Boetius, 2013, Seafloor oxygen consumption fuelled by methane from cold seeps, Nat. Geosci., 6, 725, 10.1038/ngeo1926
Boulart, 2010, Sensors and technologies for in situ dissolved methane measurements and their evaluation using technology readiness levels, TrAC Trends Anal. Chem., 29, 186, 10.1016/j.trac.2009.12.001
Boyd, 2007, Mesoscale iron enrichment experiments 1993-2005: synthesis and future directions, Science, 315, 612, 10.1126/science.1131669
Brewer, 2004, Development of a laser Raman spectrometer for deep-ocean science, Deep Sea Res. Part I, 51, 739, 10.1016/j.dsr.2003.11.005
Brewer, 1998, Gas hydrate formation in the deep sea: in situ experiments with controlled release of methane, natural gas, and carbon dioxide, Energy Fuels, 12, 183, 10.1021/ef970172q
Burke, 2000, Raman microspectrometry of fluid inclusions, Lithos, 55, 139
Chen, 2007, In situ temperature-dependent Raman spectroscopic studies on methane hydrate forming in natural fluid inclusion, Spectrosc. Spectr. Anal., 27, 1547
Chou, 1987, Phase relations in the system NaCl-KCl-H2O. III: solubilities of halite in vapor-saturated liquids above 445°C and redetermination of phase equilibrium properties in the system NaCl-H2O to 1000 °C and 1500 bars, Geochem. Cosmochim. Acta, 51, 1965, 10.1016/0016-7037(87)90185-2
Chou, 1990, High-density volatiles in the sys- tem C–O–H–N for the calibration of a laser Raman microprobe, Geochem. Cosmochim. Acta, 54, 535, 10.1016/0016-7037(90)90350-T
Chou, 2000, Transformations in methane hydrates, Proc. Natl. Acad. Sci. U.S.A., 97, 13484, 10.1073/pnas.250466497
Chou, 2008, A new method for synthesizing fluid inclusions in fused silica capillaries containing organic and inorganic material, Geochem. Cosmochim. Acta, 72, 5217, 10.1016/j.gca.2008.07.030
Chou, 2017, Application of laser Raman micro-analyses to Earth and planetary materials, J. Asian Earth Sci., 145, 309, 10.1016/j.jseaes.2017.06.032
Cremers, 2006
Demirbas, 2016, Evaluation of natural gas hydrates as a future methane source, Petrol. Sci. Technol., 34, 1204, 10.1080/10916466.2016.1185442
Ding, 2005, The in situ pH of hydrothermal fluids at mid-ocean ridges, Earth Planet Sci. Lett., 237, 167, 10.1016/j.epsl.2005.04.041
Du, 2015, Feasibility investigation on deep ocean compact autonomous Raman spectrometer developed for in-situ detection of acid radical ions, Chin. J. Oceanol. Limnol., 33, 545, 10.1007/s00343-015-4096-8
Du, 2018, In situ Raman quantitative detection of the cold seep vents and fluids in the chemosynthetic communities in the South China Sea, G-cubed, 19, 2049
Du, 2018, In situ Raman spectroscopy study of synthetic gas hydrate formed by cold seep flow in the South China Sea, J. Asian Earth Sci., 168, 197, 10.1016/j.jseaes.2018.02.003
Dubessy, 1983, The determination of sulphate in fluid inclusions using the M.O.L.E. Raman microprobe. Application to a keuper halite and geochemical consequences, Geochem. Cosmochim. Acta, 47, 1, 10.1016/0016-7037(83)90086-8
Dunk, 2005, Seeing a deep ocean CO2 enrichment experiment in a new light: laser Raman detection of dissolved CO2 in seawater, Environ. Sci. Technol., 39, 9630, 10.1021/es0511725
Elderfield, 1996, Mid-ocean ridge hydrothermal fluxes and the chemical composition of the ocean, Annu. Rev. Earth Planet Sci., 24, 191, 10.1146/annurev.earth.24.1.191
Fan, 2013, Calibration of an acoustic system for measuring 2-D temperature distribution around hydrothermal vents, Ultrasonics, 53, 897, 10.1016/j.ultras.2012.12.014
Frezzotti, 2012, Raman spectroscopy for fluid inclusion analysis, J. Geochem. Explor., 112, 1, 10.1016/j.gexplo.2011.09.009
Gillet, 1998, Vibrational properties at high pressures and temperatures, Rev. Mineral. Geochem., 37, 525
Guirado, 2015, Elemental analysis of materials in an underwater archeological shipwreck using a novel remote laser-induced breakdown spectroscopy system, Talanta, 137, 182, 10.1016/j.talanta.2015.01.033
Guirado, 2012, Chemical analysis of archeological materials in submarine environments using laser-induced breakdown spectroscopy. on-site trials in the mediterranean sea, Spectrochim. Acta, Part B, 74–75, 137, 10.1016/j.sab.2012.06.032
