eng 5:9625–9629 Chen Y, Sun P, Xing W (2019) Cobalt nitride nanoflakes supported on Ni foam as a high-performance bifunctional catalyst for hydrogen production via urea electrolysis. J Chem Sci 131:101 Cheng F, Wang L, Wang H, Lei C, Yang B, Li Z, Zhang Q, Lei L, Wang S, Hou Y (2020) Boosting alkaline hydrogen evolution and Zn–H2O cell induced by interfacial electron transfer. Nano Energy 71:104621 Chuah X-F, Hsieh C-T, Huang C-L, Senthil Raja D, Lin H-W, Lu S-Y (2019) In-situ grown, passivator-modulated anodization derived synergistically well-mixed Ni–Fe oxides from Ni foam as high-performance oxygen evolution reaction electrocatalyst. ACS Appl Energy Mater 2:743–753 Xu S, Zhao H, Li T, Liang J, Lu S, Chen G, Gao S, Asiri AM, Wu Q, Sun X (2020) Iron-based phosphides as electrocatalysts for the hydrogen evolution reaction: recent advances and future prospects. J Mater Chem A 8:19729–19745 Lu W, Liu T, Xie L, Tang C, Liu D, Hao S, Qu F, Du G, Ma Y, Asiri AM, Sun X (2017) In Situ Derived Co–B Nanoarray: a high-efficiency and durable 3D bifunctional electrocatalyst for overall alkaline water splitting. Small 13:1700805 Li X, Zhang R, Luo Y, Liu Q, Lu S, Chen G, Gao S, Chen S, Sun X (2020) A cobalt–phosphorus nanoparticle decorated N-doped carbon nanosheet array for efficient and durable hydrogen evolution at alkaline pH. Sustain Energy Fuels 4:3884–3887 Xiong X, Ji Y, Xie M, You C, Yang L, Liu Z, Asiri AM, Sun X (2018) MnO2-CoP3 nanowires array: an efficient electrocatalyst for alkaline oxygen evolution reaction with enhanced activity. Electrochem Commun 86:161–165 Xiong X, You C, Liu Z, Asiri AM, Sun X (2018) Co-Doped CuO Nanoarray: an efficient oxygen evolution reaction electrocatalyst with enhanced activity. ACS Sustain Chem Eng 6:2883–2887 You C, Ji Y, Liu Z, Xiong X, Sun X (2018) Ultrathin CoFe-borate layer coated CoFe-layered double hydroxide nanosheets array: a non-noble-metal 3D catalyst electrode for efficient and durable water oxidation in potassium borate. ACS Sustain Chem Eng 6:1527–1531 Gao X, Chen Y, Sun T, Huang J, Zhang W, Wang Q, Cao R (2020) Karst landform-featured monolithic electrode for water electrolysis in neutral media. Energy Environ Sci 13:174–182 Gu Y, Chen S, Ren J, Jia YA, Chen C, Komarneni S, Yang D, Yao X (2018) Electronic structure tuning in Ni3FeN/r-GO aerogel toward bifunctional electrocatalyst for overall water splitting. ACS Nano 12:245–253 Guo M, Li Y, Zhou L, Zheng Q, Jie W, Xie F, Xu C, Lin D (2019) Hierarchically structured bimetallic electrocatalyst synthesized via template-directed fabrication MOF arrays for high-efficiency oxygen evolution reaction. Electrochim Acta 298:525–532 Han A, Jin S, Chen H, Ji H, Sun Z, Du P (2015) A robust hydrogen evolution catalyst based on crystalline nickel phosphide nanoflakes on three-dimensional graphene/nickel foam: high performance for electrocatalytic hydrogen production from pH 0–14. J Mater Chem A 3:1941–1946 He Z, Tong Y, Ni S, Ye X, Makwarimba CP, Huang X, Zhang S, Song S (2018) Electrochemically reductive dechlorination of 3,6-dichloropicolinic acid on a palladium/nitrogen-doped carbon/nickel foam electrode. Electrochim Acta 292:685–696 Huang K, Dong R, Wang C, Li W, Sun H, Geng B (2019) Fe–Ni layered double hydroxide arrays with homogeneous heterostructure as efficient electrocatalysts for overall water splitting. ACS Sustain Chem Eng 7:15073–15079 Jiang D, Ma W, Yang R, Quan B, Li D, Meng S, Chen M (2020) Nickel–manganese bimetallic phosphides porous nanosheet arrays as highly active bifunctional hydrogen and oxygen evolution electrocatalysts for overall water splitting. Electrochim Acta 329:135121 Kang J, Sheng J, Xie J, Ye H, Chen J, Fu X-Z, Du G, Sun R, Wong C-P (2018) Tubular Cu(OH)2 arrays decorated with nanothorny Co–Ni bimetallic carbonate hydroxide supported on Cu foam: a 3D hierarchical core–shell efficient electrocatalyst for the oxygen evolution reaction. J Mater Chem A 6:10064–10073 Lee J, Sher Shah SA, Yoo PJ, Lim B (2017) Hydrous RuO2 nanoparticles