The Synthesis and Structural Features of Tetra(para-tolyl)antimony Derivatives
Tóm tắt
The interaction of penta(para-tolyl)antimony with oximes and carboxylic acids in benzene synthesized oximates and carboxylates of tetra(para-tolyl)antimony p-Tol4SbX (X = ON=CHR, R = CHCHPh (1), С6H4(Br-3) (2); X = OC(O)R', R' = CH2OС6H3Cl2-2,4 (3), CF2CF2C(O)OH (4). The structure of compounds 1–4 was established by X-ray diffraction analysis (XRD). According to XRD data, the antimony atoms in complexes 1–3 have the coordination of a distorted trigonal bipyramid with three aryl ligands in the equatorial plane, while the CSbO axial angles are 178.94(5)°, 174.4(2)° and 176.95(5)°. Crystal 4 consists of distorted tetrahedral cations of tetra(para-tolyl)stibonium (CSbC angles 106.6(2)°−112.46(19)°) and singly charged anions of tetrafluoroethanedioic acid. Complete tables of atomic coordinates, bond lengths, and bond angles for compounds 1, 2, 3, 4 have been deposited at the Cambridge Crystallographic Data Center (CCDC 2130472, 2131085, 2131084, 2126158; [email protected];
http://www.ccdc.cam.ac.uk
).
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