Guo, 2017, Development of a compact underwater laser-induced breakdown spectroscopy (LIBS) system and preliminary results in sea trials, Appl. Optic., 56, 8196, 10.1364/AO.56.008196
Hahn, 2010, Laser-induced breakdown spectroscopy (LIBS), part I: review of basic diagnostics and plasma particle interactions: still-challenging issues within the analytical plasma community, Appl. Spectrosc., 64, 335, 10.1366/000370210793561691
Hahn, 2012, Laser-induced breakdown spectroscopy (LIBS), part II: review of instrumental and methodological approaches to material analysis and applications to different fields, Appl. Spectrosc., 66, 347, 10.1366/11-06574
Harmon, 2006, Laser-induced breakdown spectroscopy-an emerging chemical sensor technology for real-time field-portable, geochemical, mineralogical, and environmental applications, Appl. Geochem., 21, 730, 10.1016/j.apgeochem.2006.02.003
Hester, 2006, Raman spectroscopic measurements of synthetic gas hydrates in the ocean, Mar. Chem., 98, 304, 10.1016/j.marchem.2005.09.006
Hester, 2007, Gas hydrate measurements at hydrate ridge using Raman spectroscopy, Geochem. Cosmochim. Acta, 71, 2947, 10.1016/j.gca.2007.03.032
Hester, 2007, Direct measurements of multi-component hydrates on the seafloor: pathways to growth, Fluid Phase Equil., 261, 396, 10.1016/j.fluid.2007.07.053
Horita, 1999, Abiogenic methane formation and isotopic fractionation under hydrothermal conditions, Science, 285, 1055, 10.1126/science.285.5430.1055
Hou, 2014, Study of pressure effects on laser induced plasma in bulk seawater, J. Anal. At. Spectrom., 29, 169, 10.1039/C3JA50244A
John, 1979, Submarine thermal springs on the galápagos rift, Science, 203, 1073, 10.1126/science.203.4385.1073
Kelley, 2002, Volcanoes, fluids, and life at mid-ocean ridge spreading centers, Annu. Rev. Earth Planet Sci., 30, 385, 10.1146/annurev.earth.30.091201.141331
Kirschner, 2001, Classification and identification of enterococci: a comparative phenotypic, genotypic, and vibrational spectroscopic study, J. Clin. Microbiol., 39, 1763, 10.1128/JCM.39.5.1763-1770.2001
Klein, 2019, Abiotic methane synthesis and serpentinization in olivine-hosted fluid inclusions, Proc. Natl. Acad. Sci. Unit. States Am., 116, 17666, 10.1073/pnas.1907871116
Kvenvolden, 1993, Gas hydrates-geological perspective and global change, Rev. Geophys., 31, 173, 10.1029/93RG00268
Kvenvolden, 2001, The global occurrence of natural gas hydrate, Natural Gas Hydrates: Occurrence, Distribution, and Detection, 124, 3
Lawrence-Snyder, 2007, Sequential-pulse laser-induced breakdown spectroscopy of high-pressure bulk aqueous solutions, Appl. Spectrosc., 61, 171, 10.1366/000370207779947639
Lazic, 2014, Laser induced breakdown spectroscopy inside liquids: processes and analytical aspects, Spectrochim. Acta, Part B, 101, 288, 10.1016/j.sab.2014.09.006
Levin, 2005, Ecology of cold seep sediments: interactions of fauna with flow, chemistry and microbes, 11
Levin, 2016, Hydrothermal vents and methane seeps: rethinking the sphere of influence, Front Mar Sci, 3, 72, 10.3389/fmars.2016.00072
Li, 2018, In situ Raman spectral characteristics of carbon dioxide in a deep-sea simulator of extreme environments reaching 300 °C and 30 MPa, Appl. Spectrosc., 72, 48, 10.1177/0003702817722820
Li, 2018, A new approach to measuring the temperature of fluids reaching 300 °C and 2 mol/kg NaCl based on the Raman shift of water, Appl. Spectrosc., 72, 1621, 10.1177/0003702818776662
Li, 2019, Salinity effects on elemental analysis in bulk water by laser-induced breakdown spectroscopy, Appl. Optic., 58, 3886, 10.1364/AO.58.003886
Li, 2019, Effects of ambient temperature on laser-induced plasma in bulk water, Appl. Spectrosc., 73, 1277
Li, 2018, In situ quantitative Raman detection of dissolved carbon dioxide and sulfate in deep-sea high-temperature hydrothermal vent fluids, G-cubed, 19, 1809
Li, 2020, Hydrothermal vapor-phase fluids on the seafloor: evidence from in situ observations, Geophys. Res. Lett., 2020
Lilley, 2003, Magmatic events can produce rapid changes in hydrothermal vent chemistry, Nature, 422, 878, 10.1038/nature01569