as highly active electrocatalysts for hydrogen evolution reaction. Chem Phys Lett 673:89–92 Li K, Yang Y, Bacha A-U-R, Feng Y, Ajmal S, Nabi I, Zhang L (2019) Efficiently complete degradation of 2,4-DCP using sustainable photoelectrochemical reduction and sequential oxidation method. Chem Eng J 378:122191 Zhang L, Yang P, Chen W, Cheng L, Yan J, Yang H (2020) Direct growth of Fe-incorporated NiSe microspheres on FeNi alloy foam as a highly efficient electrocatalyst for oxygen evolution reaction. J Mater Sci Mater Electron 31:15968–15975 Yan C, Huang J, Wu C, Li Y, Tan Y, Zhang L, Sun Y, Huang X, Xiong J (2020) In-situ formed NiS/Ni coupled interface for efficient oxygen evolution and hydrogen evolution. J Mater Sci Technol 42:10–16 Lei X, Ge S, Tan Y, Li J, Wang Z, Liu P, Feng C, Xiang B (2019) Bimetallic phosphosulfide Zn–Ni–P–S nanosheets as binder-free electrodes for aqueous asymmetric supercapacitors with impressive performance. J Mater Chem A 7:24908–24918 Du X, Yang Z, Li Y, Gong Y, Zhao M (2018) Controlled synthesis of Ni(OH)2/Ni3S2 hybrid nanosheet arrays as highly active and stable electrocatalysts for water splitting. J Mater Chem A 6:6938–6946 Du X, Su H, Zhang X (2019) Metal–organic framework-derived Cu-doped Co9S8 nanorod array with less low-valence Co sites as highly efficient bifunctional electrodes for overall water splitting. ACS Sustain Chem Eng 7:16917–16926 Wang T, Zhang X, Zhu X, Liu Q, Lu S, Asiri AM, Luo Y, Sun X (2020) Hierarchical CuO@ZnCo LDH heterostructured nanowire arrays toward enhanced water oxidation electrocatalysis. Nanoscale 12:5359–5362 Ashraf MA, Yang Y, Zhang D, Pham BT (2020) Bifunctional and binder-free S-doped Ni-P nanospheres electrocatalyst fabricated by pulse electrochemical deposition method for overall water splitting. J Colloid Interface Sci 577:265–278 Wang C, Xu H, Wang Y, Shang H, Jin L, Ren F, Song T, Guo J, Du Y (2020) Hollow V-doped CoMx (M = P, S, O) nanoboxes as efficient OER electrocatalysts for overall water splitting. Inorg Chem 59:11814–11822 Zou Y, Xiao B, Shi J-W, Hao H, Ma D, Lv Y, Sun G, Li J, Cheng Y (2020) 3D hierarchical heterostructure assembled by NiFe LDH/(NiFe)Sx on biomass-derived hollow carbon microtubes as bifunctional electrocatalysts for overall water splitting. Electrochim Acta 348:136339 Du X, Fu J, Zhang X (2019) Construction of a MnCo2O4@NiyMx (S and P) crosslinked network for efficient electrocatalytic water splitting. CrystEngComm 21:7293–7302 Jo W-K, Moru S, Tonda S (2019) Cobalt-coordinated sulfur-doped graphitic carbon nitride on reduced graphene oxide: an efficient metal–(N,S)–C-class bifunctional electrocatalyst for overall water splitting in alkaline media. ACS Sustain Chem Eng 7:15373–15384 Karuppasamy K, Bose R, Jothi VR, Vikraman D, Jeong Y-T, Arunkumar P, Velusamy DB, Maiyalagan T, Alfantazi A, Kim H-S (2020) High performance, 3D-hierarchical CoS2/CoSe@C nanohybrid as an efficient electrocatalyst for hydrogen evolution reaction. J Alloys Compd 838:155537 Huang H, Song J, Yu D, Hao Y, Wang Y, Peng S (2020) Few-layer FePS3 decorated with thin MoS2 nanosheets for efficient hydrogen evolution reaction in alkaline and acidic media. Appl Surf Sci 525:146623 Xiao Y, Li B, Qin L, Lin H, Li Q, Nie M, Li Y, Liao B (2020) CuGeO3 micro-nanomaterial as electrocatalyst for hydrogen evolution reaction. Catal Commun 144:106075 Wang J, Zhu R, Cheng J, Song Y, Mao M, Chen F, Cheng Y (2020) Co, Mo2C encapsulated in N-doped carbon nanofiber as self-supported electrocatalyst for hydrogen evolution reaction. Chem Eng J 397:125481 Adegbemiga YB, Ullah N, Xie M, Hussain S, Oluigbo CJ, Yaseen W, Kumar AJ, Xu Y, Xie J (2020) Ni3Fe nanoparticles enclosed by B-doped carbon for efficient bifunctional performances of oxygen and hydrogen evolution reactions. J Alloys Compd 835:155267 Sumi VS, Elias L, Deepa MJ, Shibli SMA (2020) Tuning of the electrocatalytic characteristics of PANI/Fe2O3 composite coating for alkaline hydrogen evolution reaction. Dalton Trans 49:11628–11639