Long, 1977
Lu, 2007, Complex gas hydrate from the Cascadia margin, Nature, 445, 303, 10.1038/nature05463
Lu, 2007, A unified equation for calculating methane vapor pressures in the CH4-H2O system with measured Raman shifts, Geochem. Cosmochim. Acta, 71, 3969, 10.1016/j.gca.2007.06.004
López-Claros, 2017, Double pulse laser induced breakdown spectroscopy of a solid in water: effect of hydrostatic pressure on laser induced plasma, cavitation bubble and emission spectra, Spectrochim. Acta, Part B, 133, 63, 10.1016/j.sab.2017.02.010
Lu, 2008, Determination of methane concentrations in water in equilibrium with sI methane hydrate in the absence of a vapor phase by in situ Raman spectroscopy, Geochem. Cosmochim. Acta, 72, 412, 10.1016/j.gca.2007.11.006
McMillan, 1988, Infrared and Raman spectroscopy, vol. 18, 99
Michel, 2007, Laser-induced breakdown spectroscopy of bulk aqueous solutions at oceanic pressures: evaluation of key measurement parameters, Appl. Optic., 46, 2507, 10.1364/AO.46.002507
Milucka, 2012, Zero-valent sulphur is a key intermediate in marine methane oxidation, Nature, 491, 541, 10.1038/nature11656
Oguchi, 2007, Effects of pulse duration upon the plume formation by the laser ablation of Cu in water, J. Appl. Phys., 102, 1, 10.1063/1.2759182
Pancost, 2000, Biomarker evidence for widespread anaerobic methane oxidation in Mediterranean sediments by a consortium of methanogenic archaea and bacteria, Appl. Environ. Microbiol., 66, 1126, 10.1128/AEM.66.3.1126-1132.2000
Pasteris, 2004, Raman spectroscopy in the deep ocean: successes and challenges, Appl. Spectrosc., 58, 195A, 10.1366/0003702041389319
Pätzold, 2006, A new approach to non-destructive analysis of biofilms by confocal Raman microscopy, Anal. Bioanal. Chem., 386, 286, 10.1007/s00216-006-0663-3
Paull, 1984, Biological communities at the Florida Escarpment resemble hydrothermal vent taxa, Science, 226, 965, 10.1126/science.226.4677.965
Paull, 2001, vol. 124, 53
Peltzer, 2016, In situ Raman measurement of HS- and H2S in sediment pore waters and use of the HS-: H2S ratio as an indicator of pore water pH, Mar. Chem., 184, 32, 10.1016/j.marchem.2016.05.006
Qiu, 2020, In situ Raman spectroscopic quantification of CH4-CO2 mixture: application to fluid inclusions hosted in quartz veins from the Longmaxi Formation shales in Sichuan Basin, southwestern China, Petrol. Sci., 17, 23, 10.1007/s12182-019-00395-z
Qiu, 2020, In situ Raman spectroscopic quantification of aqueous sulfate: experimental calibration and application to natural fluid inclusions, Chem. Geol., 533, 119447, 10.1016/j.chemgeo.2019.119447
Resing, 2015, Basin-scale transport of hydrothermal dissolved metals across the South Pacific Ocean, Nature, 523, 200, 10.1038/nature14577
Rull, 2012, The Raman effect and the vibrational dynamics of molecules and crystalline solids, 1
Sakai, 1990, Venting of carbon dioxide-rich fluid and hydrate formation in mid-Okinawa trough backarc basin, Science, 248, 1093, 10.1126/science.248.4959.1093
Sander, 2011, Metal flux from hydrothermal vents increased by organic complexation, Nat. Geosci., 4, 145, 10.1038/ngeo1088
Schmidt, 2004, Detection of PAHs in seawater using surface-enhanced Raman scattering (SERS), Mar. Pollut. Bull., 49, 229, 10.1016/j.marpolbul.2004.02.011
Schmidt, 2017, Chem. Geol., 467, 64, 10.1016/j.chemgeo.2017.07.022
Sloan, 2003, Fundamental principles and applications of natural gas hydrates, Nature, 426, 353, 10.1038/nature02135
Smith, 2005
Suess, 2014, Marine cold seeps and their manifestations: geological control, biogeochemical criteria and environmental conditions, Int. J. Earth Sci., 103, 1889, 10.1007/s00531-014-1010-0
Thornton, 2014, Long-duration nano-second single pulse lasers for observation of spectra from bulk liquids at high hydrostatic pressures, Spectrochim. Acta, Part B, 97, 7, 10.1016/j.sab.2014.04.008
Thornton, 2015, Development of a deep-sea laser-induced breakdown spectrometer for in situ multi-element chemical analysis, Deep Sea Res. Part I, 95, 20, 10.1016/j.dsr.2014.10.006
Thornton, 2011, Effects of pressure on the optical emissions observed from solids immersed in water using a single pulse laser, Appl. Phys. Express., 4, 3, 10.1143/APEX.4.022702
Tian, 2019, Laser focusing geometry effects on laser-induced plasma and laser-induced breakdown spectroscopy in bulk water, J. Anal. At. Spectrom., 34, 118, 10.1039/C8JA00282G
Tognoni, 2006, From sample to signal in laser-induced breakdown spectroscopy: a complex route to quantitative analysis, Laser-Induced Breakdown Spectrosc., 122
Truche, 2016, Direct measurement of CO2 solubility and pH in NaCl hydrothermal solutions by combining in-situ potentiometry and Raman spectroscopy up to 280 °C and 150 bar, Geochem. Cosmochim. Acta, 177, 238, 10.1016/j.gca.2015.12.033
Wan, 2017, In situ optical and Raman spectroscopic observations of the effects of pressure and fluid composition on liquid-liquid phase separation in aqueous cadmium sulfate solutions (≤400 °C, 50 MPa) with geological and geochemical implications, Geochem. Cosmochim. Acta, 211, 133, 10.1016/j.gca.2017.05.020
Wang, 2011, Raman spectroscopic measurements of CO2 density: experimental calibration with high-pressure optical cell (HPOC) and fused silica capillary capsule (FSCC) with application to fluid inclusion observations, Geochem. Cosmochim. Acta, 75, 4080, 10.1016/j.gca.2011.04.028
Wang, 2013, Raman spectroscopic characterization on the OH stretching bands in NaCl-Na2CO3-Na2SO4-CO2-H2O systems: implications for the measurement of chloride concentrations in fluid inclusions, J. Geochem. Explor., 132, 111, 10.1016/j.gexplo.2013.06.006
Weiss, 1977, Hydrothermal plumes in the Galapagos rift, Nature, 267, 600, 10.1038/267600a0
Wenner, 2004, Environmental chemical mapping using an underwater mass spectrometer, TrAC Trends Anal. Chem., 23, 288, 10.1016/S0165-9936(04)00404-2
White, 2006, In situ Raman analyses of deep-sea hydrothermal and cold seep systems (Gorda Ridge and Hydrate Ridge), G-cubed, 7
White, 2009, Laser Raman spectroscopy as a technique for identification of seafloor hydrothermal and cold seep minerals, Chem. Geol., 259, 240, 10.1016/j.chemgeo.2008.11.008
White, 2005, Development and deployment of a precision underwater positioning system for in situ laser Raman spectroscopy in the deep ocean, Deep Sea Res. Part I, 52, 2376, 10.1016/j.dsr.2005.09.002
Wopken, 1986, Limitations to quantitative analysis of fluid inclusions in geological samples by laser Raman microprobe spectroscopy, Appl. Spectrosc., 40, 144, 10.1366/0003702864509592
Wopken, 1987, Raman intensities and detection limits of geochemically relevant gas mixtures for a laser Raman microprobe, Anal. Chem., 59, 2165, 10.1021/ac00144a034
Xi, 2019, Micro-Raman study of thermal transformations of sulfide and oxysalt minerals based on the heat induced by laser, Minerals, 9, 751, 10.3390/min9120751
Xi, 2018, A direct quantitative Raman method for the measurement of dissolved bisulfate in acid-sulfate fluids, Appl. Spectrosc., 72, 1234, 10.1177/0003702818773117
Xi, 2018, Laser Raman detection of authigenic carbonates from cold seeps at the Formosa Ridge and east of the Pear River Mouth Basin in the South China Sea, J. Asian Earth Sci., 168, 207, 10.1016/j.jseaes.2018.01.023
Xi, 2020, Biogeochemical implications of chemosynthetic communities on the evolution of authigenic carbonates, Deep Sea Res. Part I, 10.1016/j.dsr.2020.103305
Zhang, 2017, In situ Raman detection of gas hydrates exposed on the seafloor of the South China Sea, G-cubed, 18, 3700
Zhang, 2017, Development of a new deep-sea hybrid Raman insertion probe and its application to the geochemistry of hydrothermal vent and cold seep fluids, Deep Sea Res. Part I, 123, 1, 10.1016/j.dsr.2017.02.005
Zhang, 2011, In situ Raman-based measurements of high dissolved methane concentrations in hydrate-rich ocean sediments, Geophys. Res. Lett., 38, 10.1029/2011GL047141
Zhang, 2020, Discovery of supercritical carbon dioxide in a hydrothermal system, Sci. Bull., 65, 958, 10.1016/j.scib.2020.03.023
Zhang, 2010, Development and deployment of a deep-sea Raman probe for measurement of pore water geochemistry, Deep Sea Res. Part I, 57, 297, 10.1016/j.dsr.2009.11.004